Conclusion
In many ways the durable nature of copper and its alloys lends itself to trouble-free conservation. Artifacts of copper and its alloys brass and bronze, are durable and long lasting. They will survive well in the archaeological record and if their corrosion product is reduced and plated once again as pure metal on the artifact they may well envisage the same detail they had when they were in active use. The artifacts detailed micro-excavation should easily provide details of manufacturing and wear that will not be as well preserved on other metals. Yet these details will only be revealed if the artifact is protected and conserved from the moment it is archaeologically located, until after it goes into final storage.
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Chapter 4: Archaeological Copper (Cu) And Copper Alloys
American Copper and Brass. New York: Bonanza Books, 1968.
Alsop, Joseph.“Warriors from a Watery Grave.” National Geographic 163 (1983): 820–827. [ECU-271]
Angelucci, S., P. Fiorentino, J. Kosinkova, and M. Marabelli. “Pitting Corrosion in Copper and Copper Alloys: Comparative Treatment Tests.” Studies in Conservation 23 (1978): 147–156. [ECU-127]
Anon. “Navy Board’s Report to the Admiralty on the First Coppering Experiment—31 August, 1763,” American Neptune I (1941): 304–306. [ECU-116]
Bankok National Museum. Bronze Disease and its Treatment. Bankok: Department of Fine Arts, Bankok Museum, 1975.
Barclay, B. “Basic Care of Coins and Metals.” CCI Notes (Canadian Conservation Institute) 9/4 (1991). [ECU-355]
Barker, Richard. “Bronze Cannon Founders: Comemnts upon Gilmartin 1974, 1982.” International. Journal of Nautical Archaeology 12 (1978): 23–27. [ECU-242]
Bianchi, G. and P. Longhi. “Copper in Sea Water, Potential pH Diagrams.” Corrosion Science 13 (1973): 853–864. [ECU-219]
CCI Laboratory Staff. “The Cleaning, Polishing, and Protective Waxing of Brass and Copper.” CCI Notes (Canadian Conservation Institute) 9/3 (1988). [ECU-467]
CCI Laboratory Staff. “Basic Care of Coins and Metals.” CCI Notes (Canadian Conservation Institute) 9/4 (1989). [ECU-466]
CCI Laboratory Staff. “Silver-Care and Tarnish Removal.” CCI Notes (Canadian Conservation Institute) 9/7 (1993). [ECU-473]
Cohen, A. “Copper Alloys in Marine Enviroments.” (1975 Liberty Bell Corrosion Symposium) (1973).
—. “The Corrosion of Copper-Nickel Alloys in Sulfide-Polluted Seawater: The Effect of Sulfide Concentration.” Corrosion Science Vol. 34No. 1, pp. 163–177. [ECU-677]
Cotton, J.B. “Control of Surface Reactions on Copper by Means of Organic Reagents.” Proceedings (Second International Congress on Metallic Corrosion, New York) (1963): 590–596.
Cottrell, L.H. “An Introduction to Metallurgy: Copper and Its Alloys.” Retrieval of Objects from Archaeological Sites. Archetype Publications, London. [ECU-568]
Drayman-Weisser, Terry. “A Perspective on the History of the Conservation of Archaeological Copper Alloys in the United States.” Journal of the American Institute for Conservation Vol. 33No. 2, 1994. [ECU-678]
Dugdale, I., and J.B. Cotton. “An Electrochemical Investigation on the Prevention of Staining of Copper by Benzotriazole.” Corrosion Science 3 (1963): 69–74. [ECU-187]
Duncan, S., and H. Ganiaris. “Some Sulphide Corrosion Products on Copper Alloys and Lead Alloys from London Waterfront Sites.” Recent Advances in the Conservation and Analysis of Artifacts J. Black, ed. (Institute of Archaeology Summer Schools Press, London) (1987): 109–118.
Faltermeier, Robert B. “A Corrosion Inhibitor Test for Copper-Based Artifacts.” Studies in Conservation Vol. 44No. 2, 1999, pp. 121–128. [ECU-679]
Fox, Georgia L. “A note on the use of alkaline dithionite for treating ancient bronze artifacts.” Studies in Conservation Vol. 40No. 2, 1995, pp. 139–142. [ECU-680]
Fuller, Cbarles. The Art of Coppersmithing. New York: David Williams, 1894.
Furer, J., M. Lambertin, and I.C. Colson. “Morphological and Kinetic Study of Copper Corrosion when Covered with Digenite Sulphide Layers, in Sulphur, under Covvelite Formation Conditions.” Corrosion Science 17 (1977): 625–632. [ECU-496]
Ganorkar, M.C., V. Pandet Rae, P. Gayaltri, and T.A. Sreenivasa-Rae. “A Novel Method for the Conservation of Copper-Based Artifacts,” Studies in Conservation 33 (1988): 97–101. [ECU-385]
Giuliani, L. and G. Bombara. “An Electrochemical Study of Copper Alloys in Chloride Solutions.” British Corrosion Journal 5 (1970): 179–183. [ECU-139]
Hamilton, Donny L. Basic Methods of Conserving Underwater Archaeological Material Culture. Washington, D.C.: U.S. Department of Defense Legacy Resource Management Program, January 1996. [ECU-610]
Huda, Khatibul. “A note on the efficacy of ethylenediaminetetra-acetic acid disodium salt as a stripping agent for corrosion products of copper.” Studies in Conservation Vol. 47No. 3, 2002, pp. 211–216. [ECU-681]
Joseph, G., and M.T. Arce. “Contribution to the Study of Brass Dezincification.” Corrosion Science 7 (1967): 597–605. [ECU-137]
Keith, Donald Hand Worth Carlin. “Abronze cannon from LaBelle, 1686: its construction, conservation, and display.” International Journal of Nautical Archaeology Vol. 26No. 2, 1997, pp. 144–158. [ECU-682]
—. “A Laboratory Study of Corrosion Reaction on Statue Bronze.” Corrosion Science Vol. 34No. 7, pp. 1083–1097. [ECU-683]
LaFontaine, Raymond H. “The Use of a Stabilizing Wax to Protect Brass and Bronze Artifacts.” Journal of the IIC-CG 4:2 (1980).
Little, Arthur D., Inc. “Protective Coating for Copper Metals.” (International Copper Research Association, Inc., Report No. 97) (1972).
MacLeod, Donald Ian. “Bronze Disease: An Electrochemical Explanation.” ICOM Bulletin 1 (1981): 16–26.
—. “Formation of Marine Concretions on Copper and Its Alloys.” International Journal of Nautical Archaeology 11:4 (1982): 267–275. [ECU-243]
—. “Conservation of Corroded Copper Alloys: A Comparison of New and Traditional Methods for Removing Chloride Ions.” Studies in Conservation 33 (1987): 25–40. [ECU-191]
—. “Stabilization of Corroded Copper Alloys: A Study of Corrosion and Desalination Mechanisma.” ICOM (Committee for Conservation, Sydney) (1987).
MacLeod, Ian Donald and R.J. Taylor. “Corrosion of Bronzes on Shipwrecks—A Comparison of Corrosion Rates Deduced from Shipwreck Material and from Electrochemical Methods.” Corrosion 41:2 (1985): 100–104.
Madsen, H. Brinch. “A Preliminary Note on the Use of Benzotriazole for Stabilizing Bronze Objects.” Studies in Conservation 12 (1967): 163–166.
—. “Further Remarks on the Use of Benzotriazole for Stabilizing Bronze Objects.” Studies in Conservation 16 (1971): 120–122.
Mcneil, Michael B. and Brenda J. Little. “Corrosion Mechanisms for Copper and Silver Objects in Near-Surface Environments.” Journal of the American Institute for Conservation Vol. 31No. 3, 1992. [ECU-684]
Merk, Linda A. “A Study of Reagents used in the Stripping of Bronzes.” Studies in Conservation 23 (1978): 15–22. [ECU-184]
Mor, E.D. and A.M. Beccaria. “Behavior of Copper in Artificial Seawater Containing Sulphides.” British Corrosion Journal 10 (1975): 33–38.
—. “Effects of Hydrostatic Pressure on the Corrosion of Copper in Water.” British Corrosion Journal 13:3 (1978): 142–146. [ECU-140]
—. “Effects of Temperature on the Corrosion of Copper in Seawater at Different Hydrostatic Pressures.” Wersktoffe und Korrosion 30 (1979): 554–558.
Nord, Anders G., Karin Lindahl, and Kate Tronner. “A note of spionkopite as a corrosion product on a marine copper find.” Studies in Conservation Vol. 38No. 2, 1993, pp. 92–98. [ECU-685]
North, N.A. and Colin Pearson. “Investigations Into Methods for Conserving Iron Relics from Marine Sites.” Contributions to the 1975 Stockholm Conference. IIC London, 1976: 173–182. [ECU-573, 606]
Pearson, Colin, ed. Conservation of Marine Archaeological Objects, London: Butterworths Series in Conservation and Museology, 1987. [ECU-6]
Richey, W.D. “The Interaction of Benzotriazole with Copper Compounds.” (ICOM Comittee for Conservation, Madrid) (1972).
Scott, David A. “Ancient Bronzes Modern Science.” Chemistry in Britain Vol. 31No. 8, 1995, pp. 627–630. [ECU686]
—. “An Examination of the Patina and Corrosion Morphology of Some Roman Bronzes.” Journal of the American Institute for Conservation Vol. 33No. 1, 1994. [ECU-686]
Schussler, A. and H.E. Exner. “The Corrosion of Nickel-Aluminum Bronzes in Seawater I—Protective Layer Formation and the Passivation Mechanism.” Corrosion Science Vol. 34No. 11, 1993. [ECU-704]
Schussler, A. and H.E. Exner. “The Corrosion of Nickel-Aluminum Bronzes in Seawater II—The Corrosion Mechanism in the Presence of Sulfide Pollution.” Corrosion Science Vol. 34No. 11, 1993. [ECU-705]
Sharma, V.C. and B.V. Kharbade. “Sodium Tripolyphosphate—a safe sequestering agent for the treatment of excavated copper objects.” Studies in Conservation Vol. 39No. 1, 1994, pp. 39–44. [ECU-687]
Sharma, V.C., Uma Shankar Lal, and M.V. Nair. “Zinc Dust Treatment—an Effective Method for the Control of Bronze Disease on Excavated Objects.” Studies in Conservation Vol. 40No. 2, 1995, pp. 110–119. [ECU-688]
Spriggs, J.A. “Treating the Coppergate Structures—A Quest for Antishrink Efficiency.” Archaeological. Papers from York M.W. Barley, P.V. Addyman and V.E. Black, eds. (1984): 78–86.
Suguwara, H. and Hideaki Ebiko. “Dezincification of Brass.” Corrosion Science 7(167): 513–523. [ECU-0136]
Sweeny, Louise. “Winning the Pigeon Battle of Washington.” Christian Science Monitor (1991): 13. [ECU-366]
Taylor, R.J. and Ian D. MacLeod. “Corrosion of Bronzes on Shipwrecks: A Comparison of Corrosion Rates Deduced from Shipwreck Material and from Electrochemical Methods.” Corrosion 41:2 (1985): 100–104. [ECU-144]
Trentelman, K.L. Stodulski, D. Scott, M. Back, D. Strahan, A.R. Drews, A.O. ’Neill, H. Weber, A.E. Chen, and S.J. Garrett. “The Characterization of a new Pale Blue Corrosion Product Found on Copper Alloy Artifacts.” Studies in Conservation Vol. 47No. 4, 2002, pp. 217–227. [ECU-689]
Uminski, Maciej and Viviana Guidetti. “The Removal of Chloride Ions from Artificially Corroded Bronze Plates.” Studies in Conservation Vol. 40No. 4, 1995, pp. 274–278. [ECU-690]
Walker, R. “Benzotriazole as a Corrosion Inhibitor for Immersed Copper.” Corrosion 29 (1973): 290–296. [ECU-145]
—. “Benzotriazole as a Corrosion Inhibitor,” Metal Finishing 71:9 (1973): 63–66. [ECU-394]
—. “The Role of Benzotriazole in the Preservation of Copper Based Antiquities.” The Conservation. and Restoration of Metals (Proceedings of the Edinburgh Symposium, Scottish Society for Conservation and Restoration, Edinburgh) (1979): 40–49.
Watanabe, Masamitsu, and Yasohiro Higashiand Tohru Tavaka. “Difference Between Corrosion Products Formed on Copper Exposed in Tokyo in Summer and Winter.” Corrosion Science Vol. 45No. 7, 2003, pp. 1439–1453. [ECU-691]
Weisser, T.D. “The De-Alloying of Copper Alloys.” Conservation in Archaeology and the Applied Arts N. Brumellie and P. Smith, eds. (Proceedings of the 1975 Stockholm Congress, International Institute for Conservation of Historic and Artistic Works, London) (1976): 207–214.
Zhang, Xiaomei. “An Unusual Corrosion Product, Pyromorphite, from a Bronze An: a Technical Note.” Studies in Conservation Vol. 47No. 1, 2002, pp. 76–79. [ECU-692]
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(2004). Archaeological Copper (Cu) and Copper Alloys. In: The Archaeologist’s Manual for Conservation. Springer, Boston, MA. https://doi.org/10.1007/0-306-48613-X_5
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