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Electron Spectroscopies Applied to Low-Dimensional Materials pp 283–315Cite as

Photoelectron Spectroscopy of Low-Dimensional Organic Systems

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Part of the book series: Physics and Chemistry of Materials with Low-Dimensional Structures ((PCMALS,volume 24))

Abstract

In the context of electronic devices based on so-called conjugated polymers, it is of critical importance to understand the effects of exposing the polymers to the conditions encountered during manufacture or the operation of the devices. It has been shown that photoelectron spectroscopy, in combination with quantum mechanical calculations, is well suited for characterisation of conjugated polymers, which in many cases behave as nearly one-dimensional systems. Applications of the combined experimental and theoretical approach are described, to illustrate the nature and the degree of information, which may be obtained. The approach is applied to studies of the chemical and electronic structure of the pristine polymer materials, as well as studies of chemical interactions and reactions. Examples discussed include the interaction of water molecules with a particular conjugated polymer, and chemical reactions which occur upon exposure to UV-light in the atmosphere. Moreover, discussions of the interaction of metal atoms with the surfaces of conjugated polymers, and nature of the fundamental charge storage states in conjugated polymers, are included.

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References

  1. C.K. Chiang, C.R. Fincher, Y.W. Park, A.J. Heeger, H. Shirakawa, E.J. Louis, S.C. Gao and A.G. MacDiarmid, Phys. Rev. Lett. 39, 1098 (1977).

    Article  ADS  Google Scholar 

  2. P.L. Burn, A.B. Holmes, A. Kraft, D.D.C. Bradley, A.R. Brown and R.H. Friend, J. Chem. Soc.; Chem. Commun. 1, 32 (1992).

    Article  Google Scholar 

  3. P.L. Burn, A. Kraft, D.R. Baigent, D.D.C. Bradley, A.R. Brown, R.H. Friend, R.W. Gymer, A.B. Holmes and R.W. Jackson, J. Am. Chem. Soc. 115, 10117 (1993).

    Article  Google Scholar 

  4. R.E. Gill, G.G. Malliaras, J. Wildeman and G. Hadziioannou, Adv. Mat. 6, 132 (1994).

    Article  Google Scholar 

  5. G. Grem, G. Leditzky, B. Ullrich and G. Leising, it Adv. Mat. 4, 36 (1992).

    Article  Google Scholar 

  6. G. Gustafsson, Y. Cao, G.M. Treacy, F. Klavetter, N. Colaneri and A.J. Heeger, Nature 357, 477 (1992).

    Article  ADS  Google Scholar 

  7. D.A. Halliday, P.L. Burn, D.D.C. Bradley, R.H. Friend, O.M. Gelsen, A.B. Holmes, A. Kraft, J.H.F. Martens and K. Pichler, Adv. Mat. 5, 40 (1993).

    Article  Google Scholar 

  8. I.D. Parker, J. Appl. Phys. 75, 16566 (1994).

    Google Scholar 

  9. J.L. Brédas and R. Silbey, eds., Conjugated Polymers (Kluwer Academic, Dordrecht 1991).

    Google Scholar 

  10. J.H. Burroughes, D.D.C. Bradley, A.R. Brown, R.N. Marks, K. Mackay, R.H. Friend, P.L. Burn and A.B. Holmes, Nature 347, 539 (1990).

    Article  ADS  Google Scholar 

  11. D. Braun and A.J. Heeger, Appl. Phys. Lett. 58, 1982 (1991).

    Article  ADS  Google Scholar 

  12. M. Berggren, A. Dodabalapur, R.E. Slusher and Z. Bao, Nature 389, 466 (1997).

    Article  ADS  Google Scholar 

  13. G.J. Denton, N. Tessler and R.H. Friend, 23rd International Conference on the Physics of Semiconductors, 3331 (1996).

    Google Scholar 

  14. G.J. Denton, N. Tessler, M.A. Stevens and R.H. Friend, Adv. Mat. 9, 547 (1997).

    Article  Google Scholar 

  15. M.A. Diaz-Garcia, F. Hide, B.J. Schwartz, M.R. Andersson, Q.B. Pei and A.J. Heeger, Synth. Met. 84, 455 (1997).

    Article  Google Scholar 

  16. R.H. Friend, G.J. Denton, J.J.M. Halls, N.T. Harrison, A.B. Holmes, A. Köhler, A. Lux, S.C. Moratti, K. Pichler, N. Tessler and K. Towns, Synth. Met. 84, 463 (1997).

    Article  Google Scholar 

  17. S.V. Frolov, M. Ozaki, W. Gellerman, Z.V. Vardeny and K. Yoshino, Jpn. J. Appl. Phys. 35, L1371 (1996).

    Article  ADS  Google Scholar 

  18. S.V. Frolov, W. Gellerman, Z.V. Vardeny, M. Ozaki and K.Y. Yoshino, Synth. Met. 84, 471 (1997).

    Article  Google Scholar 

  19. V.G. Kozlov, V. Bulovic, P.E. Burrows and S.R. Forrest, Nature 389, 362 (1997).

    Article  ADS  Google Scholar 

  20. F. Hide, M.A. Diaz.Garcia, B.J. Schwartz, M.R. Andersson, Q. Pei and A.J. Heeger, Science 277, 18336 (1996).

    Google Scholar 

  21. V.G. Kozlov, G. Parthasarathy, P.E. Burrows and S.R. Forrest, Appl. Phys. Lett. 72, 144 (1998).

    Article  ADS  Google Scholar 

  22. T. Tatsuma, T. Sotomura, T. Sato, D.A. Buttry and N. Oyama, J. Electrochem. Soc. 142, 182 (1995).

    Article  Google Scholar 

  23. T. Sotomura, T. Tatsuma and N. Oyama, J. Electrochem. Soc. 143, 3152 (1996).

    Article  Google Scholar 

  24. H. Sirringhaus, N. Tessler and R.H. Friend, Synth. Met., in press.

    Google Scholar 

  25. P.J. Kinlen, D.C. Silverman and C.R. Jeffreys, Synth. Met. 85, 1327 (1997).

    Article  Google Scholar 

  26. M. Fahlman, H. Guan, J.A.O. Smallfield and A.J. Epstein, Society of Plastic Engineers Annual Technical Conference: ANTEC 98, 1238 (1998)

    Google Scholar 

  27. B. Wessling, Materials and Corrosion 47, 439 (1996).

    Article  Google Scholar 

  28. T. Ito, H. Shirakawa and S. Ikeda, J. Polym. Sci. Polym. Chem. Ed. 12, 11 (1974).

    Google Scholar 

  29. M. Berggren, O. Inganäs, G. Gustafsson, J. Rasmusson, M.R. Andersson, T. Hjertberg and O. Wennerström, Nature 372, 444 (1994).

    Article  ADS  Google Scholar 

  30. H. Inokuchi, K. Seki and N. Sato, Physica Scripta T17, 93 (1987).

    Article  ADS  Google Scholar 

  31. W.R. Salaneck, CRC Critical Reviews in Solid State and Materials Science 12, 267 (1985).

    Article  Google Scholar 

  32. W.R. Salaneck, S. Stafström and J.L. Brédas, Conjugated Polymer Surfaces and Interfaces (Cambridge University Press, Cambridge, 1996).

    Book  Google Scholar 

  33. G. Wendin, Structure and Bonding 45, 1 (1981).

    Article  Google Scholar 

  34. J.L. Brédas, R.R. Chance, R. Silbey, G. Nicolas and P. Durand, J. Chem. Phys. 75, 255 (1981).

    Article  ADS  Google Scholar 

  35. J.M. André, J. Delhalle and J.L. Brédas, Quantum Chemistry Aided Design of Organic Polymers (World Scientific, Singapore, 1991).

    Book  Google Scholar 

  36. C.B. Duke, A. Paton, W.R. Salaneck, H.R. Thomas, E.W. Plummer, A.J. Heeger and A.G. MacDiarmid, Chem. Phys. Lett. 59, 14 (1978).

    Article  Google Scholar 

  37. W.R. Salaneck, Phys. Rev. Lett. 40, 60 (1978).

    Article  ADS  Google Scholar 

  38. N. Sato, K. Seki and H. Inokuchi, J. Chem. Soc. Faraday Trans. 2 77, 1621 (1981).

    Article  Google Scholar 

  39. M.J.S. Dewar and W. Thiel, J. Am. Chem. Soc. 99, 4899 (1977).

    Article  Google Scholar 

  40. M.J.S. Dewar and W. Thiel, J. Am. Chem. Soc. 99, 4907 (1977).

    Article  Google Scholar 

  41. M.J.S. Dewar, E.G. Zoebisch, E.F. Healy and J.J.P. Stewart, J. Am. Chem. Soc. 107, 3902 (1985).

    Article  Google Scholar 

  42. M. Lögdlund, W.R. Salaneck, F. Meyers, J.L. Brédas, G.A. Arbuckle, R.H. Friend, A.B. Holmes and G. Froyer, Macromolecules 26, 3815 (1993).

    Article  ADS  Google Scholar 

  43. M. Fahlman, M. Lögdlund, S. Stafström, W.R. Salaneck, R.H. Friend, P.L. Burn, A.B. Holmes, K. Kaeriyama, Y. Sonoda, O. Lhost, F. Meyers and J.L. Brédas, Macromolecules 28, 1959 (1995).

    Article  ADS  Google Scholar 

  44. N. Johansson, D.A. dos Santos, V. Parante, M. Lögdlund, U. Scherf, J.L. Bréda and W.R. Salaneck: to be published.

    Google Scholar 

  45. J.L. Baudour, H. Cailleau and W.B. Yelon, Acta Crystalogr. Sect. B 33, 1773 (1977).

    Article  Google Scholar 

  46. J.L. Baudour, Y. Delugeard and P. Rivet, Acta Crystallogr. Sect. B 34, 625 (1978).

    Article  Google Scholar 

  47. Y. Delugeard, J. Desuche and J.L. Baudour, Acta Crystalogr. Sect. B 32, 702 (1976).

    Article  Google Scholar 

  48. C. Kittel, introduction to Solid State Physics (John Wiley & Sons, New York, 1986).

    Google Scholar 

  49. K.Z. Xing, M. Fahlman, M. Lögdlund, D.A. dos Santos, V. Parante, R. Lazzaroni, J.L. Brédas, R.W. Gymer and W.R. Salaneck, Adv. Mater. 8, 971 (1996).

    Article  Google Scholar 

  50. D.A. dos Santos, V. Parente, R. Lazzaroni, K.Z. Xing, W.R. Salaneck and J.L. Brédas, Synth. Met. 85, 1131 (1997).

    Article  Google Scholar 

  51. J. Wanna, J.A. Menapace and E.R. Bernstein, J. Chem. Phys. 85, 1795 (1986).

    Article  ADS  Google Scholar 

  52. S.L. Mayo, B.D. Olafson and W.A. Goddard, J. Chem. Phys. 94, 8897 (1990).

    Article  Google Scholar 

  53. A. Köhler, Photocurrent spectroscopy on conjugated polymers (PhD Thesis, University of Cambridge, Cambridge, 1998).

    Google Scholar 

  54. D.A. dos Santos and J.L. Brédas, Synth. Met., in press.

    Google Scholar 

  55. A. Albini and M. Frecceri, in Handbook Organic Photochemistry and Photobiology (W.M. Horspool, Ed., CRC Press, New York, 1994) p. 346.

    Google Scholar 

  56. K.Z. Xing, N. Johansson, G. Beamson, D.T. Clark, J.L. Brédas and W.R. Salaneck, Adv. Mater. 9, 1027 (1997).

    Article  Google Scholar 

  57. F. Papadimitrakopoulos, M. Yan, L.J. Rothberg, H.E. Katz, E.A. Chandross and M.E. Galvin, Mol. Cryst. Liq. Cryst. 256, 663 (1994).

    Article  Google Scholar 

  58. M. Yan, L.J. Rothberg, F. Papadimitrikopoulos, M.E. Galvin and T.M. Miller, Phys. Rev. Lett. 73, 744 (1994).

    Article  ADS  Google Scholar 

  59. G. Beamson and D. Briggs, High Resolutiuon XPS of Organic Polymers (John Wiley & Sons Ltd, Chichester, 1992).

    Google Scholar 

  60. N. Johansson, F. Cacialli, K.Z. Xing, G. Beamson, D.T. Clark, R.H. Friend and W.R. Salaneck, Synth. Met. 92, 207 (1998).

    Article  Google Scholar 

  61. P. Bröms, N. Johansson, R.W. Gymer, S.C. Graham, R.H. Friend and W.R. Salaneck, Adv. Mat., in press.

    Google Scholar 

  62. J.C. Carter, I. Grizzi, S.K. Heeks, D.J. Lacey, S.G. Latham, P.G. May O. Ruizde-los Panos, K. Pichler, C. R. Towns and H. F. Wittman, Appl. Phys. Lett. 71, 34 (1997).

    Article  ADS  Google Scholar 

  63. K. Pichler, D.A. Halliday, D.C.C. Bradley, P.L. Burn, R.H. Friend and A.B. Holmes, J. of Phys.: Condens. Matter 5, 7155 (1993).

    Article  ADS  Google Scholar 

  64. T.P. Nguyen, V. Massardier, V.H. Tran and A. Guyot, Synth. Met. 55, 235 (1993).

    Article  Google Scholar 

  65. P. Dannetun, M. Lögdlund, W.R. Salaneck, C. Fredriksson, S. Stafström, A.B. Holmes, A. Brown, S. Graham, R.H. Friend and O. Lhost, Mol. Cryst. Liq. Cryst. 228, 43 (1993).

    Article  Google Scholar 

  66. E. Ettedgui, H. Razafitrimo, K.T. Park, Y. Gao and B.R. Hsieh, J. Appl. Phys. 75, 7526 (1994).

    Article  ADS  Google Scholar 

  67. E. Ettedgui, H. Razafitrimo, K.T. Park, Y. Gao and B.R. Hsieh, Surf. Int. An. 23, 89 (1995).

    Article  Google Scholar 

  68. K. Konstadinidis, F. Papadimitrakopoulos, M. Galvin and R.L. Opila, J. Appl. Phys. 77, 5642 (1995).

    Article  ADS  Google Scholar 

  69. T.P. Nguyen, P. Le Rendu, K. Amgaad, M. Cailler and V.H. Tran, Synth. Met. 72, 35 (1995).

    Article  Google Scholar 

  70. T.P. Nguyen and J.L. Mansot, Thin Solid Films 283, 135 (1996).

    Article  ADS  Google Scholar 

  71. B.R. Hsieh, E. Ettedgui and Y. Gao: 1996, Synth. Met. 78, 269.

    Article  Google Scholar 

  72. Y. Gao, K.T. Park and B.R. Hsieh, J. Chem. Phys. 97, 6991 (1992).

    Article  ADS  Google Scholar 

  73. Y. Gao, K.T. Park and B.R. Hsieh, J. Appl. Phys. 73, 7894 (1993).

    Article  ADS  Google Scholar 

  74. P. Dannetun, M. Fahlman, C. Fauquet, K. Kaerijama, Y. Sonoda, R. Lazzaroni, J.L. Brédas and W.R. Salaneck, in Organic Materials for Electronics: Conjugated Polymer Interfaces with Metals and Semiconductors (J.L. Brédas, W.R. Salaneck and G. Wegner, Eds., North Holland, Amsterdam, 1994) p. 133.

    Google Scholar 

  75. E. Ettedgui, H. Razafitrimo, Y. Gao and B.R. Hsieh, Synth. Met. 78, 247 (1996).

    Article  Google Scholar 

  76. T.P. Nguyen, P. Jonnard, F. Vergand, P.F. Staub, J. Thirion, M. Lapkowski and V.H. Tran, Synth. Met. 75, 175 (1995).

    Article  Google Scholar 

  77. T.P. Nguyen and S. de Vos, Vacuum 47, 1153 (1996).

    Article  Google Scholar 

  78. M. Fahlman, D. Beljonne, M. Lögdlund, P.L. Burn, A.B. Holmes, R.H. Friend, J.L. Brédas and W.R. Salaneck, Chem. Phys. Lett. 214, 327 (1993).

    Article  ADS  Google Scholar 

  79. M. Fahlrnan, P. Bröms, D.A. dos Santos, S.C. Moratti, N. Johansson, K. Xing, R.H. Friend, A.B. Holmes, J.L. Brédas and W.R. Salaneck, J. Chem. Phys. 102, 8167 (1995).

    Article  ADS  Google Scholar 

  80. G. Iucci, K. Xing, M. Lögdlund, M. Fahlman and W.R. Salaneck, Chem. Phys. Lett. 244, 139 (1995).

    Article  ADS  Google Scholar 

  81. P. Dannetun: Private communication.

    Google Scholar 

  82. W.R. Salaneck and J.L. Brédas, Adv. Mat. 8, 48 (1996).

    Article  Google Scholar 

  83. W.R. Salaneck and J.L. Brédas, Bull. Mat. Res. Soc. 22, 46 (1997).

    Google Scholar 

  84. M. Lögdlund and J.L. Brédas, J. Chem. Phys. 101, 4357 (1994).

    Article  ADS  Google Scholar 

  85. C. Fredriksson, R. Lazzaroni, J.L. Brédas, P. Dannetun, M. Lögdlund and W.R. Salaneck, Synth. Met. 55–57, 4632 (1993).

    Article  Google Scholar 

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  1. Department of Physics and Measurement Technology, Linköping University, S-581 83, Linköping, Sweden

    N. Johansson & W. R. Salaneck

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  1. N. Johansson
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  1. University of Cambridge, Cambridge, UK

    H. P. Hughes

  2. Göteborg University and Chalmers University of Technology, Göteborg, Sweden

    H. I. Starnberg

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© 2002 Kluwer Academic Publishers

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Johansson, N., Salaneck, W.R. (2002). Photoelectron Spectroscopy of Low-Dimensional Organic Systems. In: Hughes, H.P., Starnberg, H.I. (eds) Electron Spectroscopies Applied to Low-Dimensional Materials. Physics and Chemistry of Materials with Low-Dimensional Structures, vol 24. Springer, Dordrecht. https://doi.org/10.1007/0-306-47126-4_6

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