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Tin pp 214-247 | Cite as

Organotin Compounds

  • J. W. Price
Chapter
Part of the Handbuch der Analytischen Chemie / Handbook of Analytical Chemistry book series (HAC, volume 3 / 4 / 4a / 4a g)

Abstract

The organic compounds of tin dealt with in this section are those in which there is at least one direct bond between tin and a carbon atom. As stable organotin compounds based on bivalent tin are virtually unknown, this means that four types of compound based on tetravalent tin, can be formed — R4 Sn, R3 SnX, R2 SnX2 and RSnX3, where R is an alkyl or aryl group attached to tin via carbon and X is any substituent group attached to tin through an electronegative atom such as halogen, oxygen, nitrogen or sulphur. The chemistry of these compounds is discussed in detail in specialist text-books [1] and is not considered here. Their industrial importance is due primarily to
  1. a)

    the biocidal properties of the R3 SnX compounds

     
  2. b)

    the stabilising action of R2 SnX2 compounds in PVC, particularly in rigid non-plasticised material.

     

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© Springer-Verlag Berlin Heidelberg 1978

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  • J. W. Price

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