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Diffusion coefficient of trans-diphenyl-diazene in 1,4-dioxane-d8

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of trans-diphenyl-diazene in 1,4-dioxane-d8 at different concentrations measured using NMR spin echo field gradient and holographic relaxation spectroscopy.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C12 H10 N2

(1)

trans-diphenyl-diazene

17082-12-1

C4 D8 O2

(2)

1,4-dioxane-d8

17647-74-4

Intradiffusion Coefficient: D1T (T); Method: NMR FG

Ref.: [1986L6]

T [K]

p [kPa]

D ⋅ 109 [m2/s]

 

298.15 ± 0.1

101.32

0.70 ± 5%

 

298.15 ± 0.1

101.32

0.72*

 

Comment: *: HRS (holographic resonance spectroscopy) measurement

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR FG

NMR spin echo field gradient

HRS

holographic relaxation spectroscopy

References

  1. [1986L6]
    Lever, L. S., Bradley, M. S., Johnson, C. S.: J. Magn. Reson. 68 (1986) 335–344.Google Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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