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Diffusion coefficient of water in methanol-d4

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of water in methanol-d4 at different concentrations measured using NMR spin echo field gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

H2 O

(1)

water

7732-18-5

C D4 O

(2)

methanol-d4

811-98-3

Intradiffusion Coefficient: D1T (T); Method: NMR FG

Ref.: [1986E2]

T [K]

p [kPa]

D ⋅ 109 [m2/s]

 

278.15 ± 0.02

101.32

1.06

 

288.15 ± 0.02

101.32

1.44

 

298.15 ± 0.02

101.32

1.94

 

308.15 ± 0.02

101.32

2.48

 

318.15 ± 0.02

101.32

3.17

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR FG

NMR spin echo field gradient

References

  1. [1986E2]
    Easteal, A. J., Woolf, L. A.: J. Solution Chem. 15 (1986) 1003–1013.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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