A novel method of preparing nano-sized gold and palladium particles dispersed in composites that uses the thermal relaxation technique

  • K. Sayo
  • S. DekiEmail author
  • S. Hayashi
Conference paper


Stable nana-sized gold and palladium particles dispersed in composites were prepared by way of the thermal relaxation technique. Continuous formation and dispersion of metal particles into a nylon-11 oligomer film were achieved by the heating of the oligomer film to 46 °C during a vapor deposition of the metal. The mean particle size in the composite was 4.4 nm (S.D. = 1.7 nm) for the gold particles prepared by the deposition of about 3.6 × 1018 atoms cm−2. For the palladium particles the particle size was 2.3 nm (S.D. = 0.67 nm) and the deposition 4.2 × 1018 atoms cm−2. The obtained composite of gold or palladium particles was readily dissolved in CH2Cl2, producing stable colloidal solutions. The procedure reported here is very effective for preparing a great deal of metal particles dispersed in composites.


81.20.Zx Other methods of materials synthesis and materials processing 61.46.+w Clusters nanoparticles, and nanocrystalline materials 07.30.-t Vacuum apparatus and techniques 


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  1. 1.
    U. Kreibig, L. Genzel: Surf. Sci. 156, 673 (1985)ADSCrossRefGoogle Scholar
  2. 2.
    F. H. Dremus: J. Them. Phys. 40, 2389 (1964)ADSGoogle Scholar
  3. 3.
    R. Kubo: J. Phys. Soc. Jpn. 17, 975 (1962)ADSCrossRefzbMATHMathSciNetGoogle Scholar
  4. 4.
    V.I. Klirnov, V.A. Karaxanskii: Phys. Rev. B 54, 8087 (1996)ADSCrossRefGoogle Scholar
  5. 5.
    S. Yatsuya: Jpn. J. Appl. Phys. 13, 749 (1974)ADSCrossRefGoogle Scholar
  6. 6.
    R. Seshadri, G.N. Subbanna, V. Vijayakrishnan„ G.U. Kulkarni, G. Ananthakrishna, C.N.R. Rao: J. Phys. Chem. 99, 5639 (1995)CrossRefGoogle Scholar
  7. 7.
    C. Petit, P. Lixon„ M.P. Pileni: J. Phys. Chem. 97, 12974 (1993)CrossRefGoogle Scholar
  8. 8.
    K.S. Birdi: Surface and Colloid Chemistry ( CRC Press, New York 1997 )Google Scholar
  9. T. Noguchi, K. Gotoh, Y. Yamaguchi, S. Deki: J. Mater. Sci. Lett, 10, 477 (1991)CrossRefGoogle Scholar
  10. 10.
    K. Sayo, S. Deki, S. Hayashi: Int. J. Adhesion Adhesives (to he published)Google Scholar
  11. 11.
    H. Sakurai, S. Tsubota, Haruta:Appl. Catal. A (Ckneral) 102, 125 (1993)CrossRefGoogle Scholar
  12. 12.
    M.T. Reetz, R. Breinbauer, K. Wanninger: Tetrahedron Lett. 37, 4499 (1996)CrossRefGoogle Scholar
  13. 13.
    K. Akamatsu, S. Deki: J. Mater, Chem. 8, 637 (1997)CrossRefGoogle Scholar
  14. 14.
    U. Kreibig, M. Vollmer: Optical Properties of Aletal Clusters ( Springer, Berlin 1995 )CrossRefGoogle Scholar
  15. : H. Natter, T. Krajewski, R. H.mpelmann: Ber. Bunsenges, Phys. Chem. 100, 55 (1996)Google Scholar
  16. 16.
    W. Hoogsteen, L.G.J. Fokkink: J. Colloid Interface Sci. 175, 12 (1995)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Italia 1999

Authors and Affiliations

  1. 1.Department of Chemical Science and Engineering, Faculty of EngineeringKobe UniversityNada-ku, KobeJapan
  2. 2.Research and Development DepartmentMitsuboshi Belting Ltd.Nagata-ku, KobeJapan

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