Spectral data of zinc complex of porphyrin derivative C56H36N4Zn

  • M. P. Dobhal
Chapter
Part of the Molecules and Radicals book series (volume 32B2)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of zinc complex of porphyrin derivative C56H36N4Zn.

2. Spectral Studies

Spectral Data of Porphyrin Isomers and Expanded Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks γ [cm−1]

Solvent

Peaks λ [nm]/ (ε [M−1cm−1]/ log ε)

  

THF-d8

1 H NMR

2.51 (s, 12H, 4xCH3),

7.44 (d, 8H, J = 7.6 Hz),

7.99 (d, 8H, J = 7.6 Hz),

9.71 (s, 8H)

 

THF

478 (5.66),

627 (4.17),

684 (4.78)

 

[07Kuo]

CDCl3

13 C NMR

21.68, 92.61, 97.87, 103.89, 122.03, 130.32, 132.03, 132.36, 139.72, 152.53

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [07Kuo]
    Kuo, M.-C., Li, L.-A., Yen, W.-N., Lo, S.-S., Lee, C.-W., Yeh, C.Y.: J. Chem. Soc. Dalton Trans. 1433 (2007)Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  • M. P. Dobhal
    • 1
  1. 1.Department of ChemistryUniversity of RajasthanJaipurIndia

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