Graphene for the Potential Renewable Energy Applications

  • Sayantan Sinha
  • Bibhu Prasad SwainEmail author
Part of the Green Energy and Technology book series (GREEN)


To combat the challenge of the upcoming energy crisis due to the shortage of fossil fuel and the global warming issue, it is evidently needed to use the non-conventional energy sources. Among the many sources, solar energy is the most popular alternative source since it is cheapest and convenient to harvest energy from sunlight. Although the conversion efficiency of the generally used conventional solar cells are not very good, in recent advancement of solar cell technology, the use of graphene has shown a 20% reduction in the reflectance of solar irradiation causing a significant increase in efficiency up to 20%. Based on the application of graphene, many different types of graphene solar cells have been developed. Basically, graphene is applied to photovoltaic cells as transparent electrode, catalytic counter electrode, Schottky junction, and electron or hole or both electron–hole transport layers. The overall power conversion efficiency also changes according to the application type. For example, with graphene/silicon solar cells, the highest efficiency obtained is 15.6% whereas in solar cell made with graphene quantum dot and P3HT, the efficiency achieved is up to 1.28%. With perovskite-based graphene solar cells, the conversion efficiency can be reached up to as high as 23.3%. So, various types of solar cells and what are the roles of graphene there are discussed in this chapter.


Renewable energy Graphene-based solar cell Graphene photovoltaic cell Green energy harvesting van der Walls Schottky diode Perovskite solar cell 


  1. 1.
    Bonaccorso F, Colombo L, Yu G, Stoller M, Tozzini V, Ferrari AC, Ruoff RS, Pellegrini V (2015) Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage. Science 347Google Scholar
  2. 2.
    Boehm HP, Clauss A, Fischer GO, Hofmann U (1962) Das Adsorptionsverhalten sehr dünner Kohlenstoff-Folien. Zaac 316:119–127Google Scholar
  3. 3.
    Mohammad R, Mohammad M, Kamyar HS, Mohammad S, Kazem MF (2012) Electronic properties of a dual-gated GNR-FET under uniaxial tensile strain. Microelectron Reliab 52:2579–2584CrossRefGoogle Scholar
  4. 4.
    Khalid A, Sampe J, Majlis BY, Mohamed MA, Chikuba T, Iwasaki T, Mizuta H (2015) Towards high performance graphene nanoribbon transistors (GNR-FETs). In: 2015 IEEE regional symposium on micro and nanoelectronics (RSM)Google Scholar
  5. 5.
    Akhavan ND, Jolley G, Membreno GU, Antoszewski J, Faraone L (2013) Study of uniformly doped graphene nanoribbon transistor (GNR) FET using quantum simulation. COMMAD 2012 (2013)Google Scholar
  6. 6.
    Varela-Rizo H, Martín-Gullón I, Terrones M (2012) Hybrid films with graphene oxide and metal nanoparticles could now replace indium tin oxide. ACS Nano 4565–4572Google Scholar
  7. 7.
    Arvidsson R, Kushnir D, Molander S, Sandén BA (2016) Energy and resource use assessment of graphene as a substitute for indium tin oxide in transparent electrodes. J Clean Prod 132:289–297 Google Scholar
  8. 8.
    Wang X, Zhi L, Müllen K (2007) Transparent, conductive graphene electrodes for dye-sensitized solar cells. Nano Lett 323–327Google Scholar
  9. 9.
    Li X, Zhu H, Wang K, Cao A, Wei J, Li C, Jia Y, Li Z, Li X, Wu D (2010) Graphene‐on‐silicon Schottky junction solar cells. Adv Mater 22:2743–2748Google Scholar
  10. 10.
    Allen MJ, Tung VC, Kaner RB (2010) Honeycomb carbon: a review of graphene. Chem Rev 110:132–145CrossRefGoogle Scholar
  11. 11.
    Tour JM (2014) Top-down versus bottom-up fabrication of graphene-based electronics. Chem Mater 26:163–171CrossRefGoogle Scholar
  12. 12.
    Feng T, Xie D, Lin Y, Zang Y, Ren T, Song R, Zhao H, Tian H, Li X, Zhu H, Liu L (2011) Graphene based Schottky junction solar cells on patterned silicon-pillar-array substrate. Appl Phys Lett 99Google Scholar
  13. 13.
    Park H, Rowehl JA, Kim KK, Bulovic V, Kong J (2010) Doped graphene electrodes for organic solar cells. Nanotechnology 21Google Scholar
  14. 14.
    Miao X, Tongay S, Petterson MK, Berke K, Rinzler AG, Appleton BR, Hebard AF (2012) High efficiency graphene solar cells by chemical doping. Nano Lett 12:2745–2750CrossRefGoogle Scholar
  15. 15.
    Song Y, Li X, Mackin C, Zhang X, Fang W, Palacios T, Zhu H, Kong J (2015) Role of interfacial oxide in high-efficiency graphene-silicon Schottky barrier solar cells. Nano Lett 15:2104–2110CrossRefGoogle Scholar
  16. 16.
    Linab XF, Zhangab ZY, Yuanab ZK, Li J, Xiao XF, Hongab W, Chenab XD, Yu DS (2016) Graphene-based materials for polymer solar cells. Chin Chem Lett 27:1259–1270CrossRefGoogle Scholar
  17. 17.
    Yong V, Tour JM (2010) Theoretical efficiency of nanostructured graphene-based photovoltaics. Small 6:313–318CrossRefGoogle Scholar
  18. 18.
    Yin Z, Sun S, Salim T, Wu S, Huang X, He Qi, Lam YM, Zhang H (2010) Organic photovoltaic devices using highly flexible reduced graphene oxide films as transparent electrodes. ACS Nano 4:5263–5268Google Scholar
  19. 19.
    Kittiratanawasin L, Hannongbua S (2016) The effect of edges and shapes on band gap energy in graphene quantum dots. Integr Ferroelectr 175:211–219CrossRefGoogle Scholar
  20. 20.
    Qin Y, Cheng Y, Jiang L, Jin X, Li M, Luo X, Liao G, Wei T, Li Q (2015) Top-down strategy toward versatile graphene quantum dots for organic/inorganic hybrid solar cells. ACS Sustain Chem Eng 3:637–644CrossRefGoogle Scholar
  21. 21.
    Bacon M, Bradley SJ, Nann T (2014) Graphene Quantum Dots. Particle 31:415–428Google Scholar
  22. 22.
    Shen J, Zhu Y, Yanga X, Li C (2012) Graphene quantum dots: emergent nanolights for bioimaging, sensors, catalysis and photovoltaic devices. Chem Com 48:3686–3699CrossRefGoogle Scholar
  23. 23.
    Zhu S, Zhang J, Tang S, Qiao C, Wang L, Wang H, Liu X, Li B, Li Y, Yu W, Wang X, Sun H, Yang B (2012) Surface chemistry routes to modulate the photoluminescence of graphene quantum dots: From fluorescence mechanism to up-conversion bioimaging applications. Adv Funct Mater 22:4732–4740CrossRefGoogle Scholar
  24. 24.
    Hamilton IP, Li B, Yan X, Li L (2011) Alignment of colloidal graphene quantum dots on polar surfaces. Nano Lett 11:1524–1529CrossRefGoogle Scholar
  25. 25.
    Liu F, Jang MH, Ha HD, Kim JH, Cho YH, Seo TS (2013) Facile synthetic method for pristine graphene quantum dots and graphene oxide quantum dots: origin of blue and green luminescence. Adv Mat 25:3657–3662CrossRefGoogle Scholar
  26. 26.
    Chen L, Guo CX, Zhang Q, Lei Y, Xie J, Ee S, Guai G, Song Q, Li CM (2013) Graphene quantum-dot-doped polypyrrole counter electrode for high-performance dye-sensitized solar cells. ACS Appl Mater Interfaces 5:2047–2052CrossRefGoogle Scholar
  27. 27.
    Liu T, Yu K, Gao L, Chen H, Wang M, Hao L, Li T, Hea H, Guo Z (2017) A graphene quantum dot decorated SrRuO3 mesoporous film as an efficient counter electrode for high-performance dye-sensitized solar cells. J Mater Chem A 5:17848–17855CrossRefGoogle Scholar
  28. 28.
    Zhou J, Ren Z, Li S, Liang Z, Sury C, Shen H (2018) Semi-transparent Cl-doped perovskite solar cells with graphene electrodes for tandem application. Mat Let 22:82–85CrossRefGoogle Scholar
  29. 29.
    Eperon GE, Stranks SD, Menelaou C, Johnston MB, Herza LM, Snaith HJ (2014) Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells. Energy Environ Sci 7:982–988CrossRefGoogle Scholar
  30. 30.
    Navrotsky A (1998) Energetics and crystal chemical systematics among ilmenite, lithium niobate, and perovskite structures. Chem Mater 10:2787–2793CrossRefGoogle Scholar
  31. 31.
    Meng L, You J, Yang Y (2018) Addressing the stability issue of perovskite solar cells for commercial applications. Nat Commun 9Google Scholar
  32. 32.
    Eperon GE, Stranks SD, Menelaou C, Johnston MB, Herz LM, Snaith HJ (2014) Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells. Energy Environ Sci 7:982–988CrossRefGoogle Scholar
  33. 33.
    Noel NK, Stranks SD, Abate A, Wehrenfennig C, Guarnera S, Haghighirad AA, Sadhanala A, Eperon GE, Pathak SK, Johnston MB, Petrozza A, Herz LM, Snaith HJ (2014) Lead-free organic–inorganic tin halide perovskites for photovoltaic applications. Energy Environ Sci 7:3061–3068CrossRefGoogle Scholar
  34. 34.
    Hao F, Stoumpos CC, Cao DH, Chang RPH, Kanatzidis MG (2014) Lead-free solid-state organic–inorganic halide perovskite solar cells. Nat Photonics 8:489–494CrossRefGoogle Scholar
  35. 35.
    Assmann E, Blaha P, Laskowski R, Held K, Okamoto S, Sangiovanni G (2013) Oxide heterostructures for efficient solar cells. Phys Rev Lett 110Google Scholar
  36. 36.
    Ke JCR, Lewis DJ, Walton AS, Spencer BF, O’Brien P, Thomas AG, Flavell WR (2018) Ambient-air-stable inorganic Cs2SnI6 double perovskite thin films via aerosol-assisted chemical vapour deposition. J Mater Chem A 6:11205–11214CrossRefGoogle Scholar
  37. 37.
    Kim K, Bae SH, Toh CT, Kim H, Cho JH, Whang D, Lee TW, Özyilmaz B, Ahn JH (2014) Ultrathin organic solar cells with graphene doped by ferroelectric polarization. ACS Appl Mater Interfaces 6:3299–3304CrossRefGoogle Scholar
  38. 38.
    Kumar A, Zhou C (2010) The race to replace Tin-Doped indium oxide: which material will win? ACS Nano 4:11–14CrossRefGoogle Scholar
  39. 39.
    Ni GX, Zheng Y, Bae S, Tan CY, Kahya O, Wu J, Hong BH, Yao K, Özyilmaz B (2012) Graphene-ferroelectric hybrid structure for flexible transparent electrodes. ACS Nano 6:3935–3942CrossRefGoogle Scholar
  40. 40.
    Bae S, Kim H, Lee Y, Xu X, Park JS, Zheng Y, Balakrishnan J, Lei T, Kim HR, Song YI, Kim YJ, Kim KS, Özyilmaz B, Ahn JH, Hong BH, Iijima S (2010) Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nat Nanotechnol 5:574–578CrossRefGoogle Scholar
  41. 41.
    Kasry A, Kuroda MA, Martyna GJ, Tulevski GS, Bol AA (2010) Chemical doping of large-area stacked graphene films for use as transparent, conducting electrodes. ACS Nano 4:3839–3844CrossRefGoogle Scholar
  42. 42.
    Jung YU (2012) Organic photovoltaic devices with low resistance multilayer graphene transparent electrodes. J Vac Sci Technol A 30Google Scholar
  43. 43.
    Hsu CL, Lin CT, Huang JH, Chu CW, Wei KH, Li LJ (2012) Layer-by-layer graphene/TCNQ stacked films as conducting anodes for organic solar cells. ACS Nano 6:5031–5039CrossRefGoogle Scholar
  44. 44.
    Li X, Chen W, Zhang S, Wu Z, Wang P, Xu Z, Chena H, Yin W, Zhong H, Lin S (2015) 18.5% efficient graphene/GaAs van der Waals heterostructure solar cell. Nano Energy 16:310–319Google Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2020

Authors and Affiliations

  1. 1.Department of PhysicsNational Institute of Technology ManipurImphalIndia

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