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Electrochemistry pp 2192-2192 | Cite as

Transference numbers of NH4+ ion in nonaqueous electrolyte solutions

  • Rudolf Holze
Chapter
Part of the Physical Chemistry book series (volume 9B2)

Abstract

This chapter contains a tabular compilation of transference numbers of NH+4 ion in nonaqueous electrolyte solutions.

Table 1.7.7

Transference numbers for ions in nonaqueous electrolyte solutions

Ion

t

T1 [K]

Solvent

Electrolyte

c 2

Ref.

\( {\mathrm{NH}}_4^{+} \)

0.031

25 °C

H2SO4

NH4HSO4

0.4766

[55Was]

0.034

25 °C

H2SO4

NH4HSO4

0.7836

[55Was]

0.037

25 °C

H2SO4

NH4HSO4

0.9780

[55Was]

0.031

25 °C

Oleum (15 %)

NH4HSO4

0.5629

[55Was]

0.058

−10.02 °C

HNO3

NH4NO3

0.1

[58Lee]

0.107

−10.02 °C

HNO3

NH4NO3

0.2

[58Lee]

0.154

−10.02 °C

HNO3

NH4NO3

0.3

[58Lee]

0.189

−10.02 °C

HNO3

NH4NO3

0.4

[58Lee]

0.217

−10.02 °C

HNO3

NH4NO3

0.5

[58Lee]

0.243

−10.02 °C

HNO3

NH4NO3

0.6

[58Lee]

0.267

−10.02 °C

HNO3

NH4NO3

0.7

[58Lee]

0.281

−10.02 °C

HNO3

NH4NO3

0.8

[58Lee]

0.315

−10.02 °C

HNO3

NH4NO3

0.9

[58Lee]

0.340

−10.02 °C

HNO3

NH4NO3

1.0

[58Lee]

0.00126

−33.5 °C

NH3

NH4I

0.033557

[04Fra]

0.00130

−33.5 °C

NH3

NH4I

0.032206

[13Kra]

0.00133

−33.5 °C

NH3

NH4NO3

0.159236

[04Fra]

0.00133

−33.5 °C

NH3

NH4NO3

0.071124

[13Kra]

0.00133

−33.5 °C

NH3

NH4NO3

0.017036

[13Kra]

1Units are K if not stated otherwise

2Concentrations are molar (units: mol · dm−3), molal concentrations are given in italics (units: mol · kg−1), other concentrations as specified

Symbols and Abbreviations

Short form

Full form

T

temperature

t

transference numbers

c

molar concentration

References

  1. [04Fra]
    Franklin, Ec., Cady, H.P.: J. Am. Chem. Soc. 26 (1904) 499.CrossRefGoogle Scholar
  2. [13Kra]
    Kraus, C.A., Bray, W.C.: J. Am. Chem. Soc. 35 (1913) 1364.Google Scholar
  3. [55Was]
    Wasif, S.: J. Chem. Soc. 1955 (1955) 372.CrossRefGoogle Scholar
  4. [58Lee]
    Lee, W.H., Millen, D.J.: J. Chem. Soc. 1958 (1958) 2248.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Rudolf Holze
    • 1
  1. 1.Technische Universität ChemnitzInstitut für ChemieChemnitzGermany

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