Advertisement

Electrochemical Infrared Spectroscopy

Chapter

Abstract

As an application of infrared reflection absorption spectroscopy (IRAS) in the electrochemistry, electrochemical infrared spectroscopy (EC-IR) is becoming a routing technique to study the chemical structures on the electrode and solution interface during the electrochemical reactions.

Keywords

Infrared spectroscopy Electrochemistry Electrode/solution interface Reaction products and intermediate Chemical structure 

References

  1. 1.
    Greenler, R.G.: IR study of adsorbed molecules on metal surfaces by reflection techniques. J. Chem. Phys. 44, 310–315 (1966)CrossRefGoogle Scholar
  2. 2.
    Suetaka, W.: Surface Infrared and Raman Spectroscopy, Methods and Applications. Plenum Press, New York (1995)CrossRefGoogle Scholar
  3. 3.
    Seki, H., Kunimatsu, K., Golden, W.G.: A thin-layer electrochemical cell for infrared spectroscopic measurements of the electrode/electrolyte interface. Appl. Spectrosc. 39, 437–443 (1985)CrossRefGoogle Scholar
  4. 4.
    Bewick, A., Kunimatsu, K., Robinson, J., Russell, J.W.: IR vibrational spectroscopy of species in the electrode-electrolyte solution interphase. J. Electroanal. Chem. 119, 175–185 (1981)CrossRefGoogle Scholar
  5. 5.
    Bewick, A., Kunimatsu, K., Pons, B.S., Russell, J.W.: Electrochemically modulated infrared spectroscopy (EMIRS): experimental details. J. Electroanal. Chem. 160, 47–61 (1984)CrossRefGoogle Scholar
  6. 6.
    Nart, F., Iwasita, T.: In situ FTIR as a tool for mechanistic studies. Fundamentals and applications. In: Bard, A.J., Stratmann, M., Calvo, E.J. (eds.) Encyclopedia of Electrochemistry, vol. 3, pp. 243–294, Interfacial Kinetics and Mass Transport. Wiley (2003)Google Scholar
  7. 7.
    Korzeniewski, C.: Recent advances in in-situ infrared spectroscopy and applications in single-crystal electrochemistry and electrocatalysis. Adv. Electrochem. Sci. Eng. 9, 233–268 (2006)Google Scholar
  8. 8.
    Zamlynny, V., Lipkowski, J.: Quantitative SNIFTIRS and PM IRRAS of organic molecules at electrode surfaces. Adv. Electrochem. Sci. Eng. 9, 315–376 (2006)Google Scholar
  9. 9.
    Osawa, M.: Dynamic processes in electrochemical reactions studied by surface-enhanced infrared absorption spectroscopy (SEIRAS). Bull. Chem. Soc. Jpn 70, 2861–2880 (1997)CrossRefGoogle Scholar
  10. 10.
    Osawa, M.: In-situ surface-enhanced infrared spectroscopy of the electrode/solution interface. Adv. Electrochem. Sci. Eng. 9, 269–314 (2006)Google Scholar
  11. 11.
    Ye, S., Yashiro, A., Sato, Y., Uosaki, K.: Electrochemical in situ FT-IRRAS studies of a self-assembled monolayer of 2-(11-mercaptoundecyl)hydroquinone. J. Chem. Soc. Faraday Trans. 92, 3813–3822 (1996)CrossRefGoogle Scholar
  12. 12.
    Chen, Y.X., Miki, A., Ye, S., Sakai, H., Osawa, M.: Formate, an active intermediate for direct oxidation of methanol on Pt electrode. J. Am. Chem. Soc. 125, 3680–3681 (2003)CrossRefGoogle Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2018

Authors and Affiliations

  1. 1.Department of Chemistry, Graduate School of ScienceTohoku UniversitySendaiJapan

Personalised recommendations