Advertisement

Diffusion coefficient of acetonitrile in acetonitrile-d3 at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of acetonitrile in acetonitrile-d3 at infinite dilution for various temperature and pressure conditions measured using NMR spin echo pulse gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C2 H3 N

(1)

acetonitrile

75-05-8

C2 D3 N

(2)

acetonitrile-d3

2206-26-0

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: NMR PG

Ref.: [1996H9]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.1

D 0 1(2)

4.17 ± 1.0%

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: NMR PG

Ref.: [1997W1]

T [K]

Type

D ⋅ 109 [m2/s]

 

303.15 ± 0.1

D 0 1(2)

3.81 ± 2.0%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR PG

NMR spin echo pulse gradient

References

  1. [1996H9]
    Holz, M., Mao, X., Seiferling, D., Sacco, A.: J. Chem. Phys. 104 (1996) 669–679.CrossRefGoogle Scholar
  2. [1997W1]
    Wakai, C., Nakahara, M.: J. Chem. Phys. 106 (1997) 7512–7518.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

Personalised recommendations