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Diffusion coefficient of benzene in tetrachloro-methane at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of benzene in tetrachloro-methane at infinite dilution for various temperature and pressure conditions measured using NMR spin echo pulse gradient, interferometry, correlation of experimental data and Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C6 H6

(1)

benzene

71-43-2

C Cl4

(2)

tetrachloro-methane

56-23-5

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2001L3]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

1.400

 

298.15

D 0 2(1)

1.912

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: MZ-INT

Ref.: [1956C1]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

1.38

 

298.15

D 0 2(1)

1.91

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: NMR PG

Ref.: [1997W1]

T [K]

Type

D ⋅ 109 [m2/s]

 

303.15 ± 0.1

D 0 1(2)

1.77 ± 2.0%

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [2008S4]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

1.45 ± 3%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

NMR PG

NMR spin echo pulse gradient

INT

interferometry

CORR

correlation of experimental data

References

  1. [1956C1]
    Caldwell, C. S., Babb, A. L.: J. Phys. Chem. 60 (1956) 51–56.CrossRefGoogle Scholar
  2. [1997W1]
    Wakai, C., Nakahara, M.: J. Chem. Phys. 106 (1997) 7512–7518.CrossRefGoogle Scholar
  3. [2001L3]
    Li J., Liu, H., Hu, Y.: Fluid Phase Equilibria 187188 (2001) 193–208.CrossRefGoogle Scholar
  4. [2008S4]
    Safi A., Nicolas, C., Neau, E., Chevalier, J. L.: J. Chem. Eng. Data 53 (2008) 444–448.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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