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Diffusion coefficient of acetonitrile in dideuterium oxide at infinite dilution

  • Jochen Winkelmann
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of acetonitrile in dideuterium oxide at infinite dilution for various temperature and pressure conditions measured using NMR spin echo pulse gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C2 H3 N

(1)

acetonitrile

75-05-8

D2 O

(2)

dideuterium oxide

7789-20-0

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: NMR PG

Ref.: [1997W1]

T [K]

Type

D ⋅ 109 [m2/s]

 

303.15 ± 0.1

D 0 1(2)

1.51 ± 2.0%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR PG

NMR spin echo pulse gradient

References

  1. [1997W1]
    Wakai, C., Nakahara, M.: J. Chem. Phys. 106 (1997) 7512–7518.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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