Advertisement

Diffusion coefficient of tetramethyl-stannane in tetrachloro-methane at infinite dilution

  • Jochen Winkelmann
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of tetramethyl-stannane in tetrachloro-methane at infinite dilution for various temperature and pressure conditions measured using NMR spin echo field gradient and Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C4 H12 Sn

(1)

tetramethyl-stannane

594-27-4

C Cl4

(2)

tetrachloro-methane

56-23-5

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1981E2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

1.22

 

Diffusion Coefficient at infinite dilution: D01(2) (T); Method: NMR FG

Ref.: [1981V1]

Equation: ln D = ln AB/RT

Range: 255 < T/K < 300

Comment: B in [kJ/mole]; relative error: ±5%

Parameter:

A ∙ 107

B

 
 

2.45492

13.0

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

NMR FG

NMR spin echo field gradient

References

  1. [1981E2]
    Evans, D. F., Tominaga, T., Davis, H. T.: J. Chem. Phys. 74 (1981) 1298–1305.CrossRefGoogle Scholar
  2. [1981V1]
    Vogel, H., Weiss, A.: Ber. Bunsen-Ges. Phys. Chem. 85 (1981) 1022–1026.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

Personalised recommendations