Advertisement

The 14N NQR Spectrum and the Crystal Structure of Ba [Fe(CN)5NO] · 3H20 at Room Temperature

  • Juan Murgich
  • Ismardo Bonalde
Conference paper

Abstract

The reported 14N NQR spectrum of the CN groups of Ba [Fe(CN)5NO] • 3H20 BNP was shown to contain lines of traces of the Na [Fe(CN)5NO] • 3H20 BNP used in its preparation. A study of the intensity of the NQR lines confirmed that BNP has a Pbcm instead of a Pca22 space group as previously assumed. Therefore, the 3 CN sites found in BNP at room temperature increases to 5 below 233 and to 8 below 131 K as a result of phase transitions occurring at these temperatures. The effect of the disorder of some H2O molecules on the intensity of the lines of the axial CN group in BNP is also discussed.

PACS number

76.60.Gv. 

References

  1. 1).
    J. Hurgich, I. Bonalde and J.A. Abanero, Z. Naturforsch. k. in press (1989)Google Scholar
  2. 2).
    A.H. Lanfranconi, A.G. Alvarez and E.E. Castellano, Acta Crystallogr. B29, 1773 (1973)CrossRefGoogle Scholar
  3. 3).
    A. Navaza, G. Rigotti, P.H. Alzari, E. Tolosa, J.R. Grigera, E.L. Yaretti and P.J. Aymonino, J. Cryst.Spectrosc.Res. submited (1989)Google Scholar
  4. 4).
    C. Retzlaff, W. Krumbe, H. Dorfel and S. Haussuhl, Z. Kristallogr. in press (1990).Google Scholar
  5. 5).
    A. Navaza, P. Schweiss, P.M. Alzari, G. Chevrier, G. Heger and J. Guida, private communication (1989).Google Scholar
  6. 6).
    I.A. Buslaev, L. Kolditz and E.A. Kravchenko, “Nuclear Quadrupole Resonance in Inorganic Chemistry”,VEB, Berlin (1987).Google Scholar
  7. 7).
    J. Murgich and R. Ambrosetti, J.Maon. Resonan. 74, 344 (1987)ADSGoogle Scholar
  8. 8).
    F. Bottomley and P.S. White, Acta Crystallogr. B35, 2193 (1979)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1990

Authors and Affiliations

  • Juan Murgich
    • 1
  • Ismardo Bonalde
    • 1
  1. 1.Centro de QuimicaIVICCaracasVenezuela

Personalised recommendations