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Technologies for Conversion Bio-Lubricant Production in Fatty Acids

  • Yu Cao
  • Ning Wang
  • Hongchen Fu
  • Fei You
  • Liangnian HeEmail author
Chapter
  • 13 Downloads

Abstract

In response to the increasing environmental pollution concern and depleting petroleum reserves, bio-lubricants have received wide attention in replacement of mineral oil. Vegetable oils can be used as potential source of environmentally friendly bio-lubricants because of their biodegradability, renewability, and excellent lubrication performance. Present chapter introduces properties of several raw oils as well as oil extraction methods. Besides, vegetable oils also have some limitations such as poor oxidative stability and low-temperature fluidity, which can be improved through various modification methods such as direct transesterification or selective hydrogenation. Technology for modification of raw oils has also been described. Additionally, additives have a significant influence on the performance of the lubricating oil. The characteristic and applicability of different commonly used additives in bio-lubricant have been summarized in this chapter. Castor oil has a higher viscosity and a lower viscosity index compared with other vegetable oils. This chapter in particular describes the development of production process for the castor-based biodegradable lubricant.

Keywords

Bio-based lubricant Vegetable oil Chemical modification Renewable resources Castor oil 

References

  1. 1.
    Adhvaryu A, Erhan SZ (2002) Epoxidized soybean oil as a potential source of high-temperature lubricants. Ind Crop Prod 15:247–254CrossRefGoogle Scholar
  2. 2.
    Asadauskas S, Perez JM, Duda JL (1997) Lubrication properties of castor oil-Potential basestock for biodegradable lubricants. Lube Eng 53:35–40Google Scholar
  3. 3.
    Bongfa B, Peter AA, Barnabas A, Adeoti MO (2015) Comparsion of lubricant properties of castor oil and commercial engine oil. J Tribol 5:1–11Google Scholar
  4. 4.
    Birová A, Pavlovicová A, Cvengros J (2002) Lubricating oils base from chemically modified vegetable oils. J Synth Lubr 18:292–299CrossRefGoogle Scholar
  5. 5.
    Canter N (2007) Special report: trends in extreme pressure additives. Tribol Lubr Technol 63:10–12Google Scholar
  6. 6.
    Charles D, WO 9835925 (1998) Method for preparing cleaved products from castor oil or derivatives thereof.Google Scholar
  7. 7.
    Chen B, Fang J, Dong L, Sun X, Wang J (2008) Enhancement of biodegradability of lubricants by biodegradation accelerants. Lubr Sci 20:311–317CrossRefGoogle Scholar
  8. 8.
    Chen J (1999) Refining mixed oil. China Oils Fats 24:25–26 (in Chinese)Google Scholar
  9. 9.
    Demirbas A (2005) Biodiesel production from vegetable oils by supercritical methanol. J Sci Ind Res India 64:858–865Google Scholar
  10. 10.
    Demirbas A (2006) Biodiesel production via non-catalytic SCF method and biodiesel fuel characteristics. Energ Convers Manage 47:2271–2282CrossRefGoogle Scholar
  11. 11.
    Fernández-Martinez J, Jimenez A, Dominguez J, Garcia JM, Garces R, Mancha M (1989) Genetic analysis of the high oleic acid content in cultivated sunflower (Helianthus annuus, L.). Euphytica 41:39–51CrossRefGoogle Scholar
  12. 12.
    Gilbert EE (1941) The unique chemistry of castor oil. J Chem Educ 18:338–341CrossRefGoogle Scholar
  13. 13.
    Grant I, Charne DG (1999) Brassica napus plant oil wherein the levels of oleic, alpha-linolenic, and saturated fatty acids are endogenously formed and simultaneously provided in an atypical highly beneficial distribution via genetic control. US Patent 5955623 21 Sep 1999Google Scholar
  14. 14.
    Grushcow J (2005) High oleic plant oils with hydroxy fatty acids for emission reduction. World Tribology Congress III, Washington, D.C. USA, 12–16 Sep 2005Google Scholar
  15. 15.
    Han H (2002) Viscosity index improvers for oil products. Sichuan Chem Ind 5:42–44 (in Chinese)Google Scholar
  16. 16.
    He LN, Dou XY, Ye F (2009) Phenol-free process for Sebacic acid production. CN 101367719 18 Feb 2009Google Scholar
  17. 17.
    He LN, Dou XY, Gao YS, Ye F (2011) Biomass-based energy: castor-derived biodegradable lubricate from laboratory to pilot plant. Prep Pap Am Chem Soc Div Fuel Chem 56:15–16Google Scholar
  18. 18.
    Kalam MA, Masjuki HH, Varman M, Liaquat AM (2011) Friction and wear characteristics of waste vegetable oil contaminated lubricants. Int J Mech Mater Eng 3:431–436Google Scholar
  19. 19.
    Kodali DR (2002) Process for modifying unsaturated triacylglycerol oils: resulting products and uses thereof. US Patent 6420322 16 July 2002Google Scholar
  20. 20.
    Kodali DR, Nivens SC (2001) Transesterified oils. US Patent 6278006 B1 21 Aug 2001Google Scholar
  21. 21.
    Koh MY, Ghazi TIM, Idris A (2014) Synthesis of palm based biolubricant in an oscillatory flow reactor (OFR). Ind Crop Prod 52:567–574CrossRefGoogle Scholar
  22. 22.
    Li B, Wang X, Liu W, Xue Q (2006) Tribochemistry and antiwear mechanism of organic-inorganic nanoparticles as lubricant additives. Tribol Lett 22:79–84CrossRefGoogle Scholar
  23. 23.
    Logan RL, Udeshi SV (2002) Method for preparing sebacic acid and octanol-2. US Patent 6392074B1 21 May 2002Google Scholar
  24. 24.
    Miller JF, Zimmerman DC, Vick BA (1987) Genetic control of high oleic acid content in sunflower oil 1. Crop Sci 27:923–926CrossRefGoogle Scholar
  25. 25.
    Mobarak HM, Niza Mohamad E, Masjuki HH, Kalam MA, Al Mahmud KAH, Habibullah M, Ashraful AM (2014) The prospects of biolubricants as alternatives in automotive applications. Renew Sust Energ Rev 33:34–43CrossRefGoogle Scholar
  26. 26.
    Naughton FC (1974) Production, chemistry, and commercial applications of various chemicals from castor oil. J Am Oil Chem Soc 51:65–71CrossRefGoogle Scholar
  27. 27.
    Ogunniyi DS (2006) Castor oil: a vital industrial raw material. Bioresour Technol 97:1086–1091CrossRefGoogle Scholar
  28. 28.
    Salih N, Salimon J, Yousif E, Abdullah BM (2013) Biolubricant basestocks from chemically modified plant oils: ricinoleic acid based-tetraesters. Chem Cent J 7:128–140CrossRefGoogle Scholar
  29. 29.
    Schneider MP (2006) Plant-oil-based lubricants and hydraulic fluids. J Sci Food Agr 86:1769–1780CrossRefGoogle Scholar
  30. 30.
    Silva JACD, Habert AC, Freire DMG (2013) A potential biodegradable lubricant from castor biodiesel esters. Lub Sci 25:53–61CrossRefGoogle Scholar
  31. 31.
    Sun LJ (2007) High yield cultivation techniques of hybrid castor. J Seed Ind Guid 4:20–21 (in Chinese)Google Scholar
  32. 32.
    Tao DH (2003) Ye B (2003) Modified castor lubricants and preparation methods. CN Pat 1424387:18 (in Chinese)Google Scholar
  33. 33.
    Todd LK, Brajendra KS, Kenneth MD, Sevim ZE (2007) Adsorption behavior of epoxidized fatty esters via boundary lubrication coefficient of friction measurements. Chem Eng Commun 194:1065–1077CrossRefGoogle Scholar
  34. 34.
    Tu G (2001) Refining technology of mixed castor oil. China oils and fats 26:40–43 (in Chinese)Google Scholar
  35. 35.
    Wagner H, Luther R, Mang T (2001) Lubricant base fluids based on renewable raw materials: their catalytic manufacture and modification. Appl Catal A-Gen 221:429–442CrossRefGoogle Scholar
  36. 36.
    Xiao CL (2000) Synthesis and properties of zinc dialkyl aromatic dithiophosphates. Chem Eng 1:14–15 (in Chinese)Google Scholar
  37. 37.
    Wu X, Zhang X, Yang S, Chen HG, Wang DP (2000) The study of epoxidized rapeseed oil used as a potential biodegradable lubricant. J Am Oil Chem Soc 77:561–563CrossRefGoogle Scholar
  38. 38.
    Yan XP, He BL, Zhang J, Liu HF (2005) Modification of transition metal cations to polymer-stabilized platinum colloidal clusters in enantioselective hydrogenation of methyl pyruvate. Chin J Polym Sci 23:393–399CrossRefGoogle Scholar
  39. 39.
    Zainal NA, Zulkifli NWM, Gulzar M, Masjuki HH (2018) A review on the chemistry, production, and technological potential of bio-based lubricants. Renew Sust Energ Rev 82:80–102CrossRefGoogle Scholar
  40. 40.
    Zeng X, Wu H, Yi H, Ren T (2007) Tribological behavior of three novel triazine dervivative as additives in rapeseed oil. Wear 262:718–726CrossRefGoogle Scholar
  41. 41.
    Zhang C, Liu H, Zhang P, Zhang Z (2014) Lubricant additives-colorful condiments. Chin J Nat 36:264–273 (in Chinese)Google Scholar
  42. 42.
    Zhu F, Fan W, Wang A, Zhu Y (2009) Tribological study of novel S-N style 1,3,4-thiadiazole-2-thione derivatives in rapeseed oil. Wear 266:233–238CrossRefGoogle Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2020

Authors and Affiliations

  • Yu Cao
    • 1
  • Ning Wang
    • 1
  • Hongchen Fu
    • 1
    • 2
  • Fei You
    • 1
  • Liangnian He
    • 1
    Email author
  1. 1.State Key LaboratoryInstitute of Elemento-Organic Chemistry, College of Chemistry, Nankai UniversityTianjinChina
  2. 2.College of Pharmacy, Nankai UniversityTianjinChina

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