Skip to main content
SpringerLink
Log in

Inhomogeneous Broadening of Electronic Spectra of Dye Molecules in Solutions

  • Chapter
Topics in Fluorescence Spectroscopy

Part of the book series: Topics in Fluorescence Spectroscopy ((TIFS,volume 2))

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.00
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. N. G. Bakhshiev, Spectroscopy of Intermolecular Interactions, Nauka, Leningrad (1972).

    Google Scholar 

  2. E. Lippert, in: Organic Molecular Pholophysics (J. B. Birks, ed.), Vol. 2, pp. 1–31, Wiley-Interscience, London (1975).

    Google Scholar 

  3. N. Mataga, in: Molecular Interactions (H. Ratajczak and W. J. Orville-Thomas, eds.), Vol. 2, pp. 502–567, John Wiley & Sons, New York (1981).

    Google Scholar 

  4. A. N. Rubinov and V. I. Tomin, Bathochromic luminescence of organic dyes, Opt. Spektrosk. 29(2), 1082–1085 (1970).

    CAS  Google Scholar 

  5. W. C. Galley and R. M. Purkey, Role of heterogeneity of the solvation site in electronic spectra in solution, Proc. Natl. Acad. Sci. U.S.A. 67, 1116–1121 (1970).

    CAS  Google Scholar 

  6. K. I. Rudik and L. G. Pikulik, On the influence of exciting light on fluorescence spectra of phthalimide solutions, Opt. Spektrosk. 30(2), 275–278 (1971).

    CAS  Google Scholar 

  7. R. I. Personov, E. I. Alshits, and L. A. Bykovskaya, Fine structure arising in fluorescence spectra of complex molecules at laser excitation, Pis’ma Zh. Eksp. Tear. Fiz. 15, 609–612 (1972).

    CAS  Google Scholar 

  8. L. A. Gorokhovsky, R. A. Kaarli, and L. A. Rebane, Hole burning in merely electronic line contour in Shpolsky’s systems, Pis’ma Zh. Eksp. Tear. Fiz. 20(7), 474–479 (1974).

    Google Scholar 

  9. B. M. Kharlamov, R, I. Personov, and L. A. Bykovskaya, Stable gap in absorption spectra of solid solutions of organic molecules by laser irradiation, Opt. Commun. 12, 191–193 (1974).

    Article  CAS  Google Scholar 

  10. N. A. Nemkovich, V. I. Matseyko, A. N. Rubinov, and V. I. Tomin, Intermolecular up-relaxation in phthalimide polar solutions, Pis’ma Zh. Eksp. Teor. Fiz. 29(12), 780–783 (1979).

    CAS  Google Scholar 

  11. N. A. Nemkovich, V. I. Matseyko, and V. I. Tomin, Intermolecular up-relaxation in phthalimide solutions at excitation by frequency tuned dye laser, Opt. Spektrosk. 49(2), 274–283 (1980).

    CAS  Google Scholar 

  12. A. N. Rubinov and V. I. Tomin, Inhomogeneous Broadening of Organic Molecules in Rigid and Liquid Solutions, Institute of Physics, BSSR Acad. Sci., Minsk, Preprint N 348, p. 40 (1984).

    Google Scholar 

  13. I. M. Gulis and A. I. Komyak, Peculiarities of inductive-resonance energy transfer in the conditions of organic molecule electronic levels inhomogeneous broadening, Zh. Prikl. Spektrosk, 27(5), 841–845 (1977).

    CAS  Google Scholar 

  14. G. Weber, Fluorescence-polarization spectrum and electronic energy transfer in tyrosine, tryptophan and related compounds, Biochem. J. 75, 335–345 (1960).

    CAS  PubMed  Google Scholar 

  15. G. Weber and M. Shinitzky, Failure of energy transfer between identical aromatic molecules on excitation at the absorption spectrum long wave edge, Proc. Natl. Acad. Sci. U.S.A. 65, 823–830 (1970).

    CAS  Google Scholar 

  16. J. Eisinger, A. A. Lamola, J. W. Longworth, and W. B. Gratzer, Biological molecules in their excited states, Nature 226, 113–118 (1970).

    Article  CAS  PubMed  Google Scholar 

  17. E. N. Bodunov, E. V. Kolobkova, and V. L. Ermolaev, The Weber effect and inhomogeneous spectra broadening, Opt. Spektrosk. 44(2), 252–255 (1978).

    CAS  Google Scholar 

  18. B. D. Ryzhikov, L. V. Levshin, and N. R. Senatorova, On the nature of long wavelength concentrational shift of dye luminescence spectra, Opt. Spektrosk. 45(2), 282–287 (1978).

    CAS  Google Scholar 

  19. A. N. Rubinov, E. I. Zenkevich, N. A. Nemkovich, and V. I. Tomin, Directional energy transfer in photosynthetic pigment solution caused by orientational broadening of energy levels, Opt. Spektrosk. 50(6), 848–854 (1982).

    Google Scholar 

  20. A. N. Rubinov, E. I. Zenkevich, N. A. Nemkovich, and V. I. Tomin, Directed energy transfer due to orientational broadening of energy levels in photosynthetic pigment solutions, J. Lumin. 26, 367–376 (1982).

    CAS  Google Scholar 

  21. A. N. Rubinov, D. M. Gakamsky, N. A. Nemkovich, and V. I. Tomin, Dye Molecule Rotation in Solution Induced by Optical Excitation, Institute of Physics, BSSR Acad. Sci., Minsk, Preprint N 476, p. 10 (1987).

    Google Scholar 

  22. A. N. Rubinov, V. I. Tomin, and B. A. Bushuk, Kinetic spectroscopy of orientational states of solvated dye molecules in polar solutions, J. Lumin. 26, 377–391 (1982).

    CAS  Google Scholar 

  23. T. B. Tamm, Ya. V. Kikas, and A. E. Sirk, Measurement of nonhomogeneous distribution function of impurity centers by the method of double scanning of spectra, Zh. Prikl. Spektrosk. 24(3), 315–321 (1976).

    CAS  Google Scholar 

  24. G. Mourou and M. M. Malloy, The Stokes-shifted fluorescence risetime of dye molecules in solution, Chem. Phys. Lett. 45, 291–294 (1977).

    Google Scholar 

  25. C. V. Shank, E. P. Ippen, and O. Teschke, Sub-picosecond relaxation of large organic molecules in solution, Chem. Phys. Lett. 45, 291–294 (1977).

    Article  CAS  Google Scholar 

  26. J. Fünfschilling, Ha Biletationd dchrift. Inst. für Physik der Univ. Basel, 135 (1979).

    Google Scholar 

  27. R. I. Personov, E. P. Altshits, L. A. Bykovskaya, and B. M. Kharlamov, Fine structure of organic molecule luminescence spectra at laser excitation and the nature of rigid solution broad spectral bands, Zh. Eksp. Teor. Fiz. 65, 1826–1835 (1973).

    Google Scholar 

  28. A. A. Gorokhovskii, R. Kaarli, and L. A. Rebane, The homogeneous pure electronic linewidth in the spectrum of a N-phthalocyanine solution in N-octane at 5 K, Opt. Commun. 16, 282–284 (1976).

    CAS  Google Scholar 

  29. H. de Vries and D. A. Wiersma, Homogeneous broadening of optical transitions in organic mixed crystals, Phys. Rev. Lett. 36, 91–94 (1976).

    Google Scholar 

  30. I. Dombi, I. Kechkemety, and L. Kosma, On the fluorescent solution spectra profile, Opt. Spektrosk. 18, 10–14 (1965).

    Google Scholar 

  31. B. I. Stepanov and V. P. Gribkovsky, Introduction to the Theory of Luminescence, Izd. Akad. Nauk Byel. SSR, Minsk (1963).

    Google Scholar 

  32. A. N. Rubinov and V. I. Tomin, On the condition for realizability of Stepanov’s universal relation for complex molecules in solution, Opt. Spektrosk. 30(6), 859–862 (1971).

    CAS  Google Scholar 

  33. S. I. Vavilov, Light Microstructure, Collected papers in 2 volumes, Izv. Akad. Nauk SSSR 2, 999 (1952).

    Google Scholar 

  34. V. I. Tomin and A. N. Rubinov, Bathochromic luminescence of organic dyes in alcohol solutions and polymer matrices, Opt. Spektrosk. 32(2), 424–427 (1972).

    CAS  Google Scholar 

  35. V. I. Tomin, A. N. Rubinov, and V. F. Voronin, Quencher effect on fluorescence spectra of polar dye solutions, Opt. Spektrosk. 34(6), 1108–1111 (1973).

    CAS  Google Scholar 

  36. A. N. Rubinov, V. A. Zhivnov, and V. I. Tomin, Molecule spectrum fluorescence shift in the laser nonresonance frequency light field, Opt. Spektrosk. 35(4), 778–779 (1973).

    CAS  Google Scholar 

  37. A. N. Rubinov, V. I. Tomin, L. Kosma, I. Hilbert, and B. Nemet, Homogeneous and non-homogeneous broadening of dye α-and β-phosphorescene spectra, Ada Phys. Chem. Szeged 21(1,2), 11–18 (1975).

    CAS  Google Scholar 

  38. L. Kosma, N. A. Nemkovich, A. N. Rubinov, and V. I. Tomin, The anti-Stokes luminescence quantum yield drop and nonhomogeneous broadening of dye spectra in solution, Opt. Spektrosk. 59(2), 311–316 (1985).

    Google Scholar 

  39. V. L. Ermolaev, B. N. Bodunov, E. B. Sveshnikova, and T. A. Shakhverdov, Nonradiative Electronic Excitation Energy Transfer, Nauka, Leningrad (1977).

    Google Scholar 

  40. M. D. Galanin, Resonance excitation energy transfer in luminescent solutions, Trudy FIAN 12, 3–53 (1960).

    CAS  Google Scholar 

  41. T. Förster, Fluoreszenz Organischer Verbindungen, Göttingen Vandenhoeck and Ruprecht (1951).

    Google Scholar 

  42. I. M. Gulis, A. I. Komyak, and V. I. Tomin, Electronic excitation energy transfer in the conditions of complex organic molecules level nonhomogeneous broadening, Izv. Akad. Nauk SSSR, Ser. Fiz. 42, 307–312 (1978).

    CAS  Google Scholar 

  43. N. A. Nemkovich, I. M. Gulis, and V. I. Tomin, Excitation frequency dependence of directed nonradiative energy transfer efficiency in two-component rigid solutions, Opt. Spektrosk. 53(2), 239–244 (1982).

    CAS  Google Scholar 

  44. N. A. Nemkovich, A. N. Rubinov, and V. I. Tomin, Directed energy transfer in single-component dye solutions, Pis’ma Zh. Eksp. Tear. Fiz. 6(5), 270–273 (1980).

    CAS  Google Scholar 

  45. I. M. Gulis and A. I. Komyak, Inhomogeneous broadening effect on temporal characteristics of complex molecules luminescence at energy transfer, Vestn. Byel. Gos. Univ., Ser. I, 2, 3–6 (1980).

    Google Scholar 

  46. Yu. T. Mazurenko and V. S. Udaltzov, Fluorescence spectral relaxations, Opt. Spektrosk. 44(4), 714–719 (1978).

    CAS  Google Scholar 

  47. V. I. Tomin and A. N. Rubinov, Spectroscopy of nonhomogeneous configurational broadening in dye solutions, Zh. Prikl. Spektrosk. 35(2), 237–251 (1981).

    CAS  Google Scholar 

  48. N. G. Bakhshiev, Yu. T. Mazurenko, and I. V. Piterskaya, On the emission decay in various regions of molecule luminescence spectra in viscous solutions, Opt. Spektrosk. 21(5), 550–554 (1966).

    CAS  Google Scholar 

  49. W. Rapp, H. H. Klingenberg, and H. E. Lessing, A kinetic model for fluorescence solvatochromism, Ber. Bunsen-Ges. Phys. Chem. 75(9), 883–886 (1971).

    CAS  Google Scholar 

  50. W. Ware, P. P. Chow, and S. K. Lee, Time-resolved nanosecond emission spectroscopy: Spectral shifts due to solvent-solute relaxation, Chem. Phys. Lett. 2(6), 356–358 (1968).

    Article  CAS  Google Scholar 

  51. W. Ware, S. K. Lee, G. J. Brant, and P. P. Chow, Nanosecond time-resolved emission spectroscopy: Spectral shifts due to solvent-solute relaxation, J. Chem. Phys. 54(11), 4729–4737 (1971).

    Article  CAS  Google Scholar 

  52. B. A. Bushuk, A. N. Rubinov, and A. P. Stupak, Anti-Stokes excitation picosecond spectroscopy of dye polar solutions, Acta Phys. Chem. Szeged, 24(3), 387–390 (1978).

    Google Scholar 

  53. J. R. Lakowicz, Principles of Fluorescence Spectroscopy, Plenum Press, New York (1983).

    Google Scholar 

  54. V. L. Levshin, Photoluminescence of Liquid and Solid Substances, G1TTL, Moscow, Leningrad (1951).

    Google Scholar 

  55. Yu. A. Vladimirov and G. E. Dobretsov, Fluorescent Probes in Studies of Biological Membranes, Nauka, Moscow (1980).

    Google Scholar 

  56. M. G. Badea, R. P. Detoma, and L. Brand, Nanosecond relaxation process in liposomes, Biophys. J. 24, 197–212 (1978).

    CAS  PubMed  Google Scholar 

  57. E. D. Matayoshi and A. M. Kleinfeld, Emission wavelength dependent decay of the fluorescence probe N-phenyl-1-naphthylamine, Biochim. Biophys. Acta 644(2), 233–243 (1981).

    CAS  PubMed  Google Scholar 

  58. D. M. Gakamsky, A. P. Demchenko, N. A. Nemkovich, A. N. Rubinov, V. I. Tomin, and N. V. Shcherbatskaya, Laser Kinetic Spectroscopy of 1-PNA Probe in a Phospholipid Membrane, Institute of Physics, BSSR Acad. Sci., Preprint N 484, p. 29 (1987).

    Google Scholar 

  59. A. P. Demchenko, Ultraviolet Spectroscopy of Proteins, Springer-Verlag, Berlin (1986).

    Google Scholar 

  60. V. A. Gorodysky and A. A. Morachevsky, On the possibility of nonequilibrium solvation for chemical reactions’ intermediate states in two-component solvents, Dokl. Akad. Nauk SSSR 234(4), 855–858 (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physics of the B.S.S.R., Academy of Sciences, Minsk, 220602, USSR

    Nicolai A. Nemkovich, Anatolyi N. Rubinov & Vladimir I. Tomin

Authors
  1. Nicolai A. Nemkovich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Anatolyi N. Rubinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Vladimir I. Tomin
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Center for Fluorescence Spectroscopy Department of Biological Chemistry, University of Maryland School of Medicine, Baltimore, Maryland, USA

    Joseph R. Lakowicz

Rights and permissions

Reprints and permissions

Copyright information

© 2002 Kluwer Academic Publishers

About this chapter

Cite this chapter

Nemkovich, N.A., Rubinov, A.N., Tomin, V.I. (2002). Inhomogeneous Broadening of Electronic Spectra of Dye Molecules in Solutions. In: Lakowicz, J.R. (eds) Topics in Fluorescence Spectroscopy. Topics in Fluorescence Spectroscopy, vol 2. Springer, Boston, MA. https://doi.org/10.1007/0-306-47058-6_8

Download citation

  • DOI: https://doi.org/10.1007/0-306-47058-6_8

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-0-306-43875-2

  • Online ISBN: 978-0-306-47058-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation