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Diffusion coefficient of trichloro-methane into acetic acid and water

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of trichloro-methane into acetic acid and water at different concentrations measured using interferometry and Gouy interferometry.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.3. Diffusion in Ternary Mixtures

C H Cl3

(1)

trichloro-methane

67-66-3

C2 H4 O2

(2)

acetic acid

64-19-7

H2 O

(3)

water

7732-18-5

Mutual Diffusion Coefficient Matrix: Dij (xi, xj); Method: G-INT

Ref.: [2007B3]

T = 298.15 K; p = 101.325 kPa

x 1

x 2

D11 ⋅ 109 [m2/s]

D12 ⋅ 109 [m2/s]

D21 ⋅ 109 [m2/s]

D22 ⋅ 109 [m2/s]

0.0503

0.7000

0.311

−0.465

0.456

1.362

0.0667

0.6000

0.183

−0.448

0.513

1.272

0.0830

0.5020

0.001

−0.479

0.621

1.219

0.0925

0.4480

−0.043

−0.451

0.581

1.124

0.1000

0.4000

−0.139

−0.463

0.637

1.090

Mutual Diffusion Coefficient Matrix: Dij (ci, cj); Method: No Info

Ref.: [1986M6]

T = 298.15 K; p = 101.325 kPa

c1 [mol/dm3]

c2 [mol/dm3]

D11 ⋅ 109 [m2/s]

D12 ⋅ 109 [m2/s]

D21 ⋅ 109 [m2/s]

D22 ⋅ 109 [m2/s]

4.90

8.57

−0.616

−1.088

1.1162

1.813

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

x i

mole fraction

No Info

no information on method used

G-INT

Gouy interferometry

References

  1. [1986M6]
    Miller, D. G., Vitagliano, V., Sartorio, R.: J. Phys. Chem. 90 (1986) 1509–1519.CrossRefGoogle Scholar
  2. [2007B3]
    Buzatu D., Buzatu, F. D., Paduano, L., Sartorio, R.: J. Solution Chem. 36 (2007) 1373–1384.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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