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Diffusion coefficient of cyclohexane in hexane at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of cyclohexane in hexane at infinite dilution for various temperature and pressure conditions measured using gel techniques and interferometry.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C6 H12

(1)

cyclohexane

110-82-7

C6 H14

(2)

hexane

110-54-3

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: MZ-INT

Ref.: [1969B8]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

3.77 ± 1%

 

Comment: data of low reliability; a factor of 10−5 is missing in dimension of D

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: GEL

Ref.: [1981F2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.18 ± 0.01

D 0 1(2)

3.876 ± 0.4%

 

298.18 ± 0.01

D 0 1(2)

4.004 ± 0.4%

 

298.18 ± 0.01

D 0 1(2)

3.896 ± 0.4%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

INT

interferometry

GEL

gel techniques

References

  1. [1969B8]
    Bidlack, D. L., Kett, T. K., Kelly, C. M., Anderson, D. K.: J. Chem. Eng. Data 14 (1969) 342–343.CrossRefGoogle Scholar
  2. [1981F2]
    Freer, R., Sherwood, J. N.: J. Phys. Chem. 85 (1981) 102–106.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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