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Dynamics of Organometallic Oxides: From Synthesis and Reactivity to DFT Calculations

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Polyoxometalate Chemistry for Nano-Composite Design

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Conclusion

Several famillies of organometallic oxides have been described and especially the first carbene derivative of polyoxometallates. The concept of isolobality between some oxo and organometallic fragments has been extended to {Ru(arene)} 2+-containing species, which could turn out to be convenient precursors for catalytic purposes. Stereochemical non rigidity has been evidenced in the system [M 4 O 16 {Ru(arene)} 4 ], which is under further investigation.

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Authors and Affiliations

  1. Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie, 4 place Jussieu, Case 42, 75252, Paris Cedex 05, France

    V. Artero & A. Proust

  2. Chimie Quantique, Institut le Bel, Université Louis Pasteur, 4 rue Blaise Pascal, 67000, Strasbourg, France

    M.-M. Rohmer & M. Bénard

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Editors and Affiliations

  1. Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama, Japan

    Toshihiro Yamase

  2. Department of Chemistry, Georgetown University, Washington, DC, USA

    Michael T. Pope

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Artero, V., Proust, A., Rohmer, MM., Bénard, M. (2002). Dynamics of Organometallic Oxides: From Synthesis and Reactivity to DFT Calculations. In: Yamase, T., Pope, M.T. (eds) Polyoxometalate Chemistry for Nano-Composite Design. Nanostructure Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/0-306-47933-8_7

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