Advertisement

Diffusion coefficient of D(+)-xylose in water at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of D(+)-xylose in water at infinite dilution for various temperature and pressure conditions measured using interferometry, correlation of experimental data and Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C5 H10 O5

(1)

D(+)-xylose

58-86-6

H2 O

(2)

water

7732-18-5

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [2007M1]

T [K]

Type

D ⋅ 109 [m2/s]

 

273.2 ± 0.1

D 0 1(2)

0.348 ± 2.5%

 

293.2 ± 0.1

D 0 1(2)

0.665 ± 2.5%

 

298.2 ± 0.1

D 0 1(2)

0.769 ± 2.5%

 

313.2 ± 0.1

D 0 1(2)

1.11 ± 2.5%

 

333.2 ± 0.1

D 0 1(2)

1.64 ± 2.5%

 

353.2 ± 0.2

D 0 1(2)

2.33 ± 2.5%

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [1998G3]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

0.7480 ± 0.002

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: R-INT

Ref.: [1985U2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.01

D 0 1(2)

0.7495

 

Diffusion Coefficient at infinite dilution: D01(2) (T); Method: TAYLOR

Ref.: [2007M1]

Equation: D = A ∙ exp[−B/RT]

Range: 273 < T/K < 353

Comment: B in [kJ/mole]; D01(2) [m2/s] = D

Parameter:

A⋅ 106

B

Std-Dev

 

1.511

18.89

3.4%

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

INT

interferometry

CORR

correlation of experimental data

References

  1. [1985U2]
    Uedaira H., Uedaira, H.: J. Solution Chem. 14 (1985) 27–34.CrossRefGoogle Scholar
  2. [1998G3]
    Groß, T., Buchhauser, J., Price, W. E., Tarassov, I. N., Lüdemann, H.-D.: Rev. High Pressure Sci. Technol. 7 (1998) 1432–1434.CrossRefGoogle Scholar
  3. [2007M1]
    Mogi N., Sugai, E., Fuse, Y., Funazukuri, T.: J. Chem. Eng. Data 52 (2007) 40–43.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

Personalised recommendations