Skip to main content
SpringerLink
Log in
Book cover

Nanoscale Materials pp 79–96Cite as

Metal Nanoparticles for Catalysis

  • Chapter

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD   329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

8. References

  1. G. Schmid (Ed.): Clusters and Colloids. From theory to Applications (VCH, Wienheim, 1994).

    Google Scholar 

  2. N. Toshima and T. Yonezawa, Bimetallic nanoparticles—novel materials for chemical and physical applications, New J. Chem. 22, 1179–1201 (1998).

    Article  CAS  Google Scholar 

  3. N. Toshima and Y. Shiraishi, Catalysis by metallic colloids. In: Encyclopedia of Surface and Colloid Science, edited by A. T. Hubbard (Marcel Dekker, New York, 2002), pp. 879–886.

    Google Scholar 

  4. H. Hirai and N. Toshima, Polymer-attached catalysis. In: Tailored Metal Catalysts, edited by Y. Iwasawa (D. Reidel Pub. Co., Dordrecht, 1985), pp. 87–140.

    Google Scholar 

  5. H. Hirai, Y. Nakao, N. Toshima, and K. Adachi, Colloidal rhodium in polyvinyl alcohol as hydrogenation catalyst of olefins, Chem. Lett., 905 (1976).

    Google Scholar 

  6. N. Toshima, K. Kushihashi, T. Yonezawa, and H. Hirai, Colloidal dispersions of palladium-platinum bimetallic clusters protected by polymers. Preparation and application to catalysis, Chem. Lett., 1769–1772 (1989).

    Google Scholar 

  7. A. S. Eppler, G. Rupprechter, E. A. Anderson, and G. A. Somorjai, Thermal and chemical stability and adhesion strength of Pt nanoparticle arrays supported on silica studied by transmission electron microscopy and atomic force microscopy, J. Phys. Chem. B 104, 7286–7292 (2000).

    Article  CAS  Google Scholar 

  8. A. S. Eppler, J. Shu, E. A. Anderson, and G. A. Somorjai, Model catalysts fabricated by electron beam lithography: AFM and TPD surface studies and hydrogenation/dehydrogenation of cyclohexene H2 on a Pt nanoparticle array supported by silica, Topics in Catal. 13, 33–41 (2000).

    CAS  Google Scholar 

  9. N. Toshima, Nanostructured metal clusters in polymeric field as a model of artificial enzyme, Supramol. Sci. 5, 395–398 (1998).

    Article  CAS  Google Scholar 

  10. N. Toshima, Reactions in homogeneous solutions. In: Fine Particle. Synthesis, Characterization, and Mechanism of Growth, edited by T. Sugimoto (Marcel Dekker, New York, 2000), pp. 430–459.

    Google Scholar 

  11. S. S. Hladyi, M. K. Starchevsky, Y. A. Pazdersky, M. N. Vargaftik, and I. I. Moiseev, Oxidative and anaerobic reactions of benzyl alcohol catalysed by a Pd-561 giant cluster, Mendeleev Commun., 45–46 (2002).

    Google Scholar 

  12. J. S. Bradley, The chemistry of transition metal colloids. In: Clusters and Colloids. From Theory to Application, edited by G. Schmid (VCH, Wienhiem, 1994), pp. 459–544.

    Google Scholar 

  13. H. Bönneman and W. Brijoux, Surfactant-stabilized nanosized colloidal metals and alloys as catalyst precursors. In: Advanced Catalysts and Nanostructured Materials, edited by W. R. Moser (Academic Press, San Diego, 1996), pp. 165–196.

    Google Scholar 

  14. T. Teranishi and N. Toshima, Preparation, characterization and properties of bimetallic nanoparticles. In: Catalysis and Electrocatalysis at Nanoparticle Surfaces, edited by E. R. Savinova, et al. (Marcel Dekker, New York, 2002) in press.

    Google Scholar 

  15. N. Toshima, M. Harada, T. Yonezawa, K. Kushihashi, and K. Asakura, Structural analysis of polymer-protected Pd-Pt bimetallic clusters as dispersed catalysts by using extended X-ray absorption fine structure spectroscopy, J. Phys. Chem. 95, 7448–7453 (1991).

    Article  CAS  Google Scholar 

  16. N. Toshima, M. Harada, Y. Yamazaki, and K. Asakura, Catalytic activity and structural analysis of polymer-protected Au-Pd bimetallic clusters prepared by the simultaneous reduction of HAuCl4 and PdCl2, J. Phys. Chem. 96, 9927–9933 (1992).

    CAS  Google Scholar 

  17. Y. Mizukoshi, T. Fujimoto, Y. Nagata, R. Oshima, and Y. Maeda, Characterization and catalytic activity of core-shell structured gold/palladium bimetallic nanoparticles synthesized by the sonochemical method, J. Phys. Chem. B 104, 6028–6032 (2000).

    Article  CAS  Google Scholar 

  18. M.-L. Wu, D.-H. Chen, and T.-C. Huang, Synthesis of Au/Pd bimetallic nanoparticles in reverse micelles, Langmuir 17, 3877–3883 (2001).

    CAS  Google Scholar 

  19. T. Yonezawa, T. Tominaga, and N. Toshima, Novel Characterization of the structure of surfactants on nanoscopic metal clusters by a physico-chemical method, Langmuir 11, 4601–4604 (1995).

    Article  CAS  Google Scholar 

  20. M. T. Reetz, W. Helbig, S. A. Quaiser, U. Stimming, N. Breuer, and R. Vogel, Visualization of surfactants on nanostructured palladium clusters by a combination of STM and high-resolution TEM, Science 267, 367–369 (1995).

    CAS  Google Scholar 

  21. M. Harada, K. Asakura, and N. Toshima, Structural analysis of polymer-protected platinum/rhodium bimetallic clusters using extended X-ray absorption fine structure spectroscopy. Importance of microclusters for the formation of bimetallic clusters, J. Phys. Chem. 98, 2653–2662 (1994).

    Article  CAS  Google Scholar 

  22. M. P. Pileni, Nanosized particles made in colloidal assemblies, Langmuir 13, 3266–3276 (1997).

    Article  CAS  Google Scholar 

  23. X. Fu, Y. Wang, N. Wu, L. Gui, and Y. Tang, Shape-selective preparation and properties of oxalate-stabilized Pt colloid, Langmuir 18, 4619–4624 (2002).

    CAS  Google Scholar 

  24. H. Hirai, Y. Nakao, and N. Toshima, Colloidal rhodium in poly(vinylpyrrolidone) as hydrogenation catalyst for internal olefins, Chem. Lett., 545 (1978).

    Google Scholar 

  25. N. Toshima, M. Kuriyama, Y. Yamada, and H. Hirai, Colloidal platinum catalyst for light-induced hydrogen evolution from water. A particle size effect, Chem. Lett., 793–796 (1981).

    Google Scholar 

  26. H. Hirai, H. Chawanya, and N. Toshima, Colloidal palladium protected with poly(N-vinyl-2-pyrrolidone) for selective hydrogenation of cyclopentadiene, Reactive Polym. 3, 127–141 (1985).

    CAS  Google Scholar 

  27. N. Toshima and K. Hirakawa, Polmer-protected bimetallic nanocluster catalysts having core/shell structure for accelerated electron transfer in visible-light-induced hydrogen generation,Polym. J. 31, 1127–1132 (1999).

    Article  CAS  Google Scholar 

  28. T. Yonezawa and N. Toshima, Mechanistic consideration of formation of polymer-protected nanoscopic bimetallic clusters, J. Chem. Soc., Faraday Trans. 91, 4111–4119 (1995).

    CAS  Google Scholar 

  29. C.-R. Bian, S. Suzuki, K. Asakura, L. Ping, and N. Toshima, EXAFS studies on the structure of the PVP-stabilized Cu/Pd nanoclusters colloidally dispersed in solution, J. Phys. Chem. B, in press (2002).

    Google Scholar 

  30. K. Esumi, T. Tano, K. Torigoe, K. Meguro, Preparation and characterization of bimetallic palladium-copper colloids by thermal decomposition of their acetate compounds in organic solvents, Chem. Mater. 2, 564–567(1990).

    Article  CAS  Google Scholar 

  31. N. Toshima and Y. Wang, Preparation and catalysis of novel colloidal dispersions of copper/noble metal bimetallic clusters, Langmuir 10, 4574–4580 (1994).

    Article  CAS  Google Scholar 

  32. Y. Wang and N. Toshima, Preparation of Pd-Pt bimetallic colloids with controllable core/shell structures, J. Phys. Chem. B 101, 5301–5306 (1997).

    CAS  Google Scholar 

  33. N. Toshima, Y. Shiraishi, A. Shiotsuki, D. Ikenaga, and Y. Wang, Novel synthesis, structure and catalysis of inverted core/shell structured Pd/Pt bimetallic nanoclusters, Eur. Phys. J. D 16, 209–212 (2001).

    Article  CAS  Google Scholar 

  34. M. T. Reetz and G. Lohmer, Propylene carbonate stabilized nanostructured palladium clusters as catalysts in Heck reactions, Chem. Commun., 1921–1922 (1996).

    Google Scholar 

  35. Y. Li and M. A. El-Sayed, The effect of stabilizers on the catalytic activity and stability of Pd colloidal nanoparticles in the Suzuki reactions in aqueous solution, J. Phys. Chem. B 105, 8938–8943 (2001).

    CAS  Google Scholar 

  36. S. Klingelhöfer, W. Heitz, A. Greiner, S. Oestreich, S. Förster, and M. Antonietti, Preparation of palladium colloids in block copolymer micelles and their use for the catalysis of the Heck reaction, J. Am. Chem. Soc. 119, 10116–10120(1997).

    Google Scholar 

  37. S. Papp and I. Dékány, Structural properties of palladium nanoparticles embedded in inverse microemulsions, Colloid Polym. Sci. 279, 449–458 (2001).

    Article  CAS  Google Scholar 

  38. S.-W. Kim, S. U. Son, S. S. Lee, T. Hyeon, and Y. K. Chung, Colloidal cobalt nanoparticles: a highly active and reusable Pauson-Khand catalyst, Chem. Commun., 2212–2213 (2001).

    Google Scholar 

  39. M. Ohtake, M. Komiyama, H. Hirai, and N. Toshima, Effects of polymer support on substrate selectivity of covalently immobilized ultrafine rhodium particles as catalyst for olefin hydrogenation, Macromolecules 24, 5567–5572 (1991).

    Google Scholar 

  40. N. Toshima, Y. Shiraishi, and T. Teranishi, Effect of additional metal ions on the catalysis of polymer-stabilized metal nanoclusters, J. Mol. Catal. A, Chem. 177, 139–147 (2001).

    Article  CAS  Google Scholar 

  41. X. Yan, H. Liu, and J. Zhao, Improvement in the enantioselective hydrogenation of mehyl pyruvate over platinum clusters by addition of rare earth cations, Catal. Lett. 74, 81–83 (2001).

    Article  CAS  Google Scholar 

  42. X. Yan, M. Liu, H. Liu, K. Y. Liew, and N. Zhao, Metal complex effect on the hydrogenation of o-chloronitrobenzene over polymer-stabilized colloidal ruthenium clusters, J. Mol. Catal. A. Chem. 170, 201–208(2001).

    Article  Google Scholar 

  43. Y. Shiraishi, M. Hayashi, and N. Toshima, Preparation and catalysis of poly(β-cyclodextrin)-stabilized palladium nanoclusters, Abstracts of 9 Int’l. Symp. Macromol.-Metal Complexes, August 2001, New York, Poster Abstract No. 49.

    Google Scholar 

  44. H. Bönnemann and G. A. Braun, Enantioselective hydrogenations on platinum colloids, Angew. Chem. Int. Ed. Engl. 35, 1992–1995 (1996).

    Google Scholar 

  45. N. Toshima, T. Takahashi, and H. Hirai, Polymerized micelle-protected platinum clusters. Preparation and application to catalyst for visible light-induced hydrogen generation, J. Macromol. Sci. Cham. A25, 669–686 (1988).

    CAS  Google Scholar 

  46. N. Toshima and T. Takahashi, Colloidal dispersion of platinum and palladium cluster embedded in micelles. Preparation and application to catalysis for hydrogenation of olefins, Bull. Chem. Soc. Jpn. 65, 400–409(1992).

    CAS  Google Scholar 

  47. S.-W. Kim, M. Kim, W. Y. Lee, and T. Hyeon, Fabrication of hollow palladium spheres and their successful application to the recyclable heterogeneous catalyst for Suzuki coupling reactions, J. Am. Chem. Soc. 124, 7642–7643 (2002).

    CAS  Google Scholar 

  48. S. Hermans, R. Raja, J. M. Thomas, B. F. G. Johson, G. Sankar, and D. Gleeson, Solvent-free, low-temperature, selctive hydrgenation of polyenes using a bimetallic nanoparticle Ru-Sn catalyst, Angew. Chem. Int. Ed. Engl. 40, 1211–1215 (2001).

    Article  CAS  Google Scholar 

  49. H. Bönnemann, W. Brijoux, A. S. Tilling, and K. Siepen, Application of heterogeneous colloid catalysts for the preparation of fine chemicals, Topics in Catalysis 4, 217–227 (1997).

    Google Scholar 

  50. H. Bönnemann, U. Endruschat, B. Tesche, A. Rufínska, C. W. Lehmann, F. E. Wagner, G. Filoti, V. Pârulescu, and V. I. Pârulescu, An SiO2-embedded nanoscopic Pd/Au alloy colloid, Eur. J. Inorg. Chem. 819–822 (2000).

    Google Scholar 

  51. J. P. M. Niederer, A. B. J. Arnold, W. F. Hölderich, B. Spliethof, B. Tesche, M. Reetz, and H. Bönnemann, Noble metal nanoparticles incorporated in mesoporous hosts, Topics in Catalysis 18, 265–269 (2002).

    Article  CAS  Google Scholar 

  52. H. Bönnemann and N. Waldöfner, Preparation and characterization of three-dimensional Pt nanoparticle networks, Chem. Mater. 14, 1115–1120 (2002).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tokyo University of Science, Yamaguchi

    Naoki Toshima

  2. The former Science University of Tokyo in Yamaguchi, Onoda-shi, Yamaguchi, Japan, 756-0884

    Naoki Toshima

Authors
  1. Naoki Toshima
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Universidade de Vigo, Spain

    Luis M. Liz-Marzán

  2. University of Notre Dame, USA

    Prashant V. Kamat

Rights and permissions

Reprints and permissions

Copyright information

© 2004 Kluwer Academic Publishers

About this chapter

Cite this chapter

Toshima, N. (2004). Metal Nanoparticles for Catalysis. In: Liz-Marzán, L.M., Kamat, P.V. (eds) Nanoscale Materials. Springer, Boston, MA. https://doi.org/10.1007/0-306-48108-1_3

Download citation

  • DOI: https://doi.org/10.1007/0-306-48108-1_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4020-7366-3

  • Online ISBN: 978-0-306-48108-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation