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Synthesis of Polyesters I: Hydrolase as Catalyst for Polycondensation (Condensation Polymerization)

  • Shiro KobayashiEmail author
  • Hiroshi Uyama
Chapter
Part of the Green Chemistry and Sustainable Technology book series (GCST)

Abstract

Synthesis of polyesters via enzymatic polymerization is described comprehensively in up-to-dated review manner, in which the polymerization is of polycondensation type using hydrolases mainly lipase as catalyst. First, characteristics of lipase catalysis are discussed: catalyst nature for green polymer chemistry including the catalysis mechanism, immobilization of lipases, role of surfactants for lipase catalysis, and so forth. Then, the lipase-catalyzed polycondensation synthesis of polyesters is argued according to the types of polymerization reactions: via dehydration of α- and ω-oxyacids and of dicarboxylic acids, via transesterification using carboxylic acid esters, and via ring-opening addition-condensation polymerization using cyclic anhydrides or cyclic esters as a monomer component. Other polymers like polyamides, polyamines, polycarbonates, and sulfur-containing polymers were synthesized by lipase catalyst. These reaction results indicate that lipase catalysts induce various polycondensation reactions to produce a variety of new polyesters. Further, protease which catalyzes primarily the peptide bond cleavage and bond formation catalyzed also the polyester production via polycondensation.

Keywords

Lipase catalyst Polyester synthesis Polycondensation Dehydration polymerization Transesterification polymerization Ring-opening addition-condensation polymerization Protease catalyst 

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© Springer Nature Singapore Pte Ltd. 2019

Authors and Affiliations

  1. 1.Kyoto University, Yoshida-honmachi, Sakyo-kuKyotoJapan
  2. 2.Department of Applied Chemistry, Graduate School of EngineeringOsaka UniversitySuitaJapan

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