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Photocatalytic Oxidation of Organic Substrates

  • Marye Anne Fox
Chapter
Part of the NATO ASI Series book series (ASIC, volume 237)

Abstract

Photocatalytic oxidation of organic substrates occurs with high chemical yield on irradiated semiconductor surfaces. Photocatalysis is defined and exemplified and the theories of photoelectrochemistry are used to construct model cells. Mechanistic criteria needed to define a redox reaction pathway on a heterogeneous photocatalyst are reviewed, and a brief survey of functional group transformations which have been reported on semiconductor surfaces is given. The photocatalytic oxygenation of olefins is considered as a vehicle to illustrate these principles, and several practical applications of such investigations are cited.

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Copyright information

© Springer Science+Business Media Dordrecht 1988

Authors and Affiliations

  • Marye Anne Fox
    • 1
  1. 1.Department of ChemistryUniversity of Texas at AustinAustinUSA

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