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Hydrohalic acid anion interaction with silver surfaces: Ag(111) – chloride

  • M. NowickiEmail author
  • K. Wandelt
Chapter
Part of the Condensed Matter book series (volume 45B)

Abstract

In this chapter the experimental results on adsorption of chloride interaction on Ag(111) surface is described.

Cl-Ag(111) interaction was studied by in situ STM, LEED, AES, and DFT. In 5 × 10−4 M KCl + 0.1 KPF6 Cl is described to form a (1.38 × 1.38) structure before a sharp CV peak at 0.0 V (SCE) as seen with in situ STM [in UHV (√3 × √3)R30°] [1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12].

Symbols and abbreviations

Short form

Full form

LEED

low-energy electron diffraction

STM

scanning tunneling microscopy

UHV

ultrahigh vacuum

AES

Auger electron spectroscopy

SCE

saturated calomel electrode

DFT

density functional theory

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Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  1. 1.Institute of Experimental PhysicsUniversity of WroclawWroclawPoland
  2. 2.Institute of Physical and Theoretical ChemistryUniversity of BonnBonnGermany

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