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Diffusion coefficient of 1-undecanesulfonic acid sodium salt in dideuterium oxide

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of 1-undecanesulfonic acid sodium salt in dideuterium oxide at different concentrations measured using NMR spin echo pulse gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C11 H24 O3 S Na

(1)

1-undecanesulfonic acid sodium salt

5838-34-6

D2 O

(2)

dideuterium oxide

7789-20-0

Intradiffusion Coefficient: D1T (m i ); T = 298.15 ± 0.1 K; Method: NMR PG

Ref.: [1999A11]

m1 [mol/kg]

p [kPa]

D ⋅ 109 [m2/s]

 

0.0752

101.32

0.157

 

0.0922

101.32

0.143

 

0.1060

101.32

0.126

 

0.1388

101.32

0.102

 

0.1795

101.32

0.0797

 

0.2250

101.32

0.0651

 

Intradiffusion Coefficient: D1T (m i ); T = 298.15 ± 0.1 K; Method: NMR PG

Ref.: [2001R10]

m1 [mol/kg]

p [kPa]

D ⋅ 109 [m2/s]

 

0.0000

101.32

0.600 ± 3%

 

0.0127

101.32

0.512 ± 3%

 

0.0159

101.32

0.454 ± 3%

 

0.0173

101.32

0.439 ± 3%

 

0.0186

101.32

0.314 ± 3%

 

0.0246

101.32

0.287 ± 3%

 

0.0357

101.32

0.241 ± 3%

 

0.0468

101.32

0.178 ± 3%

 

0.0638

101.32

0.134 ± 3%

 

0.0829

101.32

0.107 ± 3%

 

0.1021

101.32

0.103 ± 3%

 

0.1205

101.32

0.083 ± 3%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR PG

NMR spin echo pulse gradient

m i

molality

References

  1. [1999A11]
    Annunziata O., Costantino, L., D’Errico, G., Paduano, L., Vitagliano, V.: J. Colloid Interface Sci. 216 (1999) 16–24.CrossRefPubMedGoogle Scholar
  2. [2001R10]
    Roscigno P., Paduano, L., D’Errico, G., Vitagliano, V.: Langmuir 17 (2001) 4510–4518.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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