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Diffusion coefficient of dimethyl-sulfoxide in dimethyl-sulfoxide-d6 at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of dimethyl-sulfoxide in dimethyl-sulfoxide-d6 at infinite dilution for various temperature and pressure conditions measured using NMR spin echo pulse gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C2 H6 O S

(1)

dimethyl-sulfoxide

67-68-5

C2 D6 O S

(2)

dimethyl-sulfoxide-d6

2206-27-1

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: NMR PG

Ref.: [1996H9]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.1

D 0 1(2)

0.66 ± 1.0%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR PG

NMR spin echo pulse gradient

References

  1. [1996H9]
    Holz, M., Mao, X., Seiferling, D., Sacco, A.: J. Chem. Phys. 104 (1996) 669–679.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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