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Fourier transform infrared and mass spectrometry studies of a photoirradiated KxC60 film

  • J. OnoeEmail author
  • Y. Hashi
  • K. Esfarjani
  • Y. Kawazoe
  • K. Takeuchi
Conference paper

Abstract

A photoirradiated potassium-doped C60 film has been studied by Fourier transform mass spectrometry (FT-MS) and by in situ high-resolution Fourier transform infrared spectroscopy (FT-IR) in combination with tight-binding IR calculations. The results of FT-MS and FT-IR strongly suggest that C120 bucky peanuts, which have been theoretically predicted to be stable, were formed in the photoirradiated film.

PACS

61.46.+w Clusters, nanoparticles, and nanocrystalline materials 33.20.Ea Infrared spectra 82.35.+t Polymer reactions and polymerization 82.50.−m Photochemistry and radiation chemistry 33.15.Ta Mass spectra 36.40.Mr Spectroscopy and geometrical structure of clusters 36.40.Wa Charged clusters 61.48.+c Fullerenes and fullerenes-related materials 

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Copyright information

© Springer-Verlag Italia 1999

Authors and Affiliations

  • J. Onoe
    • 1
    Email author
  • Y. Hashi
    • 2
  • K. Esfarjani
    • 3
  • Y. Kawazoe
    • 3
  • K. Takeuchi
    • 1
  1. 1.The Institute of Physical and Chemical ResearchWako, SaitamaJapan
  2. 2.Research and Development CenterHitachi Tohoku Software, Ltd.Sendai 980Japan
  3. 3.Institute for Materials ResearchTohoku UniversityAoba-ku, SendaiJapan

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