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Diffusion coefficient of 1,2,3,4,5,6,6-C-d7-D-glucose in dideuterium oxide

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of 1,2,3,4,5,6,6-C-d7-D-glucose in dideuterium oxide at different concentrations measured using NMR spin echo pulse gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C6 H5 D7 O6

(1)

1,2,3,4,5,6,6-C-d7-D-glucose

66034-51-3

D2 O

(2)

dideuterium oxide

7789-20-0

Intradiffusion Coefficient: D1T (T); Method: NMR PG

Ref.: [1999M10]

Equation: D = A ∙ exp[− B/RT]

Range: 250 < T/K < 330

Comment: B in [kJ/mol]

Parameter:

w 1

A ⋅ 109

B

Δ A ⋅ 109

Δ B

 

0.400

1.1

27.8

0.3

0.6

Intradiffusion Coefficient: D2T (T); Method: NMR PG

Ref.: [1999M10]

Equation: D = A ∙ exp[− B/RT]

Range: 250 < T/K < 330

Comment: B in [kJ/mol]

Parameter:

w 1

A ⋅ 109

B

Δ A ⋅ 109

Δ B

 

0.400

1.1

25.4

0.1

0.3

 

0.750

1.7

31.1

0.8

1.0

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR PG

NMR spin echo pulse gradient

References

  1. [1999M10]
    Moran G. R., Jeffrey, K. R.: J. Chem. Phys. 110 (1999) 3472–3483.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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