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Determination of the Number of Active Centers in Ziegler-Natta Polymerizations of Olefins

  • Jiří Mejzlík
  • Marie Lesná
  • Jan Kratochvíla
Conference paper
Part of the Advances in Polymer Science book series (POLYMER, volume 81)

Abstract

The methods developed for the determination of the number of active centers are classified into three main categories, based on: (i) labelling of the macromolecules, (ii) consumption data of an effective catalyst poison, and (iii) other principles. The methods are characterized and their advantages, shortcomings and pitfalls are specified. Examples of procedures used to obtain the number of active centers employing various methods are presented. The importance of the data obtained for understanding Ziegler-Natta polymerizations of olefins is outlined.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1986

Authors and Affiliations

  • Jiří Mejzlík
    • 1
  • Marie Lesná
    • 1
  • Jan Kratochvíla
    • 1
  1. 1.Chemopetrol, Research Institute of Macromolecular ChemistryBrnoCzechoslovakia

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