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Diffusion coefficient of cyclohexane in toluene at infinite dilution

  • Jochen Winkelmann
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of cyclohexane in toluene at infinite dilution for various temperature and pressure conditions measured using Gouy interferometry, gel techniques, correlation of experimental data and interferometry.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C6 H12

(1)

cyclohexane

110-82-7

C7 H8

(2)

toluene

108-88-3

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [1973V1]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

2.420

 

298.15

D 0 2(1)

1.569

 

313.15

D 0 1(2)

3.069

 

313.15

D 0 2(1)

1.913

 

328.15

D 0 1(2)

3.800

 

328.15

D 0 2(1)

2.409

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: G-INT

Ref.: [1964R2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

2.27

 

298.15

D 0 2(1)

1.75

 

Comment: total uncertainty: ±0.2%

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: GEL

Ref.: [1981F2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.18 ± 0.01

D 0 1(2)

2.420 ± 0.4%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

INT

interferometry

G-INT

Gouy interferometry

GEL

gel techniques

CORR

correlation of experimental data

References

  1. [1964R2]
    Rettig, R. L.: Ph. D. Thesis, University of Wisconsin (1964).Google Scholar
  2. [1973V1]
    Vadovic, C. J., Colver, C. P.: AIChE J. 19 (1973) 546–551.CrossRefGoogle Scholar
  3. [1981F2]
    Freer, R., Sherwood, J. N.: J. Phys. Chem. 85 (1981) 102–106.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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