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Diffusion coefficient of trichloro-methane in tetrachloro-methane

  • Jochen Winkelmann
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of trichloro-methane in tetrachloro-methane at different concentrations measured using open ended capillary.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C H Cl3

(1)

trichloro-methane

67-66-3

C Cl4

(2)

tetrachloro-methane

56-23-5

Mutual Diffusion Coefficient: D12(x i ); T = 298.15 ± 0.1 K; Method: OEC

Ref.: [1971K2]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.027

101.32

1.505 ± 1.5%

 

0.234

101.32

1.557 ± 1.5%

 

0.234

101.32

1.572 ± 1.5%

 

0.431

101.32

1.644 ± 1.5%

 

0.690

101.32

1.680 ± 1.5%

 

0.739

101.32

1.752 ± 1.5%

 

0.774

101.32

1.757 ± 1.5%

 

0.774

101.32

1.779 ± 1.5%

 

0.907

101.32

1.881 ± 1.5%

 

0.942

101.32

1.972 ± 1.5%

 

0.946

101.32

1.976 ± 1.5%

 

0.977

101.32

2.007 ± 1.5%

 

Intradiffusion Coefficient: D1T (x i ); T = 298.15 ± 0.1 K; Method: OEC

Ref.: [1971K2]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.08

101.32

1.57 ± 1.5%

 

0.29

101.32

1.82 ± 1.5%

 

0.50

101.32

2.02 ± 1.5%

 

0.75

101.32

2.23 ± 1.5%

 

1.00

101.32

2.44 ± 1.5%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

OEC

open ended capillary

x i

mole fraction

References

  1. [1971K2]
    Kelly, C. M., Wirth, G. B., Anderson, D. K.: J. Phys. Chem. 75 (1971) 3293–3296.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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