Advertisement

Diffusion coefficient of methanol in propan-1-ol at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of methanol in propan-1-ol at infinite dilution for various temperature and pressure conditions measured using diaphragm cell, correlation of experimental data and holographic interferometry.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C H4 O

(1)

methanol

67-56-1

C3 H8 O

(2)

propan-1-ol

71-23-8

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1963S2]

T [K]

Type

D ⋅ 109 [m2/s]

 

303.15

D 0 1(2)

0.804 ± 0.041

 

303.15

D 0 2(1)

1.966 ± 0.059

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: HOLO

Ref.: [2010R1]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

0.68

 

298.15

D 0 2(1)

1.37

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2012B2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

0.75

 

298.15

D 0 2(1)

1.97

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2001L3]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

0.750

 

298.15

D 0 2(1)

1.970

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1971L4]

T [K]

Type

D ⋅ 109 [m2/s]

 

303.15

D 0 1(2)

0.80 ± 3%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

HOLO

holographic interferometry

DIA

diaphragm cell

CORR

correlation of experimental data

References

  1. [1963S2]
    Shuck, F. O., Toor, H. L.: J. Phys. Chem. 67 (1963) 540–545.CrossRefGoogle Scholar
  2. [1971L4]
    Lusis, M. A., Ratcliff, G. A.: AIChE J. 17 (1971) 1492–1496.CrossRefGoogle Scholar
  3. [2001L3]
    Li J., Liu, H., Hu, Y.: Fluid Phase Equilibria 187188 (2001) 193–208.CrossRefGoogle Scholar
  4. [2010R1]
    Rehfeldt S., Stichlmair J.: Fluid Phase Equilib. 290 (2010) 1–14.CrossRefGoogle Scholar
  5. [2012B2]
    Beigzadeh R., Rahimi, M., Shabanian, S. R.: Fluid Phase Equilib. 331 (2012) 48–57.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

Personalised recommendations