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Diffusion coefficient of 1,3,5-trioxane in chlorobenzene at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of 1,3,5-trioxane in chlorobenzene at infinite dilution for various temperature and pressure conditions measured using Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C3 H6 O3

(1)

1,3,5-trioxane

110-88-3

C6 H5 Cl

(2)

chlorobenzene

108-90-7

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1985Y1]

T [K]

Type

D ⋅ 109 [m2/s]

 

301.2 ± 0.1

D 0 1(2)

1.87 ± 0.02

 

313.2 ± 0.1

D 0 1(2)

2.17 ± 0.03

 

343.2 ± 0.1

D 0 1(2)

3.15 ± 0.04

 

373.2 ± 0.1

D 0 1(2)

4.22 ± 0.05

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1984C8]

T [K]

Type

D ⋅ 109 [m2/s]

 

301

D 0 1(2)

1.87 ± 0.02

 

313

D 0 1(2)

2.17 ± 0.02

 

343

D 0 1(2)

3.15 ± 0.04

 

373

D 0 1(2)

4.22 ± 0.06

 

Diffusion Coefficient at infinite dilution: D01(2) (T); Method: TAYLOR

Ref.: [1984C8]

Equation: D = A ∙ exp[−B/RT]

Range: 301 < T/K < 373

Comment: B in [cal/mole]; D01(2) [m2/s] = D ⋅ 10−9

Parameter:

A

B

 
 

131.1

2545

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

References

  1. [1984C8]
    Chen, S.-H., Yumet, E.: Chem. Eng. Sci. 39 (1984) 663–667.CrossRefGoogle Scholar
  2. [1985Y1]
    Yumet, E., Chen, H.-C., Chen, S.-H.: AIChE J. 31 (1985) 76–81.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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