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Electrochemistry pp 2204-2204 | Cite as

Ionic conductance of acetonitrile/benzene-based electrolyte solutions

  • Rudolf Holze
Chapter
Part of the Physical Chemistry book series (volume 9B2)

Abstract

This chapter contains a tabular compilation of ionic conductance of acetonitrile/benzene-based electrolyte solutions at various temperatures.

Table 1.7.9

Ionic conductances of mixed solvent-based electrolyte solutions

Solvent1

Salt

k or Λ or Λ02

−1cm−1 or Ω−1mol−1cm2]

T [K]

c3 [mol · dm−3]

Ref.

Acetonitrile (100 %mol.)/benzene

Bu4NBPh4

119.96

25 °C

-

[82Gil1]

Acetonitrile (94 %mol.)/benzene

Bu4NBPh4

115.69

25 °C

-

[82Gil1]

Acetonitrile (88 %mol.)/benzene

Bu4NBPh4

111.40

25 °C

-

[82Gil1]

Acetonitrile (74 %mol.)/benzene

Bu4NBPh4

105.74

25 °C

-

[82Gil1]

Acetonitrile (66 %mol.)/benzene

Bu4NBPh4

99.28

25 °C

-

[82Gil1]

Acetonitrile (56 %mol.)/benzene

Bu4NBPh4

91.96

25 °C

-

[82Gil1]

Acetonitrile (51 %mol.)/benzene

Bu4NBPh4

89.25

25 °C

-

[82Gil1]

Acetonitrile (45 %mol.)/benzene

Bu4NBPh4

84.32

25 °C

-

[82Gil1]

Acetonitrile (95.03 %wt.)/benzene

KClO4

185.77

25 °C

-

[73D’A]

Acetonitrile (89.98 %wt.)/benzene

 

183.15

25 °C

-

[73D’A]

Acetonitrile (88.55 %wt.)/benzene

 

182.41

25 °C

-

[73D’A]

Acetonitrile (82.65 %wt.)/benzene

 

178.38

25 °C

-

[73D’A]

1Composition in units as stated

2Conductances at infinite dilution Λ0 are printed in italics without mentioning a concentration, units are Ω−1 mol−1cm2. Molar conductances are given in italics with a concentration value, units are Ω−1 mol−1cm2. Simple conductivities are given stating the concentration, units are Ω−1 cm−1

3Concentrations are molar (units: mol · dm−3), molal concentrations are given in italics (units: mol · kg−1), other concentrations as specified

Symbols and Abbreviations

Short form

Full form

κ, Λ

ionic conductivity

T

temperature

Λ 0

ionic conductance at infinite dilution

c

molar concentration

References

  1. [73D’A]
    D'Aprano, A., Donato, I.D.: J. Chem. Soc. Faraday Trans. I 69 (1973) 1685.CrossRefGoogle Scholar
  2. [82Gil1]
    Gill, D.S., Sekhri, M.B.: J. Chem. Soc., Faraday Trans. I 78 (1982) 119.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Rudolf Holze
    • 1
  1. 1.Technische Universität ChemnitzInstitut für ChemieChemnitzGermany

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