Spectral data of porphyrin derivative C51H42N4O3

  • M. P. Dobhal
Chapter
Part of the Molecules and Radicals book series (volume 32B2)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of porphyrin derivative C51H42N4O3.

2. Spectral Studies

Spectral Data of Porphyrin Isomers and Expanded Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks γ [cm−1]

Solvent

Peaks λ [nm]/ (ε [M−1cm−1]/ log ε)

  

CDCl3

1 H NMR

−2.76 (br s, 2H, 2xNH),

2.68 (s, 9H, 3xCH3),

7.23 (m, 2H, 4′, 5′-H),

7.52 (brd, 6H, 3, 5-tolyl-H),

8.07 (d, 2H, J = 7.7 Hz, 3′, 6′-H), 8.09 (d, 6H, J = 7.6 Hz, 2, 6-tolyl-H),

8.83 (br s, 8H, β-pyrrole-H)

 

CH2Cl2

420 (388.6 × 103), 517 (15.7 × 103), 553 (9.8 × 103), 592 (4.9 × 103), 648 (4.2 × 103)

 

[06Sol2]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [06Sol2]
    Sol, V., Lamarche, F., Enache, M., Garcia, G., Granet, R., Guilloton, M., Blais, J.C., Krausz, P.: Bioorg. Med. Chem. 14, 1364 (2006)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  • M. P. Dobhal
    • 1
  1. 1.Department of ChemistryUniversity of RajasthanJaipurIndia

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