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ESR-Investigations on the Solid Solution Mg2-x CuxP4O12

  • W. Gunßer
  • A. Zimmermann
Conference paper

Abstract

ESR-investigations were performed on the solid solution Mg2-xCuxP4O12. The single ion spectrum shows a tetragonal g-tensor which is caused by a planar-quadratic dynamic Jahn-Teller effect. At 2 K a HFS is observed. Pure Cu2P4O12 exhibits a static Jahn-Teller-distortion even at room temperature. The onset of ferrimagnetic ordering below 8 K leads to a pronounced shift of the g-values.

References

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    W. Gunsser, D. Fruehauf, K. Rohwer, A. Zimmermann, A. Wiedenmann, J. Solid State Chem. 82, 43 (1989).ADSCrossRefGoogle Scholar
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    D. Reinen, C. Friebel, Struct. Bonding (Berlin) 37, 1 (1979).CrossRefGoogle Scholar
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    M. Laügt, J. C. Guitel, I. Tjordman, G. Bassi, Acta Cryst. B28, 201 (1972)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1990

Authors and Affiliations

  • W. Gunßer
    • 1
  • A. Zimmermann
    • 1
  1. 1.Institut für Physikalische ChemieUniversität HamburgHamburg 13Germany

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