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Silicon Carbide Fiber-Reinforced Silicon Nitride Composites

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Handbook of Ceramic Composites

Abstract

The fabrication and thermo-mechanical properties of SiC monofilament- and SiC fiber tow-reinforced reaction-bonded silicon nitride matrix composites (SiC/RBSN) and fully dense SiC monofilament-reinforced silicon nitride matrix composites (SiC/Si3N4) have been reviewed. The SiC/RBSN composites display high strength and toughness, and low thermal conductivity in the as-fabricated condition, but are susceptible to internal oxidation and mechanical property degradation in the intermediate temperature range from 400 to 1100°C. The internal oxidation problem can be avoided by applying functionally graded oxidation resistant coatings on external surfaces of the composite. On the other hand, the fully dense SiC/Si3N4 composites fabricated by using SiC monofilaments and pressure assisted sintering methods display moderate strength and limited strain capability beyond matrix cracking stress. Advantages, disadvantages, and potential applications of SiC fiber-reinforced silicon nitride matrix composites fabricated using various fiber types and processing methods are discussed.

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References

  1. M.W. Lindley and D.J. Godfrey, “Silicon Nitride Composites with High Toughness,” Nature,229, 192–193(1971).

    Article  CAS  Google Scholar 

  2. J.W. Lucek, G.A. Rossetti, Jr., and S.D. Hartline, “Stability of Continuous Si-C (-O) Reinforcing Elements in Reaction-Bonded Silicon Nitride Process Environments,” pp. 27–38 in Metal Matrix, Carbon, and Ceramic Matrix Composites 1985, NASA CP-2406, Edited by J.D. Buckley, NASA, Washington, D.C., 1985.

    Google Scholar 

  3. N.D. Corbin, G.A. Rossetti, Jr., and S.D. Hartline, “Microstructure/Property Relationships for SiC Filament-Reinforced RBSN,” Ceram. Eng. Sci. Proc., 10,[9–10], pp. 1083–1089 (1989).

    Google Scholar 

  4. J. Brandt, K. Rundgren, R. Pompe, H. Swan, C. O’Meara, R. Lundberg, and Pejryd, “SiC Continuous Fiber-Reinforced Si3N4 by Infiltration and Reaction Bonding,” Ceram. Eng. Sci. Proc. 13,[9–10], pp. 622–631 (1992).

    CAS  Google Scholar 

  5. T.L Starr, D.L. Mohr, W.J. Lackey, and J.A. Hanigofsky, “Continuous Fiber-Reinforced Reaction Sintered Silicon Nitride Composites,” Ceram. Eng. Sci. Proc. 14,[9–10], pp. 1125–1132 (1993).

    CAS  Google Scholar 

  6. R.T. Bhatt, “Method of Preparing Fiber Reinforced Ceramic Materials,” U.S. Pat. No. 4689188, 1987.

    Google Scholar 

  7. R.T. Bhatt, “Mechanical Properties of SiC/RBSN Composites”, in “Tailoring Multiphase and Composite Ceramics,” (1986), p. 675 edited by R.E. Tressler, G.L. Messing, C.G. Pantano and R.E. Newnham, Plenum Press, New York.

    Google Scholar 

  8. R.T. Bhatt, “The Properties of Silicon Carbide Fiber Reinforced Silicon Nitride Composites,” in Whiskerand Fiber-Toughened Ceramics (1988) pp. 199–208 edited by R.A. Bradley, D.E. Clark, D.C. Larsen, and J.O. Stiegler, ASM International, Ohio.

    Google Scholar 

  9. R.T. Bhatt and R.E. Phillips, “Laminate Behavior for SiC Fiber-Reinforced Reaction-Bonded Silicon Nitride Matrix Composites,” J. Comp. Techn. Res. 12, p. 13, 1990.

    Article  CAS  Google Scholar 

  10. R.T. Bhatt and J.D. Kiser, “Matrix Density Effects on Mechanical Properties of SiC/RBSN Composites,” NASA-TM 103733, 1990.

    Google Scholar 

  11. R.T. Bhatt, “Tensile Properties and Microstructural Characterization of Hi-Nicalon SiC/RBSN Composites,” Ceramics International, #26, pp. 535–539, 2000.

    Google Scholar 

  12. A.J. Moulson, “Review: Reaction Bonded Silicon Nitride; Its Formation and Properties,” J. Mater. Sci., 14, pp. 1017–1051, 1979.

    Article  CAS  Google Scholar 

  13. S. Hamshire, “Engineering Properties of Nitrides,” Engineered Materials Handbook, V1, 1987 ASM International, Metals Park, Ohio 44073.

    Google Scholar 

  14. R.T. Bhatt, “Tension, Compression, and Bend Properties for SiC/RBSN Composites,” Proc. of the 8th ICCM Conference Vol. III, 23–A, 1991.

    Google Scholar 

  15. G.K. Bansal and W.H. Duckworth, “Effects of Specimen Size on Ceramic Strength,” in “Fracture Mechanics of Ceramics” (1978), 3, p. 189 edited by R.C. Bradt, D.P.H. Hasselman and F.F. Lange, Plenum Press, New York.

    Google Scholar 

  16. J.Z. Gykenyesi, “High Temperature Mechanical Characterization of Ceramic Matrix Composites” NASA CR-206611, 1998.

    Google Scholar 

  17. R.T. Bhatt and A.R. Palczer, “Effects of Thermal Cycling on Thermal Expansion and Mechanical Properties of SiC Fiber-Reinforced Silicon Nitride Matrix Composites,” J. Mat. Sci. 32, 1039–1047, 1997.

    Article  CAS  Google Scholar 

  18. H. Bhatt, K.Y. Donaldson, D.P.H. Hasselman, and R.T. Bhatt, “Effect of Finite Interfacial Conductance on the Thermal Diffusivity/Conductivity of SiC Fiber Reinforced RBSN,” Thermal Conductivity 21. 1990, ed. C.J. Cremers and H.A. Fines, Plenum Press, New York, NY.

    Google Scholar 

  19. H. Bhatt, K.Y. Donaldson, D.P.H. Hasselman, and R.T. Bhatt, “Role of Interfacial Thermal Barrier in the Effective Thermal Diffusivity / Conductivity of SiC Fiber Reinforced RBSN,” J. Am. Ceram. Soc., 73,[2], 312, 1990.

    Article  CAS  Google Scholar 

  20. R.T. Bhatt and R.E. Phillips, “Thermal Effects on the Mechanical Properties of SiC Fiber-Reinforced Reaction-Bonded Silicon Nitride Matrix Composites,” J. Mat. Sci., 25, 3401, 1990.

    Article  CAS  Google Scholar 

  21. R.T. Bhatt, “Oxidation Effects on the Mechanical Properties of a SiC Fiber Reinforced Reaction-Bonded Si3N4 Matrix Composites,” J. Am. Ceram. Soc., 75, 406, 1992.

    Article  CAS  Google Scholar 

  22. G.E. Hilmas, J.W. Holmes, R.T. Bhatt, and J.A. DiCarlo, “Tensile Creep Behavior and Damage Accumulation in a SiC-Fiber/RBSN-Matrix Composite,” in Ceramic Transactions Vol. 38 — Advances in Ceramic Matrix Composites, N. Bansal (ed.), ACS, Westerville, OH, pp. 291–304, 1993.

    Google Scholar 

  23. A.P.M. Adriaansen, and H. Gooijer, “Comparative Study of the Oxidation of RBSN and RBSN Coated With CVD Si3N4,” Euro. Ceram., V3, 1989, pp. 569–574.

    Google Scholar 

  24. O.J. Gregory and M.H. Richman, “Thermal Oxidation of Sputter-Coated Reaction-Bonded Silicon Nitride,” J. Amer. Ceram. Soc. 67,[5], pp. 335–340 (1984).

    CAS  Google Scholar 

  25. J. Desmaison, N. Roels, and P. Belair, “High-Temperature Oxidation-Protection CVD Coatings for Structural Ceramics: Oxidation Behavior of CVD-Coated Reaction-Bonded Silicon Nitride,” Mater. Sci. and Eng., A121 441–447 (1989).

    Article  Google Scholar 

  26. D.S. Fox, “Oxidation Kinetics of Coated SiC/RBSN,” 6th Annual HITEMP Review — 1993 NASA CP 19117 pp. 69-1 to 69-3.

    Google Scholar 

  27. D.S. Fox, “Oxidation Protection of Porous Reaction-Bonded Silicon Nitride,” J. Mat. Sci. 29(21), 5693–5698, 1994.

    Article  CAS  Google Scholar 

  28. W. Fohey, R.T. Bhatt, and G.Y. Baaklini, “Burner Rig and Engine Test Results on SiC/RBSN Composites,” 6th Annual HITEMP Review — 1993 NASA CP 19117 pp. 68-1 to 68-3.

    Google Scholar 

  29. R.W. Rice, P.F. Becher, S.W. Freiman, and W.J. McDonough, “Thermal Structural Ceramic Composites,” Ceram. Eng. Sci. Proc., 1,[7–8], pp. 424–443 (1980).

    CAS  Google Scholar 

  30. D.K. Shetty, M.R. Pascucci, B.C. Mutsudy, and R.R. Wills, “SiC Monofilament-Reinforced Si3N4 Matrix Composites,” Ceram. Eng. Sci. Proc. 16,[7–8], pp. 632–645 (1985).

    Google Scholar 

  31. W. Foulds, J.F. Lecostaouec, C. Landry, and S. Dipietro, “Tough Silicon Nitride Matrix Composites Using Textron Silicon Carbide Monofilaments,” Ceram. Eng. Sci. Proc. 10,[9–10], pp. 1083–1089 (1989).

    CAS  Google Scholar 

  32. A.G. Razzel and M.H. Lewis, “Silicon Carbide/SRBSN Composites,” Ceram. Eng. Sci. Proc. 12,[7–8], pp. 1304–1317 (1991).

    Google Scholar 

  33. K. Nakano, S. Kume, K. Sasaki, and H. Saka, “Microstructure and Mechanical Properties of Hi-Nicalon Fiber Reinforced Si3N4 Matrix Composites,” Ceram. Eng. Sci. Proc. 17,[4], pp. 324–332 (1996).

    Article  CAS  Google Scholar 

  34. J.W. Holmes, Y. Parks, and J.W. Jones, “Tensile Creep and Creep Recovery Behavior of a SiC Fiber Si3N4 Matrix Composite,” J. Am. Ceram. Soc., 76[5] 1281–1293 (1993).

    Article  CAS  Google Scholar 

  35. J.W. Holmes, “Tensile Creep Behavior of a Fiber Reinforced SiC-Si3N4 Composite,” J. Mat. Sci., 26, 1808–1814 (1991).

    Article  CAS  Google Scholar 

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Bhatt, R.T. (2005). Silicon Carbide Fiber-Reinforced Silicon Nitride Composites. In: Bansal, N.P. (eds) Handbook of Ceramic Composites. Springer, Boston, MA . https://doi.org/10.1007/0-387-23986-3_7

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