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Electrochemistry pp 2207-2207 | Cite as

Ionic conductance of acetonitrile/dioxan-based electrolyte solutions

  • Rudolf Holze
Chapter
Part of the Physical Chemistry book series (volume 9B2)

Abstract

This chapter contains a tabular compilation of ionic conductance of acetonitrile/dioxan-based electrolyte solutions at various temperatures.

Table 1.7.9

Ionic conductances of mixed solvent-based electrolyte solutions

Solvent1

Salt

k or Λ or Λ02

−1cm−1 or Ω−1mol−1cm2]

T [K]

c3 [mol · dm−3]

Ref.

Acetonitrile/dioxan

100/0 %wt.

TBAP

164.69

25 °C

-

[72Gof]

Acetonitrile/dioxan

90/10 %wt.

TBAP

156.60

25 °C

-

[72Gof]

Acetonitrile/dioxan

80/20 %wt.

TBAP

147.69

25 °C

-

[72Gof]

Acetonitrile/dioxan

60/40 %wt.

TBAP

128.1

25 °C

-

[72Gof]

Acetonitrile/dioxan

50/50 %wt.

TBAP

117.28

25 °C

-

[72Gof]

Acetonitrile/dioxan

40/60 %wt.

TBAP

104.4

25 °C

-

[72Gof]

Acetonitrile/dioxan

35/65 %wt.

TBAP

98.7

25 °C

-

[72Gof]

Acetonitrile/dioxan

30/70 %wt.

TBAP

92.3

25 °C

-

[72Gof]

1Composition in units as stated

2Conductances at infinite dilution Λ0 are printed in italics without mentioning a concentration, units are Ω−1 mol−1cm2. Molar conductances are given in italics with a concentration value, units are Ω−1 mol−1cm2. Simple conductivities are given stating the concentration, units are Ω−1 cm−1

3Concentrations are molar (units: mol · dm−3), molal concentrations are given in italics (units: mol · kg−1), other concentrations as specified

Symbols and Abbreviations

Short form

Full form

κ, Λ

ionic conductivity

T

temperature

Λ 0

ionic conductance at infinite dilution

c

molar concentration

References

  1. [72Gof]
    Goffredi, M., Triolo, R.: J. Chem.Soc. Faraday Trans. I 68 (1972) 2324.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Rudolf Holze
    • 1
  1. 1.Technische Universität ChemnitzInstitut für ChemieChemnitzGermany

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