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Electrochemistry pp 2186-2186 | Cite as

Transference numbers of H+ ion in nonaqueous electrolyte solutions

  • Rudolf Holze
Part of the Physical Chemistry book series (volume 9B2)

Abstract

This chapter contains a tabular compilation of transference numbers of H+ ion in nonaqueous electrolyte solutions.

Table 1.7.7

Transference numbers for ions in nonaqueous electrolyte solutions

Ion

t

T1 [K]

Solvent

Electrolyte

c 2

Ref.

H+

0.758

25 °C

Ethanol

HCl

0

[25Har]

0.753

25 °C

Ethanol

HCl

0.001

[25Har]

0.738

25 °C

Ethanol

HCl

0.002

[25Har]

0.718

25 °C

Ethanol

HCl

0.005

[25Har]

0.702

25 °C

Ethanol

HCl

0.01

[25Har]

0.687

25 °C

Ethanol

HCl

0.02

[25Har]

0.669

25 °C

Ethanol

HCl

0.05

[25Har]

0.654

25 °C

Ethanol

HCl

0.1

[25Har]

0.641

25 °C

Ethanol

HCl

0.2

[25Har]

0.626

25 °C

Ethanol

HCl

0.5

[25Har]

0.610

25 °C

Ethanol

HCl

1.0

[25Har]

0.595

25 °C

Ethanol

HCl

2.0

[25Har]

0.584

25 °C

Ethanol

HCl

3.0

[25Har]

0.580

25 °C

Ethanol

HCl

3.5

[25Har]

0.022

25 °C

H2SO4

CH3COOH

0.5723

[55Was]

0.061

25 °C

Oleum (15 %)

CH3COOH

0.3521

[55Was]

1Units are K if not stated otherwise

2Concentrations are molar (units: mol · dm−3), molal concentrations are given in italics (units: mol · kg−1), other concentrations as specified

Symbols and Abbreviations

Short form

Full form

T

temperature

t

transference numbers

c

molar concentration

References

  1. [25Har]
    Harned, H.S., Fleysher, M.H.: J. Am. Chem. Soc. 47 (1925) 94.Google Scholar
  2. [55Was]
    Wasif, S.: J. Chem. Soc. 1955 (1955) 372.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Rudolf Holze
    • 1
  1. 1.Technische Universität ChemnitzInstitut für ChemieChemnitzGermany

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