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C. Zhang, Y. Ozawa, Y. Hayashi, K. Isobe, Oxidation of cyclohexene with t-butyl hydroperoxide catalyzed by transition metal oxide clusters, J. Organomet. Chem.. 373: C21 (1989); b) K. Isobe, A. Yagasaki, Cubane-type clusters as potential models for inorganic solid surfaces, Acc. Chem. Res. 26: 524 (1993); c) K. Takahashi, M. Yamaguchi, T. Shido, H. Ohtani, K. Isobe, M. Ichikawa, Molecular modeling of supported metal catalysts: SiO2-grafted [{(η 3-C 4 H 7)2 Rh}2 V 4 O 12] and [{Rh(C5Me5)}4V5O19] are catalytically active in the selective oxidation of propene to acetone, J. Chem. Soc. Chem. Commun. 1301 (1995); d) M. Ichikawa, W. Pan, Y. Imada, M. Yamaguchi, K. Isobe, T. Shido, Surface-grafted metal oxide clusters and metal carbonyl clusters in zeolite micropores; XAFS/FTIR/TPD characterization and catalytic behavior, J. Mol. Catal. A 107: 23 (1996).
K. Sawabe, N. Koga, K. Morokuma, Y. Iwasawa, An ab initio molecular orbital study on adsorption at the MgO surface. I. H2 chemisorption on the (MgO)4 cluster, J. Chem. Phys. 97: 6871 (1992); b) R. Cain, L.J. Matienzo, F. Emmi, Potential energy hypersurface for ammonia adsorbing onto nickel oxide, J. Phys. Chem. 94: 4985 (1990).
S. Takara, T. Nishioka, I. Kinoshita, K. Isobe, A novel organometallic oxide cluster with multi-valley sites: synthesis and structure of [NBu n 4]2[{(η5-C 5 Me 5)Rh}2 Mo 6 O 20-(OMe)2] and its framework transformations, Chem. Commun. 891 (1997).
S. Takara, S. Ogo, Y. Watanabe, K. Nishikawa, I. Kinoshita, K. Isobe, Direct observation by electrospray ionization mass spectrometry of [Cp*RhMo3O8(OMe)5]−, a key intermediate in the formation of the double-bookshelf-type oxide cluster [(Cp*Rh)2Mo6O20(OMe)2]2−, Angew. Chem. Int. Ed. Engl. 38: 3051 (1999).
J. W. Sam, X. J. Tang, J. Peisach, Electrospray mass spectrometry of iron bleomycin: demonstration that activated bleomycin is a ferric peroxide complex, J. Am. Chem. Soc. 116: 5250 (1994); b) J. Kim, Y. Dong, E. Larka, L. Que, Jr., Electrospray ionization mass spectral characterization of transient iron species of bioinorganic relevance, Inorg. Chem. 35: 2369 (1996); c) C. Hinderling, D.A. Plattner, P. Chen, Direct observation of a dissociative mechanism for C-H activation by a cationic iridium(III) complex, Angew. Chem. Int. Ed. Engl. 36: 243 (1997); d) D. Feichtinger, D.A. Plattner, Direct proof for O=Mnv(salen) complexes, Angew. Chem. Int. Ed. Engl. 36: 1718 (1997).
G. Süss-Fink, L. Plasseraud, V. Ferrand, H. Stoeckli-Evans, [(p-Pr i C 6 H 4 Me)4 Ru 4-Mo 4 O 16]: an amphiphilic organoruthenium oxomolybdenum cluster presenting a unique framework geometry, Chem. Commun. 1657 (1997); b) V. Artero, A. Proust, P. Herson, R. Thouvenot, P. Gouzerh, (η 6-Arene) ruthenium oxomolybdenum and oxotungsten clusters. Stereochemical non-rigidity of [{(η6-p-MeC 6 H 4 Pr i)Ru}4 Mo 4 O 16] and crystal structure of [{(η6-p-MeC 6 H 4 Pr i)Ru 4}4 W 2 O 10] Chem. Commun. 883 (2000).
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Nishikawa, K. et al. (2002). An Organorhodium Tungsten Oxide Cluster with a Windmill-Like Skeleton: Synthesis of [(Cp*Rh)4W4O16] and Direct Observation by ESI-MS of an Unstable Intermediate [Cp*RhClWO4]. In: Yamase, T., Pope, M.T. (eds) Polyoxometalate Chemistry for Nano-Composite Design. Nanostructure Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/0-306-47933-8_8
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DOI: https://doi.org/10.1007/0-306-47933-8_8
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