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Diffusion coefficient of iodine in 1,4-dioxane at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of iodine in 1,4-dioxane at infinite dilution for various temperature and pressure conditions measured using diaphragm cell, correlation of experimental data and open ended capillary.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

I2

(1)

iodine

7553-56-2

C4 H8 O2

(2)

1,4-dioxane

123-91-1

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: OEC

Ref.: [1978N3]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

0.96 ± 0.03

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [1955W1]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

1.07

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1953S5]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.01

D 0 1(2)

1.07 ± 1%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

OEC

open ended capillary

DIA

diaphragm cell

CORR

correlation of experimental data

References

  1. [1953S5]
    Stokes R. H., Dunlop, P. J., Hall, J. R.: Trans. Faraday Soc. 49 (1953) 886–890.CrossRefGoogle Scholar
  2. [1955W1]
    Wilke, C. R., Chang, P.: AIChE J. 1 (1955) 264–270.CrossRefGoogle Scholar
  3. [1978N3]
    Nakanishi K.: Bull. Chem. Soc. Jpn. 51 (1978) 713–717.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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