Treatment and Recycling of Wastewater from Oil Refinery/Petroleum Industry

  • Shailja Singh
  • Shikha
Part of the Applied Environmental Science and Engineering for a Sustainable Future book series (AESE)


Petroleum refinery effluents (PRE) are generally the wastes generated from industries primarily engaged in refining crude oil, manufacturing fuels, lubricants and petrochemical intermediates. These effluents or wastewater, generated, are considered as a major source of aquatic environmental pollution. The effluents are mainly composed of oil, grease and many other toxic organic compounds. The process of crude oil refining consumes large volume of water. Consequently, significant volume of wastewater is generated. The requirement of water depends upon on the size, crude products and complexity of operation. Petroleum refining units need water for distillation, desalting, thermal cracking, catalytic and treatment processes in order to produce useful products such as LPG (Liquefied Petroleum Gas), gasoline, asphalt, diesel, jet fuel, petroleum feedstock etc. Wastewater generated through petroleum refineries contains various hydrocarbons. It has been estimated that the demand for world oil is expected to rise to 107 mbpd (million barrels per day) in the next two decades. By 2030 oil will account for 32% of the world’s energy supply. The increasing demand of oil clearly shows that effluents produced from the oil industry will continue to be produced and discharged into the water bodies. The pollutants found in the effluent are seriously toxic and hazardous to the environment. Techniques used for effluent treatment include adsorption, coagulation, chemical oxidation, biological techniques as well as contemporary technologies like membranes and microwave-assisted catalytic wet air oxidation and Advanced oxidation processes (AOP) like heterogeneous photo-catalytic degradation which is based on its potential to completely mineralize the organic effluents beside being cost effective, readily available and the catalyst used itself is non-toxic in nature. The review provides a detailed description on nature of effluent or wastewater produced from the oil refinery units, its discharge into the water bodies, toxicological effects of the effluent on terrestrial and aquatic ecosystem and the various treatment technologies designed for the treatment and recycling of wastewater generated during operation.


Oil refinery Petroleum industry Petrochemical intermediates Advanced oxidation processes (AOP) Crude oil refining 


  1. Alade TJ, Suleyman AM, Karim MLA et al (2011) Removal of oil and grease as emerging pollutants of concern in wastewater stream. IIUM Eng J 12(4):161–169Google Scholar
  2. Aljuboury DA, Palaniandy P, Aziz HBA, Feroz S (2015) Treatment of petroleum wastewater using combination of solar photo-two catalyst TiO2 and photo-Fenton process. J Environ Chem Eng 3(2):1117–1124CrossRefGoogle Scholar
  3. Al-Ani FH (2012) Treatment of oily wastewater produced from old processing plant of north oil company. Tikrit J Eng Sci 19(1):23–34Google Scholar
  4. Altas L, Buyukgungor H (2008) Sulfide removal in petroleum refinery wastewater by chemical precipitation. J Hazard Mater 53:462–469CrossRefGoogle Scholar
  5. Arthur JD, Langhus BG, Patel C (2005) Technical summary of oil & gas produced water treatment technologies NETL, Tulsa, Okla, USA. Accessed 28 June 2017
  6. Bagajewicz M (2000) A review of recent designing procedures for water networks in refineries and process plants. Comput Chem Eng 24:2093–2113CrossRefGoogle Scholar
  7. Batelle CD (2000) Mushrooms: higher macrofungi to clean up the environment. Batelle Environmental IssuesGoogle Scholar
  8. Benyahia F, Abdulkarim M, Embaby A et al (2006) Refinery wastewater treatment: a true technological challenge. The seventh annual U.A.E. University research conference, Al Ain, UAE, 22–25 April 2006Google Scholar
  9. Brar SK, Verma M, Surampalli RY et al (2006) Bioremediation of hazardous wastes: a review. Pract Period Manag 10:59–72Google Scholar
  10. Bush KE (1980) Refinery wastewater treatment and reuse. Originally published April 12, 1976, Industrial wastewater and solid waste engineering. In: Vincent C (ed) and the Staff of Chemical Engineering, Chemical Engineering McGrawHill Pub. Co., New York, pp 13–18Google Scholar
  11. Chanthamalee J, Wongchitphimon T, Luepromchai E (2013) Treatment of oily bilge water from small fishing vessels by PUF-immobilized Gordonia sp. JC11. Water Air Soil Pollut 224:1601CrossRefGoogle Scholar
  12. Chavan A, Mukherji S (2008) Treatment of hydrocarbon-rich wastewater using oil degrading bacteria and phototrophic microorganisms in rotating biological contactor: effect of N:P ratio. J Hazard Mater 154(1–3):63–72CrossRefGoogle Scholar
  13. Chen C, Huang X, Lei C, Zhang TC, Wu W (2013) Effect of organic matter strength on anammox for modified greenhouse turtle breeding wastewater treatment. Bioresour Technol 148:172–179CrossRefGoogle Scholar
  14. Coelho A, Castro AV, Dezotti M et al (2006) Treatment of petroleum refinery sourwater by advanced oxidation processes. J Hazard Mater 137:178–184CrossRefGoogle Scholar
  15. Da-Cruz GF, Dos Santos Neto EV, Marsaioli AJ (2008) Petroleum degradation by aerobic microbiota from the Pampo Sul Oil Field, Campos Basin, Brazil. Org Geochem 39(8):1204–1209CrossRefGoogle Scholar
  16. Demirci S, Erdogan B, Ozcimder R (1997) Wastewater treatment at the petroleum refinery Kirikkale Turkey using some coagulant and Turkiskh clays as coagulant aids. Water Res 32:3495–3499CrossRefGoogle Scholar
  17. Doggett T, Rascoe A (2009) Global energy demand seen up 44 percent by 2030. Accessed 20 Aug 2017
  18. Doran MD, Boyle WC (1979) Phosphorus removal by activated algae. Water Res 13:805–812CrossRefGoogle Scholar
  19. Dumore NS, Mukhopadhyay M (2012) Removal of oil and grease using immobilized triacylglycerin lipase. Int Biodeterior Biodegrad 68:65–70CrossRefGoogle Scholar
  20. El-Naas MH, Al-Zuhair S, Al-Lobaney A et al (2009) Assessment of electrocoagulation for the treatment of petroleum refinery wastewater. J Environ Manag 91:180–185CrossRefGoogle Scholar
  21. El-Naas M, Al-Zuhair S, Alhaija M (2010) Removal of phenol from petroleum refinery wastewater through adsorption on date-pit activated carbon. Chem Eng J 162:997–1005CrossRefGoogle Scholar
  22. Environmental Protection Agency (1997) Waste water treatment manuals, primary, secondary and tertiary treatment. Environmental Protection Agency, ArdcavanGoogle Scholar
  23. European Commission, Joint Research Center (2013) Best Available Techniques (BAT) Reference document for the refining of mineral oil and gas, industrial emissions directive 2010/75/EU (Integrated pollution prevention and control). Joint Research Center, Institute for Prospective Technological Studies Sustainable Production and Consumption Unit European IPPC BureauGoogle Scholar
  24. Fakhru’l-Razi A, Pendashteh A, Abdullah LC (2009) Review of technologies for oil and gas produced water treatment. J Hazard Mater 170(2–3):530–551CrossRefGoogle Scholar
  25. Fernández-Luqueño F, Valenzuela-Encinas C, Marsch R et al (2010) Microbial communities to mitigate contamination of PAHs in soil—possibilities and challenges: a review. Environ Sci Pollut Res 10:11–30Google Scholar
  26. Goldblatt ME, Gucciardi JM, Huban CM et al (2014) New polyelectrolyte emulsion breaker improves oily wastewater cleanup at lower usage rates. Technical Paper, GE Water and Power, Water & Process Technologies, General Electric Company, pp 1–6Google Scholar
  27. Gurtekin E (2014) Sequencing batch reactor, Akademik Platform, ISEM 2014 Adiyaman e TurkeyGoogle Scholar
  28. Hammouda O, Gaber, Abdet-Raouf N (1994) Microalgae and wastewater treatment. Ecotoxicol Environ Saf 31:205–210CrossRefGoogle Scholar
  29. Harry MF (1995) Industrial pollution handbook. McGraw Hill, New YorkGoogle Scholar
  30. Hidalgo D, Martín-Marroquín JM, Sastre E (2013) Single-phase and two-phase anaerobic co-digestion of residues from the treatment process of waste vegetable oil and pig manure. Bioenergy Res 7(2):670–680CrossRefGoogle Scholar
  31. Ho SW, Cheung KK, Fung WC (2014) Sustainable wastewater treatment—ways to achieve energy neutrality. HKIE Trans 21(4):240–252CrossRefGoogle Scholar
  32. Ibrahim S, Ang HM, Wang S (2012) Adsorptive separation of emulsified oil in wastewater using biosorbents. Asia-Pacific J Chem Eng 7(S2):S216–S221CrossRefGoogle Scholar
  33. IPIECA (2010) Petroleum refining water/wastewater use and management. IPIECA, LondonGoogle Scholar
  34. Ishak S, Malakahmad A, Isa MH (2012) Refinery wastewater biological treatment: a short review. J Sci Ind Res 71:251–256Google Scholar
  35. Jafarinejad Sh (2015) Investigation of advanced technologies for wastewater treatment from petroleum refinery processes. In: 2nd e-Conference on Recent Research in Science and Technology, Kerman, Iran, Summer 2015Google Scholar
  36. Khondee N, Tathong S, Pinyakong O et al (2012) Airlift bioreactor containing chitosan-immobilized Sphingobium sp. P2 for treatment of lubricants in wastewater. J Hazard Mater 213–214:466–473CrossRefGoogle Scholar
  37. Kulkarni S, Kaware J (2013) Review on research for removal of phenol from wastewater. Int J Sci Res Publ 3(4):1–5Google Scholar
  38. Mai C, Schormann W, Majcherczyk A et al (2004) Degradation of acrylic copolymers by whiterot fungi. Appl Microbiol Biotechnol 65:479–487CrossRefGoogle Scholar
  39. Marcilly C (2003) Present status and future trends in catalysis for refining and petrochemicals. J Catal 216:47–62CrossRefGoogle Scholar
  40. McLusky DS, Martins T (1998) Long term study of an estuarine mudflat subjected to petrochemical discharges. Marine Poll Bull 36:791–798CrossRefGoogle Scholar
  41. Mesple F, Casetlas C, Troussetlier M et al (1996) Modetling orthophosphate evolution in a high rate algal pond. Ecol Modet 89(1–3):13–21CrossRefGoogle Scholar
  42. Metcalf, Eddy (1991) Wastewater engineering, treatment, disposal and reuse. Mc Graw Hill Book Company, New YorkGoogle Scholar
  43. Mohr KS, Veenstra JN, Sanders DA (1998) Refinery wastewater management using multiple angle oil-water separators, a paper presented at the International Petroleum Environment Conference in Albuquerque, New Mexico, Mohr Separations Research, Inc. Accessed on 18 Aug 2017
  44. Nopcharoenkul W, Netsakulnee P, Pinyakong O et al (2013) Diesel oil removal by immobilized Pseudoxanthomonas sp. RN402. Biodegradation 24(3):387–397CrossRefGoogle Scholar
  45. Okerentugba PO, Ezeronye OU (2003) Petroleum degrading potentials of single and mixed microbial cultures isolated from rivers and refinery effluent in Nigeria. Afr J Biotechnol 2:288–292CrossRefGoogle Scholar
  46. Okiel K, El-Sayed M, El-Kady MY (2011) Treatment of oil-water emulsions by adsorption onto activated carbon, bentonite and deposited carbon. Egy J P 20:9–15CrossRefGoogle Scholar
  47. Okoh AI (2003) Biodegradation of Bonny light crude oil in soil microcosm by some bacterial strains isolated from crude oil flow stations saver pits in Nigeria. Afr J Biotechnol 2(5):104–108CrossRefGoogle Scholar
  48. Otadi N, Hassani AH, Javid AH et al (2011) Oily compounds removal in wastewater treatment system of pars oil refinery to improve its efficiency in a lab scale pilot. J Water Chem Technol 32:370–377CrossRefGoogle Scholar
  49. Pearson TH, Rosenberg R (1978) Macrobenthic succession in relation to organic enrichment and pollution of the marine environment. Oceanogr Mar Biol Annu Rev 16:229–311Google Scholar
  50. Pombo F, Magrini A, Szklo A (2011) Technology roadmap for wastewater reuse in petroleum refineries in Brazil, Environmental Management in Practice. In: Broniewicz E (ed) In Tech, ISBN:978-953-307-358-3. Accessed 28 Aug 2017
  51. Proulx D, Lessard P, De La Noüe J (1994) Tertiary treatment of secondarily treated urban wastewater by intensive culture of Phormidium bohneri. Environ Technol 15(5):449–458CrossRefGoogle Scholar
  52. Rasheed QJ, Kannaiyan P, Karuppan M (2011) Treatment of petroleum refinery wastewater by ultrasound-dispersed nanoscale zero-valent iron particles. Ultrason Sonochem 18(5):1138–1142CrossRefGoogle Scholar
  53. Rastegar SO, Mousavi SM, Shojaosadati SA (2011) Optimization of petroleum refinery effluent treatment in a UASB reactor using response surface methodology. J Hazard Mater 197:26–32CrossRefGoogle Scholar
  54. Rattanapan C, Sawain A, Suksaroj T et al (2011) Enhanced efficiency of dissolved air flotation for biodiesel wastewater treatment by acidification and coagulation processes. Desalination 280(1–3):370–377CrossRefGoogle Scholar
  55. Renault F, Sancey B, Badot PM et al (2009) Chitosan for coagulation/flocculation processes—an eco-friendly approach. Eur Polym J 45:1337–1348CrossRefGoogle Scholar
  56. Saadoun I (2002) Isolation and characterization of bacteria from crude petroleum oil contaminated soil and their potential to degrade diesel fuel. J Basic Microbiol 42:420–428CrossRefGoogle Scholar
  57. Saien J, Nejati H (2007) Enhanced photocatalytic degradation of pollutants in petroleum refinery wastewater under mild conditions. J Hazard Mater 148:491–495CrossRefGoogle Scholar
  58. Santo CE, Vilar VJP, Bhatnagar A et al (2013) Biological treatment by activated sludge of petroleum refinery wastewaters. Desalin Water Treat 51(34–36):6641–6654CrossRefGoogle Scholar
  59. Schultz TE (2007) Wastewater treatment for the petroleum industry, selecting the right oil/water separation technology, technology & trends, specialist article, P&A Select Oil & Gas 2007Google Scholar
  60. Shokrollahzadeh S, Azizmohseni F, Golmohammad F et al (2008) Biodegradation potential and bacterial diversity of a petrochemical wastewater treatment plant in Iran. Bioresour Technol 99(14):6127–6133CrossRefGoogle Scholar
  61. Song H, Zhou L, Zhang L et al (2011) Construction of a whole-cell catalyst displaying a fungal lipase for effective treatment of oily wastewaters. J Mol Catal B Enzym 71(3–4):166–170CrossRefGoogle Scholar
  62. Suzuki T, Yamaya S (2005) Removal of hydrocarbons in a rotating biological contactor with biodrum. Process Biochem 40(11):3429–3433CrossRefGoogle Scholar
  63. Tang HL, Xie YF, Chen YC et al (2012) Use of Bio-Amp, a commercial bio-additive for the treatment of grease trap wastewater containing fat, oil, and grease. Bioresour Technol 124:52–58CrossRefGoogle Scholar
  64. Tir M, Moulai-Mostefa N (2008) Optimization of oil removal from oily wastewater by electrocoagulation using response surface method. J Hazard Mater 158(1):107–115CrossRefGoogle Scholar
  65. Tri PT (2002) Oily wastewater treatment by membrane bioreactor process coupled with biological activated carbon process. Master of Engineering Thesis, Asian Institute of Technology, School of Environment, Resources and Development, ThailandGoogle Scholar
  66. Uan DK (2013) Potential application of membrane bioreactor (MBR) technology for treatment of oily and petrochemical wastewater in Vietnam-an overview. Pet Saf Environ Petrovietnam J 6:64–71Google Scholar
  67. United States Environmental Protection Agency (U.S. EPA) (1995) Profile of the Petroleum Refining Industry, EPA Office of Compliance Sector Notebook Project, EPA/310-R95-013, September 1995, Office of Compliance, Office of Enforcement and Compliance Assurance, U.S. Environmental Protection Agency, Washington, DCGoogle Scholar
  68. USEPA (2006) Consumer factsheet on nitrates/nitrites. USEPA, Washington, DCGoogle Scholar
  69. USEPA (2013) Aquatic life ambient water quality criteria for ammonia-freshwater. USEPA, Washington, DCGoogle Scholar
  70. Valles M, Benavides-Mendoza A, Valdez-Aguilar AL et al (2013) Effect of the application of produced water on the growth, the concentration of minerals and toxic compounds in tomato under greenhouse. J Environ Prot 4:138–146CrossRefGoogle Scholar
  71. Wake H (2005) Oil refineries: a review of their ecological impacts on the aquatic environment. Estuar Coast Shelf Sci 62:131–140CrossRefGoogle Scholar
  72. WHO (2003) Polynuclear aromatic hydrocarbons in drinking water. GenevaGoogle Scholar
  73. Wu QX, Mueller GM, Lutzoni FM (2000) Phylogenetic and biogeographic relationships of eastern Asian and eastern north American disjunct Suillus species (Fungi) as inferred from nuclear ribosomal RNA ITS sequences. Mol Phylogenet Evol 17:37–47CrossRefGoogle Scholar
  74. Xie WY, Zhong L, Chen JJ (2007) Treatment of slightly polluted wastewater in an oil refinery using a biological aerated filter process. Wuhan Univ J Nat Sci 12(6):1094–1098CrossRefGoogle Scholar
  75. Yokogawa Corporation of America (2008) Refinery wastewater: oil & grease removal. Yokogawa Corporation of America. Accessed 28 Sept 2017
  76. Yuan X, Kumar A, Sahu AK, Ergas SJ (2011) Impact of ammonia concentration on Spirulina platensis growth in an airlift photobioreactor. Bioresour Technol 102(3):3234–3239CrossRefGoogle Scholar
  77. Zeng YB, Yang CZ, Zhang JD (2007) Feasibility investigation of oily wastewater treatment by combination of zinc and PAM in coagulation/flocculation. J Hazard Mater 147(3):991–996CrossRefGoogle Scholar
  78. Zhao X, Wang Y, Ye Z et al (2006) Oil field wastewater treatment in biological aerated filter by immobilized microorganisms. Process Biochem 41(7):1475–1483CrossRefGoogle Scholar
  79. Zhu YZ, Wang D, Jiang L (2014) Recent progress in developing advanced membranes for emulsified oil/water separation. NPG Asia Mater 6(5):101CrossRefGoogle Scholar
  80. Zouboulis AI, Avranas A (2000) Treatment of oil-in-water emulsions by coagulation and dissolved-air flotation. Colloids Surf A Physicochem Eng Asp 172(1–3):153–161CrossRefGoogle Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2019

Authors and Affiliations

  • Shailja Singh
    • 1
  • Shikha
    • 1
  1. 1.Department of Environmental ScienceBabasaheb Bhimrao Ambedkar UniversityLucknowIndia

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