Advertisement

Low energy acetone dimer ion/surface collisions studied with high energy resolution

  • C. Mair
  • T. Fiegele
  • F. Biasioli
  • T. D. Märk
Conference paper

Abstract

We have recently constructed the tandem mass spectrometer set-up BESTOF (consisting of a B-sector field combined with an E-sector field, a Surface and a Time Of Flight mass spectrometer) which allows the investigation of ion/surface reactions with high primary mass and energy resolution. Using BESTOF we have extended previous investigations from molecular projectile ions to cluster ions. In particular, we have studied here surface induced dissociation (SID) and surface induced reactions (SIR) of acetone dimer ions upon impact on a hydrocarbon covered stainless steel surface as a function of incident collision energy up to about 80 eV.

PACS

34.90.+q Other topics in atomic and molecular collision processes and interactions 82.65.Fr Film and membrane processes: ion exchange, dialyse, osmosis; electroosmosis 82.30.Fi. Ion—molecule, ion—ion, and charge transfer reactions 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    R.G. Cooks, T. Ast, M.A. Mabud: Int. J. Mass Spectrom. Ion Processes 100, 209 (1990); A. Amirav: Comments At. Mol. Phys. 24, 187 (1990) 25.Google Scholar
  2. L. Hanley (Ed.): Special issue on Polyatomic ion-surface interactions, Int. J. Mass Spectrom. 174 (1998)Google Scholar
  3. 3.
    W.O. Hofer, J. Roth (Eds.): Physical Processes of the Interaction of Fusion Plasmas with Solids (Academic Press, San 26. Diego 1996 )Google Scholar
  4. 4.
    J.P. Booth; PrOC. XIVtli European Sectional Conference Atomic and Molecular Physics in ionized Gases (ESCAMPIG), Malahide, Ireland (1998)Google Scholar
  5. 5.
    D.H. Graves, M.J. Kushner, J.W. Gallagher, A. Garscaclden, G.S. Oehrlein, A.V. Phelps: Database needs for modeling and simulation of plasma proce.ssing, Report by the panel on database needs in plasma processing (National Research Council, National Academy Press, Washington, DC 1996 )Google Scholar
  6. 6.
    R.K. Janev (Ed.): Atomic and Molecular Processes in Fusion Edge Plasmas ( Plenum, New York 1995 )Google Scholar
  7. 7.
    S. Matt, T.D. Mark, K.H. Meiwes-Broer (Eds.): Cluster Surface Interactions, Book of Abstracts of ESE’ Conference, Cargese, Corse (1998)Google Scholar
  8. 8.
    T.D. Märk, A.W. Castleman: Adv. Atom. Molec. Phys. 20, 66 (1985)Google Scholar
  9. 9.
    H. Haberland (Ed.): Clusters of Atoms and Molecules and II ( Springer, Berlin 1994Google Scholar
  10. 10.
    W. Christen, U. Even, T. Raz, R.D. Levine: Int. J. Mass Spectrom. 174, 35 (1998)ADSCrossRefGoogle Scholar
  11. 11.
    V. Grill, R. Wörgötter, J.H. Futrell, T.D. Märk; Z. Phys. D 40, 111 (1997)Google Scholar
  12. 12.
    R.D. Beck, P.S. John, M.M. Alvarez, F. Diederich, R.L. Whettem J. Phys. Chem. 95, 8402 (1991); H.G. Busmann, T. Lill, B. Reif, I.V. Hertel: Surf. Sci. 272, 146 (1992); H. Yasumatsu, U. Kalmbach, S. Koizumi, A. Terasaki, T. Kondow: in Structure and Dynamics of Clusters, ed. by T. Kondow, K. Kaya, A. Terasaki (Universal Academy Press, Tokyo 1996) pp, 48. 5Google Scholar
  13. 13.
    R.D. Beck, J. R.ockenberger, P. Weis, M.M. Kappes: J. Chem, Phys. 104.: 3638 (1996)Google Scholar
  14. 14.
    C.L. Cleveland, U. Landman: Science 257, 355 (1992)ADSCrossRefGoogle Scholar
  15. 15.
    T. Raz, R.D. Levine: Chem. Phys. Lett. 246, 405 (1995)ADSCrossRefGoogle Scholar
  16. 16.
    V. Grill, R.G. Cooks: Contributions to Symposium on Atomic and Surface Physics SASP 98. ed. by A. Hansel, W. Lindinger, ( Going 1998 ) p. 129Google Scholar
  17. 17.
    S.B. Wainhaus, B.A. Gislason, L. Hanley: J. Am. Chem, Soc. 119, 4001 (1997)CrossRefGoogle Scholar
  18. 18.
    T.M. Bernhardt, B. Kaiser, K. Rademann: Z. Phys. Chem. 195, 27.3 (1996); Z. Phys. D 40,:327 (1997); B. Kaiser, T.M. Bernhardt, K. Rademann: Nuck Instrum. Methods Phys. Res. B 125, 223 (1997)Google Scholar
  19. 19.
    R. Wörgötter, V. Grill, Z. Herman, H. Schwarz, T.D. Mink: Chem. Phys, Lett. 270, 333 (1997)ADSCrossRefGoogle Scholar
  20. 20.
    R. Wörgötter, C. Mair, T. Fiegele, V. Grill, T.D.- Mark, H. Schwarz: Int. J. Mass Spectrom. Ion Processes 164, LI (1997)Google Scholar
  21. 21.
    R. Wörgötter, J. Kubista, J. Zabka, Z. Dolejsek, T.D. Märk, Z. Herman: Int. J. Mass Spectrom. 174, 53 (1998)ADSCrossRefGoogle Scholar
  22. 22.
    C. Man, T. Fiegele, R. Wörgötter, J.H. Futrell, T.D. Märk: Int. J. Mass Spectrom. Ion Processes 177, 105 (1998)Google Scholar
  23. 23.
    C. Man, Z. Herman, T. Fiegele, J.H. Futrell, T.D. Mark: lot.1. Mass Spectrom. 188, 21 (1999)Google Scholar
  24. 24.
    C. Mair, T. Fiegele, F. Biasioli, T.D. Märk, W.R. Hess: International Congress on Plasma Physics, Book of Abstracts, ed. by J. Badalec, J. Stöckel, P. Sunka, M. Tendler, Prague (1998) p. 171Google Scholar
  25. 25.
    T. Fiegele, F. Biasioli, C. Mair, T.D. Märk, F. Aumayr, G. Betz, HP. Winter: Book of Abstracts ERC Symposium on Cluster surface interaction, ed. by S. Matt, T.D. Märk, K.H. Meiwes-Broer, Cargese (1998) p. 63Google Scholar
  26. 26.
    K. Tögelhofer, F. Aumayr, H. Kurz, HP. Winter, P. Scheler, T.D. Märk: J. Chem. Phys. 99, 8254 (1993)ADSCrossRefGoogle Scholar
  27. 27.
    HP, Winter, M. Vana, G. Betz, F. Aumayr, H. Drexel, P. Scheler, T.D. Mark: Phys. Rev. A 56, 3007 (1997)ADSCrossRefGoogle Scholar
  28. 28.
    F. Aumayr, M. \Tana, HP. Winter, H. Drexel, V. Grill, G. Senn, S. M.tt, P. Scheier, T.D. Mdrk: Int. J. Mass Spectrom. Ion Processes 163, L9 (1997)ADSGoogle Scholar
  29. 29.
    H.R. Siekmann, C. Udder, J. Faehrmann, H.O. Lutz, K.H. Meiwes-Broer: Z. Phys. D 20, 417 (1991)ADSCrossRefGoogle Scholar
  30. 30.
    R.A.G. McNeil, J.H. Futrell: J. Phys. Chem. 76, 409 (1.972)Google Scholar
  31. 31.
    A.S. Blair, A.G. Harrison: Can. J. Chem, 51. 703 (1973)CrossRefGoogle Scholar
  32. 32.
    M. Kumakura, T. Sufiura: J. Phys. Chem. 82, 639 (1978)CrossRefGoogle Scholar
  33. 33.
    T.D. Mkrk: in Linking the Gaseous and Condensed Phases of Matter, ed. by L.G. Christophorou, E. illenberger, W.F. Schmidt ( Plenum Press, New York 1994 ) pp. 155Google Scholar
  34. 34.
    C. Mair, T. Fiegele, F. Biasioli, Z. Herman, T.D. Märk: J. Chem. Phys. 111, 2770 (1999)ADSCrossRefGoogle Scholar
  35. 35.
    J.H. Futrell: private communication (1998)Google Scholar
  36. 36.
    U. Even, I. Schek, J. Jortner. Chem. Phys. Lett. 202, 303 (1993)ADSCrossRefGoogle Scholar
  37. 37.
    T. Raz, I. Schek, M. Ben-Nun, U, Even, J. Jortner, R.D. Levine: J. Chem. Phys. 101, 8606 (1994)ADSGoogle Scholar
  38. 38.
    Schek, T. Raz, R.D. Levine, J. Jortner: J. Chem. Phys. 101. 8596 (1994)ADSCrossRefGoogle Scholar
  39. 39.
    I. Schek, J Jortner, T. Raz, R.D. Levine: Chem. Phys. Le. 257, 273 (1996)ADSCrossRefGoogle Scholar

Copyright information

© Springer-Verlag Italia 1999

Authors and Affiliations

  • C. Mair
    • 1
  • T. Fiegele
    • 1
  • F. Biasioli
    • 1
  • T. D. Märk
    • 1
    • 2
  1. 1.Institut für IonenphysikLeopold Franzens UniversitätInnsbruckAustria
  2. 2.Dept. PlasmaphysicsUniverzita KomenskehoBratislava 4Slovensko

Personalised recommendations