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Electrochemical Corrosion Properties of Ti46Zr20V12Cu5Be17 In Situ Metallic Glass Matrix Composites in HCl Solutions

  • Fan YangEmail author
Conference paper
Part of the Springer Proceedings in Physics book series (SPPHY, volume 217)

Abstract

The electrochemical corrosion properties of in situ Ti46Zr20V12Cu5Be17 metallic glass matrix composites (MGMCs) in HCl solutions have been investigated. The EDS results show that the decrease of protection properties of passive film is caused by reduction of element content of Ti and Zr in passive film, leading to the acceleration of corrosion rate with the increase in of HCl solution concentration. The SEM results indicate that a galvanic effect between matrix and crystalline results in prior dissolution of matrix. With the increasing of Cl ion concentration, the corrosion-induced damage on sample surface augments and crystalline dendrites are completely revealed.

Keywords

In situ MGMCs Corrosion behavior Passive film 

References

  1. 1.
    A. Inoue, Stabilization of metallic supercooled liquid and bulk amorphous. Acta Mater. 48, 279–306 (2000)CrossRefGoogle Scholar
  2. 2.
    C.C. Hays, C.P. Kim, W.L. Johnson, Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions. Phys. Rev. Lett. 84, 2901–2904 (2000)CrossRefGoogle Scholar
  3. 3.
    D.C. Hofmann, J.Y. Suh, A. Wiest, G. Duan, M.L. Lind, M.D. Demetriou, W.L. Johnson, Development of tough, low density titanium-based bulk metallic glass matrix composites with tensile ductility. Proc. Natl. Acad. Sci. U.S.A. 105, 20136–20140 (2008)CrossRefGoogle Scholar
  4. 4.
    D.C. Hofmann, J.Y. Suh, A. Wiest, G. Duan, M.L. Lind, M.D. Demetriou, W.L. Johnson, Designing metallic glass matrix composites with high toughness and tensile ductility. Nature 451, 1085–1089 (2008)CrossRefGoogle Scholar
  5. 5.
    J.W. Qiao, Y. Zhang, G.L. Chen, Fabrication and mechanical characterization of a series of plastic Zr-based bulk metallic glass matrix composites. Mater. Des. 30, 3966–3971 (2009)CrossRefGoogle Scholar
  6. 6.
    J.W. Qiao, A.C. Sun, E.W. Huang, Y. Zhang, P.K. Liaw, C.P. Chuang, Tensile deformation micromechanisms for bulk metallic glass matrix composites: from work-hardening to softening. Acta Mater. 59, 4126–4137 (2011)CrossRefGoogle Scholar
  7. 7.
    P.F. Gostin, R. Sueptitz, A. Gebert, U. Kuehn, L. Schultz, Comparing the corrosion behaviour of Zr66/Ti66–Nb13Cu8Ni6.8Al6.2 bulk nanostructure-dendrite composite. Intermetallics 16, 1179–1184 (2008)CrossRefGoogle Scholar
  8. 8.
    M.R. Debnath, D.H. Kim, E. Fleury, Dependency of the corrosion properties of in situ Ti-based BMG matrix composites with the volume fraction of crystalline phase. Intermetallics 22, 255–259 (2012)CrossRefGoogle Scholar
  9. 9.
    M.R. Debnath, H.J. Chang Kim, E. Fleury, Effect of group 5 elements on the formation and corrosion behavior of Ti-based BMG matrix composites reinforced by icosahedral quasi crystalline phase. J. Alloy. Compd. 612, 134–142 (2014)CrossRefGoogle Scholar
  10. 10.
    J.W. Qiao, T. Zhang, F.Q. Yang, P.K. Liaw, S. Pauly, B.S. Xu., A tensile deformation model for in situ dendrite/metallic glass matrix composites. Sci. Rep.  https://doi.org/10.1038/srep02816
  11. 11.
    C.L. Qin, J.J. Oak, N. Ohtsu, K. Asami, A. Inoue, XPS study on the surface films of a newly designed Ni-free Ti-based bulk metallic glass. Acta Mater. 55, 2057–2063 (2007)CrossRefGoogle Scholar
  12. 12.
    R. Kaufmann, H. Klewe-Nebenius, H. Moers, G. Pfennig, H. Jenett, H. Ache, XPS and AES investigations of the reaction behaviour of iodine with zircaloy-4 surfaces. Surf. Interface Anal. 11, 502–509 (1998)CrossRefGoogle Scholar
  13. 13.
    M.M. Lohrengel, Thin anodic oxide layers on aluminium and other valve metals. Mater. Sci. Eng. 11, 243–294 (1993)CrossRefGoogle Scholar
  14. 14.
    J.R. Birch, T.D. Burleigh, Oxides formed on titanium by polishing, etching, anodizing, or thermal oxidizing. Corrosion 56, 1233–1241 (2000)CrossRefGoogle Scholar
  15. 15.
    A. Gebert, U. Kuehn, S. Baunack, N. Mattern, L. Schultz, Pitting corrosion of zirconium-based bulk glass-matrix composites. Mater. Sci. Eng. A 415, 242–249 (2006)CrossRefGoogle Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2019

Authors and Affiliations

  1. 1.Beijing Beiye Functional Materials CorporationHaidian District, BeijingChina

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