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Ultraviolet photoelectron spectroscopy of C60 produced by three different generation methods

  • M. Kohno
  • S. Suzuki
  • T. Kodama
  • D. Kasuya
  • H. Shiromaru
  • Y. Achiba
Conference paper

Abstract

The photoelectron spectra of C 60 produced with three different generation methods were recorded with 6.4 eV photon energy using a magnetic-bottle-type time-of-flight photoelectron spectrometer. From these spectra, it was suggested that the laser vaporization of a graphite rod mainly produces C 60 of ring-like structure. On the other hand, C 60 produced by the fragmentation process of the fullerene C70 through C2 or C2n elimination give different photoelectron features from those of C 60 having an icosahedral (Ih) symmetry or a ring-like structure.

PACS

33.60.−q Photoelectron spectra 36.40.−c Atomic and molecular cluster 

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References

  1. 1.
    W. Kraetschmer, K. Fostiropoulos, D.R. Huffman: Chem, Phys. Lett. 170, 167 (1990)ADSCrossRefGoogle Scholar
  2. 2.
    R.E. Smalley: Acc. Chem, Res. 25, 98 (1992)CrossRefGoogle Scholar
  3. 3.
    D.E. Manolopoulos, P.W. Fowler: The Chemical Physics of Fullerene 10 (and 5) Years Later, NATO ASI Series 316, 51 (1992)Google Scholar
  4. 4.
    T. Wakabayashi, Y. Achiba: Chem. Phys. Lett. 190, 465 (1992)ADSCrossRefGoogle Scholar
  5. 5.
    N.G. Gotts, G. von Helden, M.T. Bowers: Int. J. Mass. Spectrom. Ion Processes 149/150, 217 (1995)Google Scholar
  6. 6.
    O. von Helden, M.T. Hsu, N. Gotts, M.T. Bowers: J. Chem. Phys. 97, 8182 (1993)CrossRefGoogle Scholar
  7. 7.
    J.M. Hunter, J.L. Fye, M.F. Jarrold: J. Chem. Phys. 99, 1785 (1993)ADSCrossRefGoogle Scholar
  8. 8.
    Y. Yamaguchi, S. Maruyama: Chem. Phys. Lett. 286, 343 (1998)ADSCrossRefGoogle Scholar
  9. 9.
    S.H. Yang, K.J. Taylor, M.J. Craycraft, J. Conceicao, C.L. Pettiette, O. Cheshnovsky, R.E. Smalley: Chem. Phys. Lett. 144, 431 (1988)ADSCrossRefGoogle Scholar
  10. 10.
    S.H. Yang, Ci, Pettieete, J. Conceicao, O. Cheshnovsky, R.E. Smalley: Chem. Phys. Lett. 139, 233 (1987)ADSCrossRefGoogle Scholar
  11. 11.
    D.W. Arnold, S,E, Bradforth, T.N. Kitsopoulos, D.M. Neumark: J. Chem. Phys. 95, 8753 (1991)ADSCrossRefGoogle Scholar
  12. 12.
    C. Xu, G.R. Burton, T.R. Taylor, D.M. Neumark: I. Chem. Phys, 107, 3428 (1997)ADSCrossRefGoogle Scholar
  13. 13.
    L.-S. Wang: Surf. Rev, Lett. 3, 423 (1996)CrossRefGoogle Scholar
  14. 14.
    M. ‘Kohno, T. Moriwaki, S. Suzuki, H. Shiromaru, Y. Achiba: Chem. Phys. Lett. 282, 330 (1998)ADSCrossRefGoogle Scholar
  15. 15.
    M. Kohno et al.: (to be submitted)Google Scholar
  16. 16.
    W.C. Wiley, I.H. McLaren: Rev, Sci. Instrum. 26, 1150 (1955)ADSCrossRefGoogle Scholar
  17. 17.
    R.C. Haddon, L.E. Brus, K. Ragavachari: Chem. Phys. Lett. 125, 459 (1986)ADSCrossRefGoogle Scholar
  18. 18.
    M.D. Newton, R. E. Stanton: J. Am. Chem. Soc. 108, 240 (1986)CrossRefGoogle Scholar
  19. 19.
    H. Handschuh, G. Gantefoer, B. Kessler, P.S. Bechthold, W. Eberhardt: Phys. Rev. Lett. 74, 1095 (1995)ADSCrossRefGoogle Scholar
  20. 20.
    M. Kohnp, S. Suzuki, H. Shirornaru, Y. Achiba: J. Chem. Phys. 110, 3781 (1999)ADSCrossRefGoogle Scholar
  21. 21.
    E.E.B. Campbell, T. Raz, R.D. Levine: Chem. Phys. Lett, 253, 261 (1996)ADSCrossRefGoogle Scholar
  22. 22.
    H. Hohmann, R. Ehlich, S. Furrer, D. Grosenick, E.E.B. Campbell: Z. Phys. D 33, 143 (1995)ADSCrossRefGoogle Scholar
  23. 23.
    K.R. Lykke, P. Wurtz: Phys. Chem, 95, 3191 (1992)CrossRefGoogle Scholar
  24. 24.
    S.G. Kim, D. Tomanek: Phys. Rev. Lett. 72, 2418 (1994)ADSCrossRefGoogle Scholar

Copyright information

© Springer-Verlag Italia 1999

Authors and Affiliations

  • M. Kohno
    • 1
  • S. Suzuki
    • 1
  • T. Kodama
    • 1
  • D. Kasuya
    • 1
  • H. Shiromaru
    • 1
  • Y. Achiba
    • 1
  1. 1.Department of ChemistryTokyo Metropolitan UniversityHachioji, TokyoJapan

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