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Study of Structure and Interactions in Polymers by Inverse Gas Chromatography

  • J. E. G. Lipson
  • J. E. Guillet

Summary

This chapter describes the application of gas chromatography to the study of solid polymers. The word ‘inverse’ is used to indicate that the component of interest is the stationary phase, which consists of polymer-coated support. Using this technique, glass transition temperatures, percentage crystal-Unities and surface areas can be obtained for the pure polymer. In addition, solution studies can be undertaken where the polymer is the concentrated ‘solvent’ and small amounts of organic vapour act as the solute or probe. Using data from these experiments, diffusion constants and solubilities can be calculated for the probe in the polymer, as well as activity coefficients, heats of solution, Flory-Huggins interaction parameters (x) and infinite dilution polymer solubility parameters. The chapter is divided into sections describing the different applications; in each section experimental details are outlined and the literature work is reviewed.

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Copyright information

© Applied Science Publishers Ltd 1982

Authors and Affiliations

  • J. E. G. Lipson
    • 1
  • J. E. Guillet
    • 1
  1. 1.Department of ChemistryUniversity of TorontoCanada

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