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Deuteron NMR Study of Molecular Motion near the Glass Transition in Polystyrene at High Pressure

  • A. S. Kulik
  • M. de Langen
  • K. O. Prins
Conference paper

Abstract

Deuteron-NMR techniques 1) are used to study the effect of high hydrostatic pressure on the dynamical properties of polystyrene (PS) near its glass-transition temperature Tg. An analysis is made of the phenyl-flip and chain motion as a function of density.

PACS numbers

33.25 36.20 62.50 64.70 

References

  1. 1).
    H.W. Spiess, Advances in Polymer Science 66(1985)23Google Scholar
  2. 2).
    P.W.E. Peereboom, K.O. Prins, N. Trappeniers, Rev.Sci.Instr. 59 (1988) 1182Google Scholar
  3. 3).
    P. Lindner, E. Rossler, H. Sillescu, Makromol.Chem.182(1981)3653Google Scholar
  4. 4).
    H.W. Spiess, Colloid and Polymer Science 261(1983)193Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1990

Authors and Affiliations

  • A. S. Kulik
    • 1
  • M. de Langen
    • 1
  • K. O. Prins
    • 1
  1. 1.Van der Waals LaboratoryUniversity of AmsterdamAmsterdamThe Netherlands

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