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16O3 Integrated Intensity and Dipole Transition Moment Operator Constants for the 2ν2 + 2ν2 + ν3A-Type Band

  • Guy Guelachvili
  • Nathalie Picqué
Chapter
Part of the Molecules and Radicals book series (volume 20C2)

Abstract

This chapter provides the integrated intensity and dipole transition moment operator constants for the 2ν2 + 2ν2 + ν3 A-type band of 16O3 measured using Fourier transform spectroscopy.

Natural isotopic abundance: 0.992728.

Reference

[95Bar2]

Method

Fourier transform spectroscopy.

Equations

Equations  47 and  52 in chapter “ Introduction”.

Remarks

The band intensity, *from table 3 of [99Mik1], is given in cm−1/molecule cm−2 at 296 K.

Its value corresponds to the sum of its individual line intensities.

The parameter of the dipole transition moment operator is given in Debye.

Spectroscopic parameters are given in chapter “ 16O3 Vibrational Energy and Rotational and Centrifugal Distortion Constants for the (221) State. Band Center for the 2ν1 + 2ν2 + ν3 Transition”.

The isotopic composition of the elements used for the calculation of the natural isotopic abundance is taken from [2007Coh].

Band

Integrated intensity*

Transformed dipole transition moment operators

Parameter

SE

2ν2 + 2ν2 + ν3

1.1 × 10−22

   

A-type band

 

φz × 104

3.0

0.9

Symbols and abbreviations

Short form

Full form

υ 1 υ 2 υ 3

Upper vibrational level in normal mode notation

J x ,J y ,J z

Molecule-fixed components of J

SE

Statistical error

References

  1. [95Bar2]
    Barbe, A., Mikhailenko, S., Tyuterev, V.G., Hamdouni, A., and Plateaux, J.J.: Analysis of the 2ν1 + 2ν2 + ν3 Band of Ozone. J. Mol. Spectrosc. 171 (1995) 583−588.CrossRefADSGoogle Scholar
  2. [99Mik1]
    Mikhailenko, S., Barbe, A., Tyuterev, V., and Chichery, A.: High resolution IR spectra of the ozone molecule. Atmos. Oceanic Opt. 12 (1999) 771–785.Google Scholar
  3. [2007Coh]
    Cohen, E.R., Cvitaš, T., Frey, J.G., Holmström, B., Kuchitsu, K., Marquardt, R., Mills, I., Pavese, F., Quack, M., Stohner, J., Strauss, H.L., Takami, M., Thor, A.J.: Quantities, Units and Symbols in Physical Chemistry. The IUPAC Green Book, 3rd Ed., Cambridge: RSC Publishing, 2007.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Guy Guelachvili
    • 1
  • Nathalie Picqué
    • 2
  1. 1.Institut des Sciences Moléculaires d’Orsay (ISMO)CNRS, Univ. Paris-Sud, Univ. Paris-SaclayOrsayFrance
  2. 2.Institut des Sciences Moléculaires d’Orsay (ISMO)CNRS, Univ. Paris-Sud, Univ. Paris-SaclayOrsayFrance

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