Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Schlag, E. W. and Levine, R. D. (1992) Ionization, Charge Separation, Charge Recombination and Electron Transfer in Large Systems, J. Phys. Chem., 96, 10608–10616.
Remacle, F. and Levine, R. D. (1996) Unimolecular Dissociation from a Dense Set of States, J. Phys. Chem., 100, 7962–7971.
Schlag, E. W. and Levine, R. D. (1989) On the Unimolecular Dissociation of Large Molecules, Chem. Phys. Lett., 163, 523–530.
Bethe, H. A. and Salpeter, E. E. (1977) Quantum Mechanics of One-and Two-Electron Atoms, Plenum-Rosetta, New York.
Baranov, L. Y., Remacle, F. and Levine, R. D. (1996) Rydberg States about Dipolar Cores: The Quantum Dynamics of the Long Range Anisotropic Interaction, Phys. Rev., A 54, 4789–4801.
Even, U. (1997) Decay Dynamics of High Molecular Rydberg States, Phil. Trans.Roy. Soc, 355, 1539–1550.
Bahatt, D., Even, U. and Levine, R. D. (1993) Dynamics of High Rydberg States of Aromatic Molecules, J. Chem. Phys., 98, 1744–1747.
Müller-Dethlefs, K. and Schlag, E. W. (1991) High-Resolution Zero Kinetic Energy (ZEKE) Photoelectron Spectroscopy of Molecular Systems, Ann. Rev. Phys. Chem., 42, 109–136.
Merkt, F. and Softley, T. P. (1993) Rotational Line Intensities in Zero Kinetic Energy Photoelectron Spectroscopy (ZEKE-PES), Int. Rev. in Phys. Chem., 12, 205–239.
Muller-Dethlefs, K., Schlag, E. W., Grant, E. R., Wang, K. and McKoy, V. (1995) ZEKE Spectroscopy: High Resolution Spectroscopy with Photoelectrons, Adv. Chem. Phys., 90, 1–103.
Merkt, F. (1997) Molecules in High Rydberg States, Ann. Rev. Phys. Chem., 48, 675–709.
Schlag, E. W. (1997) ZEKE Spectroscopy, Adv. Chem. Phys., 101, 607–624.
Müller-Dethlefs, K. and Schlag, E. W. (1998) Chemical Applications of Zero Kinetic Energy (ZEKE) Photoelectron Spectroscopy, Angew. Chem. Int. Ed., 37, 1346–1374.
Merkt, F. and Softley, T. P. (1992) Rotationally Resolved Zero-Kinetic-Energy Photoelectron Spectrum of Nitrogen, Phys. Rev. A, 46, 302–314.
Wang, K. and McKoy, V. (1995) High-Resolution Photoelectron Spectroscopy of Molecules, Ann. Rev. Phys. Chem., 46, 275–304.
Remacle, F. and Vrakking, M. J. J. (1998) Decay Dynamics of the Predissociating High Rydberg States of NO, J. Phys.Chem., submitted.
Remacle, F. and Levine, R. D. (1998)On the Inverse Born-Oppenheimer Separation for High Rydberg States of Molecules, Int. J. Quant. Chem., 67, 85–100.
Dietrich, H. J., Muller-Dethlefs, K.M. and Baranov, L. Y. (1996) Fractional Stark State Selective Electric Field lonization of Very High-n Rydberg States of Molecules, Phys. Rev. Lett., 76, 3530–3532.
Molecular Applications of Quantum Defect Theory (1996) Jungen, C. (eds.), Institute of Physics Publishing, Bristol.
Klar, D., Harth, K., Ganz, J., Kraft, T., Ruf, M.-W., Hotop, H., Tsemekhman, V., Tsemekhman, K. and Amusia, M. Y. (1992) On the J-Dependence of the Odd (ns’J=0,1) Autoionization Resonances of the Rare Gases Ne, Ar, Kr, and Xe, Z Phys. D, 23, 101–113.
Gallagher, T. F. (1994) Rydberg Atoms, Cambridge University Press, Cambridge.
Scherzer, W. G., Selzle, H. L., Schlag, E.W. and Levine, R. D. (1994) Long Time Stability of Very High Rydberg States of Vibrationally Excited Molecules, Phys. Rev. Lett., 72, 1435–1438.
Pinnaduwage, L.A. and Zhu, Y. (1998) High Rydberg Fragment Formation via Core Dissociation of Superexcited Rydberg Molecules, J. Chem. Phys., 108, 6633–6637.
Krause, H. and Neusser, H. J. (1993) Dissociation Energies of Neutral and Ionic Benzene-Noble Gas Dimers by Pulsed Field Threshold lonization Spectroscopy, J. Chem. Phys.,99, 6278–6286.
Grebner, T. L., Unold, P.v. and Neusser, H. J. (1997) Dissociation of van der Waals Complexes in High Rydberg States Induced by Electric Fields, J. Phys. Chem., 101, 158–163.
Remacle, F. and Levine, R. D. (1997) Physical Aspects and Quantitative Theory of Time Resolved Spectroscopy of High Molecular Rydberg States, J. Chem. Phys., 107, 3382–3391.
Bordas, C., Brevet, P. F., Broyer, M., Chevaleyre, J., Labastie, P. and Perrot, J. P. (1988) Electric-Field-Hindered Vibrational Autoionization in Molecular Rydberg States, Phys. Rev. Lett., 60, 917–920.
Chupka, W.A. (1993) Factors Affecting Lifetimes and Resolution of Rydberg States Observed in Zero-Electron-Kinetic-Energy Spectroscopy, J. Chem. Phys., 98, 4520–4530.
Rabani, E., Baranov, L. Y., Levine, R.D. and Even, U. (1994) Dynamics of High Molecular Rydberg States in the Presence of a Weak DC Field, Chem. Phys. Lett., 221, 473–481.
Rabani, E., Levine, R.D., Mühlpfordt, A. and Even, U. (1995) Dynamics and Kinetics of Molecular High Rydberg States in the Presence of a DC field: An Experimental and Classical Computational Study, J. Chem. Phys., 102, 1619–1638.
Bixon, M. and Jortner, J. (1995) Dynamics of Ultrahigh Molecular Rydbergs in Weak Electrical Fields, J. Phys. Chem., 99, 7466–7472.
Remacle, F., Levine, R. D., Schlag, E. W., Selzle, H.L. and Held, A. (1996) Fields Effects on Long Living ZEKE States, J. Phys. Chem., 100, 15320–15327.
Mahon, C. R., Janik, G.R. and Gallagher, T. F. (1990) Field-Induced Rotational Autoionization of Li2, Phys. Rev. A, 41, 3746–3756.
Merkt, F., Fielding, H.H. and Softley, T. P. (1993) Electric Field Effects on Zero-Kinetic-Energy Photoelectron Spectra: an Explanation of Observed Trends, Chem. Phys. Lett., 202, 153–160.
Remacle, F. and Levine, R. D. (1996) Rotational Autoionization and Interseries Coupling of High Rydberg States by the Anisotropy of the Molecular Core: The Quantal Long Time Evolution, J. Chem. Phys., 105, 4649–4663.
Zhang, X., Smith, J.M. and Knee, J. L. (1993) Dynamics of High n Molecular Rydberg States with Application to Mass Analyzed Threshold Ionization Spectroscopy, J. Chem. Phys., 99, 3133–3136.
Merkt, F. and Zare, R. N. (1994) On the Lifetimes of Rydberg States Probed by Delayed Pulsed Field Ionization, J. Chem. Phys., 101, 3495–3505.
Vrakking, M. J., Fischer, I.. Villeneuve, D. M. and Stolow, A. (1995) Collisional Enhancement of Rydberg Lifetimes Observed in Vibrational Wavepacket Experiments, J. Chem. Phys., 103, 4538–4550.
Palm, H., Signorell, R. and Merkt, F. (1997) On the Role of Ions in Pulsed Field lonization Zero-Kinetic-Energy Photoelectron Spectroscopy, Phil. Trans. R Soc. London Ser. A, 325, 1551–1568.
Mühlpfordt, A., Even, U., Rabani, E. and Levine, R. D. (1995) Long Lifetimes of High Molecular Rydberg States in Crossed Magnetic and Electric Fields: An Experimental and Classical Computational Study, Phys. Rev. A, 51, 3922–3933.
Baranov, L. Y., Held, A., Selzle, H.L. and Schlag, E. W. (1998) Long Lived Rydberg ZEKE States Using Fast Programmed Electric Pulses, Chem. Phys. Lett., in press.
Remacle, F. and Levine, R. D. (1998) Prompt and Delayed Dissociation of Energy Rich Larger Molecules, J. Phys. Chem., submitted.
Nemeth, G. L, Ungar, H., Yeretzian, C., Selzle, H.L. and Schlag, E. W. (1994) High-Resolution Spectroscopy of Ag +2 via Long-Lived ZEKE States, Chem. Phys. Lett., 228, 1–8.
Kong, W. and Hepburn, J. W. (1994) Rotationally Resolved Threshold Photoelectron Spectroscopy of O2 Using Coherent XUV: Formation of Vibrationally Excited Ions in the Franck Condon Gap., Can. J. Phys.,72, 1284–1293.
Mackenzie, S. R., Halse, E. J., Gordon, E., Rolland, R. and Softley, T. P. (1996) Pulsed Field Ionization Spectroscopy of CO via the E1 Π State and NO via the B2Π State, Chem. Phys., 209, 127–141.
Matsui, H., Behm, J.M. and Grant, E. R. (1997) Photoselection and the Appearance of Franck-Condon-Forbidden Thresholds in the ZEKE Spectrum of NO2, J. Phys. Chem., 101, 6717–6722.
Laidler, K.J. (1987) Chemical Kinetics, Harper & Row, New York.
Even, U., Ben-Nun, M. and Levine, R. D. (1993) Time Evolution of Very High Rydberg States of Large Aromatic Molecules. A Kinetic Analysis, Chem. Phys. Lett., 210, 416–422.
Even, U., Levine, R.D. and Bersohn, R. (1994) Observation of Molecular Rydberg State Decay for n=100–200 J. Phys. Chem., 98, 3472.
Rabani, E., Levine, R.D. and Even, U. (1995) A Quantitative Model for the Dynamics of High Rydberg States of Molecules: The Iterated Map and its Kinetic Limit, Ber. Bunsenges. Phys. Chem., 99, 310–322.
Remacle, F. and Levine, R. D. (1997) Dynamic Bottlenecks and the Extreme Stability of High Rydberg States., ACH, Model in Chemistry, 134, 619–636.
Jungen, C. and Lefebvre-Brion, H. (1970) The Quadrupole Moment of NO+J. Mol. Spectr., 33, 520–524.
Jungen, C. and Miescher, E. (1969) Absorption Spectrum of the NO Molecule. IX. The Structure of the f Complexes, the Ionization Potential of NO, and the Quadrupole Moment of NO+, Can. J. Phys., 47, 1769–1787.
Bixon, M. and Jortner, J. (1996) The dynamics of Predissociating High Rydberg States of NO, J. Chem. Phys., 105, 1363–1382.
Vrakking, M. J. (1996) Lifetimes of Rydberg States in ZEKE Experiments. III. Calculation of the dc Electric Field Dependence of Predissociation Lifetimes of NO, J. Chem. Phys., 106, 7336–7347.
Vrakking, M. J. J. and Lee, Y. T. (1995) Lifetimes of Rydberg States in Zero-Electron-Kinetic-Energy Experiments. I. Electric Field Induced and Collisional Enhancement of NO predissociation Lifetimes, J. Chem. Phys., 102,8818–8832.
Alhassid, Y. and Levine, R. D. (1986) Transition Strength Fluctuations and the Onset of Chaotic Motion, Phys. Rev. Lett., 57, 2879–2882.
Remacle, F., Munster, M., Pavlov-Verevkin, V. B. and Desouter-Lecomte, M. (1990) Trapping in Competitive Decay of Degenerate States, Phys. Lett., A 145, 265–268.
Remacle, F. and Levine, R. D. (1996) Decay of High Rydberg States: A Paradigm for Intramolecular Dynamics in a Congested Bound Level Structure Coupled to a Continuum, J. Chem. Phys., 104, 1399–1414.
Feshbach, H. (1962) A Unified Theory of Nuclear Reactions. II, Ann. Phys. NY, 19, 287–313.
Levine, R. D. (1969) Quantum Mechanics of Molecular Rate Processes, Oxford University Press.
Ernst, W. E., Softley, T. P. and Zare, R. N. (1988) Stark Effect Studies in Xe Autoionizing Rydberg States Using a Tunable Extreme Ultraviolet Laser Source, Phys. Rev. A, 37, 4172–4183.
Remacle, F. and Levine, R. D. (1993) Prompt and Delayed Ionization of Large Molecules, Phys. Lett., A 173, 284–287.
Remacle, F., Desouter-Lecomte, M. and Lorquet, J. C. (1989) Extracting Laws of Decay in the Femto-picosecond Range from Autocorrelation Functions, J. Chem. Phys., 91, 4155.
Peskin, U., Reisler, H. and Miller, W. H. (1994) On the Relation Between Unimolecular Rates and Overlapping Resonances, J. Chem. Phys., 101, 9672–9680.
Someda, K., Nakamura, H. and Mies, F. H. (1994) Systematics of the Average Resonance Widths in Overlapping Resonance-Scattering and its Connection with RRKM Theory, Chem. Phys., 187, 195–209.
Mies, F. H. and Krauss, M. (1966) Time Dependent Behavior of Activated Molecules. High Pressure Unimolecular Rate Constant and Mass Spectra, J. Chem. Phys., 45, 4455–4468.
Miller, W. H. (1988) Effect of Fluctuations in State Specific Unimolecular Rate Constants on the Pressure Dependence of the Average Unimolecular Reaction Rate., J. Phys. Chem., 92, 4261–4263.
Neuhauser, R. G., Siglow, K. and Neusser, H. J. (1997) High n Rydberg Spectroscopy of Benzene: Dynamics, lonization Energy and Rotational Constant of the Cation., J. Chem. Phys., 106, 896–907.
Remacle, F., Even, U. and Levine, R. D. (1996) Time and Frequency Resolved ZEKE Spectroscopy, J. Phys. Chem, 100, 19735–19739.
Heller, E. J. (1981) The Semi-Classical Way to Molecular Spectroscopy, Acc. Chem. Res., 14, 368–375.
Pechukas, P. (1983) Remarks on “Quantum Chaos”, J. Phys. Chem., 88, 4823–4829.
Remacle, F. and Levine, R. D. (1997) Time and Frequency Resolved Spectra of High Molecular Rydberg States by Dynamical Computations, J. Chem. Phys., 107, 3392–3401.
Baranov, L. Y., Kris, R., Levine, R. D. and Even, U. (1994) On the Field Ionization Spectrum of High Rydberg States, J. Chem. Phys., 100, 186–196.
Held, A., Baranov, L. Y., Selzle, H. L. and Schlag, E. W. (1997) The Interactions of a ZEKE Electron with it’s Ionic Core: An experimental Measurement, Chem. Phys. Lett., 267, 318–322.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Kluwer Academic Publishers
About this chapter
Cite this chapter
Remacle, F., Levine, R.D. (1999). The Dynamics of Electron — Core Interaction in High Molecular Rydberg States. In: Sándorfy, C. (eds) The Role of Rydberg States in Spectroscopy and Photochemistry. Understanding Chemical Reactivity, vol 20. Springer, Dordrecht. https://doi.org/10.1007/0-306-46938-3_12
Download citation
DOI: https://doi.org/10.1007/0-306-46938-3_12
Publisher Name: Springer, Dordrecht
Print ISBN: 978-0-7923-5533-5
Online ISBN: 978-0-306-46938-1
eBook Packages: Springer Book Archive